Citation: KUANG Dai-Zhi, ZHU Xiao-Ming, FENG Yong-Lan, ZHANG Fu-Xing, YU Jiang-Xi, JIANG Wu-Jiu, TAN Yu-Xing, ZHANG Zhi-Jian. Syntheses, Crystal Structures and Biological Activities of Bis(tricyclohexyltin)dicarboxylates with Macrocyclic Building 2D Network[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 2044-2050. doi: 10.11862/CJIC.2015.268 shu

Syntheses, Crystal Structures and Biological Activities of Bis(tricyclohexyltin)dicarboxylates with Macrocyclic Building 2D Network

1.
1 College of Chemistry and Material Science, Hengyang Normal University;Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Hengyang, Hunan 421008, China;
2.
2 College of Life Science and Environment, Hengyang Normal University, Hengyang, Hunan 421008, China

Corresponding author: KUANG Dai-Zhi,
Received Date: 26 May 2015
Available Online: 15 July 2015
Fund Project: 湖南省自然科学基金(13JJ3112) (13JJ3112)科技计划(2014NK3086,2014FJ3060)项目,功能金属有机材料湖南省普通高校重点实验室开放基金资助项目(13K105,14K014,13K01-05,GN14K01) (2014NK3086,2014FJ3060)项目,功能金属有机材料湖南省普通高校重点实验室开放基金资助项目(13K105,14K014,13K01-05,GN14K01)湖南省重点学科基金和湖南省高校科技创新团队支持计划资助项目,衡阳师范学院协同创新中心培育项目(No.12XT02) (No.12XT02)湖南省教育厅基金项目(No.15C0199,15C0200,14C0171,14C0168)资助。 (No.15C0199,15C0200,14C0171,14C0168)

Two bis(tricyclohexyltin)dicarboxylate(CH₂)_n(CO₂SnCy₃)₂[(n:6(1), 7(2)] have been synthesized by the reaction of suberic acid and azelaic acid with tricyclohexyltin hydroxide, respectively. The structures of the products were confirmed by IR, ¹H and ¹³C NMR, elemental analysis and X-ray diffraction. The complexes 1 and 2 belong to monoclinic, space group P2₁/n and P2₁/c. A 2D network structure was formed by 30-membered or 32-membered macrocyclic tetratin species, which has been alternately connected through the Sn-O covalent bond or the Sn-O covalent bond and Sn...O weak interaction, respectively. The tests showed the two complexes displayed strong in vitro anti-tumor activity against five human tumor cell lines, Colo205, HepG2, MCF-7, Hela and NCI-H460 and has selective antibacterial property for S. Aureus, B. Subtilis, E. Coli and S. Typhi. CCDC: 1047100,11; 1047101,2.
- bis(tricyclohexyltin)dicarboxylate;macrocycle compounds;crystal structure;biological activity
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