Citation: WEN Xiao-Ling, GAN Qiong-Zhi, OUYANG Jian-Ming. Adsorption of Nonionic Surfactant NP-40 on Micron/Nano Calcium Oxalate Monohydrate and Dihydrate Crystals[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 2021-2029. doi: 10.11862/CJIC.2015.266 shu

Adsorption of Nonionic Surfactant NP-40 on Micron/Nano Calcium Oxalate Monohydrate and Dihydrate Crystals

1.
Institute of Biomineralization and Lithiasis Research, Jinan University, Guangzhou 510632, China

Corresponding author: OUYANG Jian-Ming,
Received Date: 24 March 2015
Available Online: 26 August 2015
Fund Project: 国家自然科学基金(No.21371077)资助项目。 (No.21371077)

In order to study the formation mechanism of calcium oxalate (CaO_x) stones, the adsorption amount of COD and COM with different sizes to NP-40 was detected by UV-Vis spectroscopy. Crystal phase transformation before and after adsorption was analyzed by XRD and FT-IR. ζ potential of crystals after the adsorption of various concentration of NP-40(c_NP-40) was measured by ζ potential analyzer. The adsorption capacity of COM and COD with different size to NP-40 was: 50 nm > 100 nm > 1 μm > > 3 μm > 10 μm. The adsorption quantity of COM was greater than COD of the same size. The adsorption curves of COM and COD with size of 3 μm and 10 μm are S-type, while the curves of COM and COD with size of 50 nm, 100 nm and 1 μm were linear-type. The absolute values of ζ potential of crystals were positively related to the adsorption density to NP-40. The molecular model of NP-40 adsorbed on CaO_x crystals was proposed in this study. The smaller the crystal size is, the greater the adsorption amount of CaO_x crystals to NP-40 possess. Although nonionic surfactant itself is uncharged, it can be adsorbed onto COM and COD crystals and increase the stability of crystals suspension by steric hindrance, which is conducive to inhibiting the formation of CaO_x stones.
- calcium oxalate;crystal size;nonionic surfactant;surface adsorption;adsorption model
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