Citation: BING Ying-Ying, WU Zhen-Ting, HU Ming. Syntheses, Crystal Structures and Properties of Three Transition Metal Coordination Compounds Based on 2,2'-Bipyridine-3,3',6,6'-tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 2059-2064. doi: 10.11862/CJIC.2015.264 shu

Syntheses, Crystal Structures and Properties of Three Transition Metal Coordination Compounds Based on 2,2'-Bipyridine-3,3',6,6'-tetracarboxylic Acid

1.
Inner Mongolia Key Laboratory of Chemistry and Physics of Rare Earth Materials, School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China

Corresponding author: HU Ming,
Received Date: 18 March 2015
Available Online: 9 July 2015
Fund Project: 国家自然科学基金(No.21361017) (No.21361017)内蒙古自然科学基金(No.2012MS0214) (No.2012MS0214)内蒙古高等学校科学技术研究重点研究(No.NJZZ12012)资助项目。 (No.NJZZ12012)

Three transition metal complexes, namely, [Co₂(H₂bptc)₂(H₂O)₄]·bpe·9H₂O (1), [Ni₂(H₂bptc)₂(H₂O)₄]·bpe·9H₂O (2), [Ni₂(H₂bptc)₂(H₂O)₄]·0.5bpp·7H₂O (3) (H₄bptc=2,2'-bipyridine-3,3',6,6'-tetracarboxylic acid, bpe=1,2-di(4-pyridyl)ethylene, bpp=1,2-di(4-pyridyl) ethane) have been synthesized under hydrothermal conditions and structurally characterized by infrared spectra, thermogravimetric analyses and single crystal X-ray diffraction. Compounds 1~3 are the mononuclear units and extended further to generate the three-dimensional supramol-ecular architectures by strong hydrogen-bonding interactions, respectively. CCDC: 1054309, 1; 1054310, 2; 1054311, 3.
- 2,2'-bipyridine-3,3',6,6'-tetracarboxylic acid;coordination compound;synthesis;crystal structure
1. [1]
  [1] Domasevitch K V, Solntsev P V, Krautscheid H, et al. Chem. Commun., 2012,48:5847-5849
2. [2]
  [2] Zhao B, Cheng P, Liao D Z, et al. Inorg. Chem., 2005,44:911-920
3. [3]
  [3] Valencia L, Pérez-Lourido P, Bastida R, et al. Cryst. Growth Des., 2008,8:2080-2082
4. [4]
  [4] LI Xin-Wei(李欣玮), WANG Peng(王鹏), ZHONG Jing-Wen (钟静文), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30(6):1361-1366
5. [5]
  [5] Urszula D, Florian P P, Radosaw S. Dalton Trans., 2009:3348-3353
6. [6]
  [6] Kochel A, Holynska M. Inorg. Chim. Acta, 2013,408:193-198
7. [7]
  [7] (a)Zheng S L, Tong M L, Fu R W, et al. Inorg. Chem., 2001, 40:3562-3569
8. [8]
  (b)YAN Li(闫丽), HAN Pan(韩盼), TIAN Wen-Chao(田文超), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014, 30(6):1255-1260
9. [9]
  [8] Yu M H, Hu M, Wu Z T, et al. Inorg. Chim. Acta, 2013,408:84-90
10. [10]
  [9] Jain P, Ramachandran V, Clark R J. J. Am. Chem. Soc., 2009,131:13625-13627
11. [11]
  [10] He Y B, Guo Z Y, Chen B L, et al. Inorg. Chem., 2013,52:11580-11584
12. [12]
  [11] Swastik M, Monika M, Koushik D, et al. Cryst. Growth Des., 2007,7:1716-1721
13. [13]
  [12] Li X, Cheng D Y, Lin J L, et al. Cryst. Growth Des., 2008,8:2854-2861
14. [14]
  [13] Houjou H, Ito M, Araki K, et al. Inorg. Chem., 2009,48:10703-10707
15. [15]
  [14] Byun Y, Yun H, Do Y, et al. Inorg. Chem., 1996,35:3981-3989
16. [16]
  [15] Ji B M, Deng D S, He X, et al. Inorg. Chem., 2012,51:2170-2177
17. [17]
  [16] (a)Hu M, Wu Z T, Yao J Y, et al. Inorg. Chem. Comm., 2013,36:31-34
18. [18]
  (b)Bai H, Wu Z T, Hu M, et al. Inorg. Chim. Acta, 2015, 427:112-117
19. [19]
  [17] Dawid U, Pruchnik F P, Starosta R. Dalton Trans., 2009,38:3348-3353
20. [20]
  [18] (a)Sheldrick G M. SHELXL-97, Program for the Solution of Crystal Structures, Göttingen University, Germany, 1997.
21. [21]
  (b)Sheldrick G M. SHELXL-97, Program for Crystal Structures Refinement, Göttingen University, Germany, 1997.
22. [22]
  [19] (a)Chu Q, Su Z, Sun W Y, et al. Cryst. Growth Des., 2011, 11:3885-3894
23. [23]
  (b)Huang F P, Liao D Z, Cheng P, et al. CrystEngComm, 2011,13:6538-6548
24. [24]
  [20] (a)Li X, Wu B L, Hou H W, et al. Inorg. Chem., 2010,49:2600-2613
25. [25]
  (b)Wang X L, Li J, Lin H Y, et al. Cryst. Growth Des., 2011, 11:3456-3462
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
3. [3]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
4. [4]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
5. [5]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
8. [8]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
9. [9]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
10. [10]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
11. [11]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103
12. [12]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
13. [13]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
14. [14]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
15. [15]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
16. [16]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
17. [17]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
18. [18]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
19. [19]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
20. [20]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(396)
HTML views(29)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142