Citation: PANG Hai-Xia, YUAN Xi-Ming, WANG Xian-Wen, HE Xiong. Syntheses, Crystal Structures and Magnetic Properties of Co(Ⅱ) and Mn(Ⅱ) Complexes with 4-(4-Pyridinemethyleneamino)-1,5-dimethyl-2-phenyl-1,2-dihydropyrazol-3-one[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 2008-2014. doi: 10.11862/CJIC.2015.243 shu

Syntheses, Crystal Structures and Magnetic Properties of Co(Ⅱ) and Mn(Ⅱ) Complexes with 4-(4-Pyridinemethyleneamino)-1,5-dimethyl-2-phenyl-1,2-dihydropyrazol-3-one

1.
1 Engineering Research Center of Nano-Geo Materials of the Ministry of Education, Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074, China;
2.
2 Department of light industry, Hubei University of Technology, Wuhan 430068, China

Corresponding author: YUAN Xi-Ming,
Received Date: 18 March 2015
Available Online: 23 June 2015
Fund Project: 国家自然科学基金(No.51173039,51202064) (No.51173039,51202064)教育部纳米矿物材料及应用工程研究中心开放课题(No.CUGNGM201412)资助项目。 (No.CUGNGM201412)

Two complexes [CoLCl₂] (1) and [MnLCl₂] (2) (L=4-(4-pyridinemethyleneamino)-1,5-dimethyl-2-phenyl-1,2-dihydropyrazol-3-one) were solvothermally synthesized and structurally characterized by elemental analysis, IR, XRD, TG, single-crystal X-ray diffraction and magnetic analysis. The complexes 1 and 2 are determined by X-ray structural analysis and the structure parameters are analyzed as follows: 1, monoclinic, Cc; 2, triclinic, P1. The X-ray diffraction results suggest that the complex 1 exhibits distorted tetrahedral configuration, and the complex 2 exhibits distorted octahedral configurations. CCDC: 913873, 1; 913872, 2.
- Schiff base;solvothermal method;pyridine-4-formaldehyde;crystal structure;magnetic properties
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