Citation: TANG Wen-Yuan, REN Shi-Bin, ZHU Dong-Dong, HAN De-Man, ZHOU Xin-Hui. Crystal Structures and Properties of Zn(Ⅱ)/Cd(Ⅱ) Coordination Polymers Based on Semirigid Tetrahedral Quadridentate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(10): 2073-2078. doi: 10.11862/CJIC.2015.229 shu

Crystal Structures and Properties of Zn(Ⅱ)/Cd(Ⅱ) Coordination Polymers Based on Semirigid Tetrahedral Quadridentate Ligand

1.
1 School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou, Zhejiang 317000, China;
2.
2 State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;
3.
3 Key Laboratory for Organic Electronics & Information Displays(KLOEID)and Institute of Advanced Materials(IAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China

Corresponding author: REN Shi-Bin, ZHOU Xin-Hui,
Received Date: 13 April 2015
Available Online: 14 May 2015
Fund Project: 国家自然科学基金(No.21471110,21375092) (No.21471110,21375092)浙江省自然科学基金(No.LY12B01006) (No.LY12B01006)中国博士后基金(No.2013M531314) (No.2013M531314)生命分析国家重点实验室开放课题(No.SKLACLS1206) (No.SKLACLS1206)浙江省大学生创新计划项目(No.2014R428014) (No.2014R428014)台州市科技局项目(No.131KY03) (No.131KY03)浙江省科技厅公益分析测试项目(No.2015C37034)资助项目。 (No.2015C37034)

Two complexes, {[Cd₂(L₁)(1,4-NDC)₂]·2H₂O}_n (1) and {[Zn₂(L₂)(1,4-NDC)₂]·DMF·3H₂O)}_n (2) (L₁=tetrakis(4-pyridyloxymethylene)methane, L₂=tetrakis(3-pyridyloxymethylene)methane, 1,4-NDC=naphthalene-1,4-dicarbox-ylic acid) are obtained by the self-assembly reaction of L₁ or L₂, 1,4-NDC, and d¹⁰ metal ions under solvothermal conditions. The X-ray analysis reveals that 1 is constructed from a 1D zigzag chain [Cd(1,4-NDC)]_n which is linked by L₁ ligand to yield a 3D framework. And yet in case of 2, one double helix is mutually interdigitated by another 1D chain into a 2D network. Above all, the effect of steric hindrance of the auxiliary linker on the structural diversity of CPs can be discussed in great detail by the introduction of two kinds of auxiliary linkers with different steric hindrance. Additionally, their luminescent properties are also observed. CCDC: 1019510, 1; 1019511, 2.
- carboxylate ligands;isomerization;steric hindrance;luminescence
1. [1]
  [1] (a)Moulton B, Zaworotko M J. Chem. Rev., 2001,101:1629-1658
2. [2]
  (b)James S L. Chem. Soc. Rev., 2003,32:276-288
3. [3]
  (c)Ockwig N W, Delgado-Friedrichs O, O'Keeffe M, et al. Acc. Chem. Res., 2005,38:176-182
4. [4]
  (d)Noro S, Kitagawa S, Kondo M, et al. Angew. Chem. Int. Ed., 2000,39:2081-2084
5. [5]
  (e)Zhang J P, Lin Y Y, Huang X C, et al. J. Am. Chem. Soc., 2005,127:5495-5506
6. [6]
  (f)Song X Z, Song S Y, Zhao S N, et al. Adv. Funct. Mater., 2014,24:4034-4041
7. [7]
  [2] (a)Perry J J 4th, Perman J A, Zaworotko M J, et al. Chem. Soc. Rev., 2009,38:1400-1417
8. [8]
  (b)Li J R, Sculley J, Zhou H C. Chem. Rev., 2012,112:869-932
9. [9]
  (c)Farha O K, Hupp J T. Acc. Chem. Res., 2010,43:1166-1175
10. [10]
  [3] (a)Ma T, Li M X, Wang Z X, et al. Cryst. Growth Des., 2014, 14:4155-4165
11. [11]
  (b)Zhang X, Hou L, Liu B, et al. Cryst. Growth Des., 2013, 13:3177-3187
12. [12]
  (c)Hua J A, Zhao Y, Liu Q, et al. CrystEngComm, 2014,16:7536-7546
13. [13]
  (d)Lu X, Ye J, Li W, et al. CrystEngComm, 2012,14:1337-1344
14. [14]
  [4] (a)Ren S B, Zhou L, Zhang J, et al. CrystEngComm, 2010, 12:1635-1638
15. [15]
  (b)Ren S B, Chen F J, Wu C L, et al. J. Mol. Struct., 2013, 1034:193-197
16. [16]
  (c)Ren S B, Qiu Z J, Yan J, et al. J. Mol. Struct., 2013,1046:15-20
17. [17]
  [5] (a)Paz F A A, Klinowski J, Vilela S M F, et al. Chem. Soc. Rev., 2012,41:1088-1110
18. [18]
  (b)Liang X, Zhang F, Zhao H, et al. Chem. Commun., 2014, 50:6513-6516
19. [19]
  (c)Zhou X H, Li L, Li H H, et al. Dalton Trans., 2013,42:12403-12409
20. [20]
  [6] (a)Ren S B, Zhou L, Zhang J, et al. CrystEngComm, 2009,11:1834-1836
21. [21]
  (b)Ren S B, Zhou L, Zhang J, et al. Inorg. Chem., Commun., 2011,14:558-561
22. [22]
  (c)Ren S B, Lin Y Q, Zhang Q, et al. Polyhedron, 2014,83:130-136
23. [23]
  (d)Zhang Q, Bu X, Lin Z, et al. Inorg. Chem., 2008,47:9724-9726
24. [24]
  [7] (a)SAINT-Plus, Version 6.02, Bruker Analytical X-ray System, Madison, WI, 1999.
25. [25]
  (b)Sheldrick G M. SADABS, An Empirical Absorption Correction Program, Bruker Analytical X-ray Systems, Madison, WI, 1996.
26. [26]
  (c)Sheldrick G M. Acta Crystallogr., 2008,A64:112
27. [27]
  [8] (a)He K H, Song W C, Li Y W, et al. Cryst. Growth Des., 2012,12:1064-1068
28. [28]
  (b)Ren S B, Yang X L, Zhang J, et al. CrystEngComm, 2009,11:246-248
29. [29]
  (c)Lu Y B, Jian F M, Jin S, et al. Cryst. Growth Des., 2014, 14:1684-1694
1. [1]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
2. [2]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
3. [3]
  Feng Lu , Tao Wang , Qi Wang . Preparation and Characterization of Water-Soluble Silver Nanoclusters: A New Design and Teaching Practice in Materials Chemistry Experiment. University Chemistry, 2025, 40(4): 375-381. doi: 10.12461/PKU.DXHX202406005
4. [4]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
5. [5]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
6. [6]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
7. [7]
  Zehua Zhang , Haitao Yu , Yanyu Qi . 多重共振TADF分子的设计策略. Acta Physico-Chimica Sinica, 2025, 41(1): 2309042-. doi: 10.3866/PKU.WHXB202309042
8. [8]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
9. [9]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
10. [10]
  Zijuan LI , Xuan LÜ , Jiaojiao CHEN , Haiyang ZHAO , Shuo SUN , Zhiwu ZHANG , Jianlong ZHANG , Yanling MA , Jie LI , Zixian FENG , Jiahui LIU . Synthesis of visual fluorescence emission CdSe nanocrystals based on ligand regulation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 308-320. doi: 10.11862/CJIC.20240138
11. [11]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
12. [12]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
13. [13]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
14. [14]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
15. [15]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
16. [16]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
17. [17]
  Xinyu Liu , Weiran Hu , Zhengkai Li , Wei Ji , Xiao Ni . Algin Lab: Surging Luminescent Sea. University Chemistry, 2024, 39(5): 396-404. doi: 10.3866/PKU.DXHX202312021
18. [18]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
19. [19]
  Chun-Lin Sun , Yaole Jiang , Yu Chen , Rongjing Guo , Yongwen Shen , Xinping Hui , Baoxin Zhang , Xiaobo Pan . Construction, Performance Testing, and Practical Applications of a Home-Made Open Fluorescence Spectrometer. University Chemistry, 2024, 39(5): 287-295. doi: 10.3866/PKU.DXHX202311096
20. [20]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(237)
HTML views(15)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142