Citation: WU Di, YU Zhu, GAO Da-Zhi, WANG Xin, SHEN Xuan, ZHU Dun-Ru. A Mixed-Bridged Linear Trinuclear Copper(Ⅱ) Complex Containing Both Square Pyramidal and Trigonal Bipyramidal Configuration[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1619-1625. doi: 10.11862/CJIC.2015.220 shu

A Mixed-Bridged Linear Trinuclear Copper(Ⅱ) Complex Containing Both Square Pyramidal and Trigonal Bipyramidal Configuration

WU Di ¹ ,
YU Zhu ¹ ,
GAO Da-Zhi ¹ ,
WANG Xin ¹ ,
SHEN Xuan ¹ ,
ZHU Dun-Ru ^1,2,,

1.
1. College of Chemical Engineering, State Key Laboratory of Materials-oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
2.
2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: ZHU Dun-Ru,
Received Date: 19 April 2015
Available Online: 2 June 2015
Fund Project: 国家自然科学基金资助项目(No.21171093,21476115) (No.21171093,21476115)

A novel trinuclear copper(Ⅱ) complex, [Cu₃L₂(py)](ClO₄)₂·2THF (1) (H₂L=(E)-3-[N,N-di(2-pyridylmethyl)aminomethyl]-2-hydroxyl-5-methylbenzaldehyde oxime, py=pyridine, THF=tetrahydrofuran), has been successfully synthesized and characterized. 1 crystallizes in monoclinic system with space group C2/c, a=2.969 0(7) nm, b=1.302 8(3) nm, c=2.057 4(9) nm, β=132.435(2)°, V=5.873(3) nm³, Z=4 with final R₁=0.047 9. X-ray crystallography analysis reveals that 1 is a mixed-bridged (-N-O-/μ₂-O-) linear tricopper(Ⅱ) complex with all the copper cations being five-coordinated by three N and two O atoms: the central Cu(Ⅱ) in a distorted trigonal bipyramidal configuration, whereas the peripheral Cu(Ⅱ) in a distorted square pyramidal arrangement. Magnetic susceptibility measurement indicates that there is a medium antiferromagnetic exchange coupling between the Cu(Ⅱ) ions with a J value of -33.3(5) cm^-1. CCDC: 916132.
- trinuclear copper;pentacoordinate;crystal structure;mixed-bridged;anti-ferromagnetism
1. [1]
  [1] Rivera-Carrillo M, Chakraborty I, Mezei G, et al. Inorg. Chem., 2008,47:7644-7650
2. [2]
  [2] Yang L, Powell D R, Klein E L, et al. Inorg. Chem., 2007, 46:6831-6833
3. [3]
  [3] Ávila-Torres Y, López-Sandoval H, Mijangos E, et al. Poly-hedron, 2013,51:298-306
4. [4]
  [4] Nicola C D, Garau F, Gazzano M, et al. Cryst. Growth Des., 2012,12:2890-2901
5. [5]
  [5] Ferrer S, Lloret F, Pardo E, et al. Inorg. Chem., 2012,51:985-1001
6. [6]
  [6] Nicola C D, Forlin E, Garau F, et al. J. Organomet. Chem., 2012,714:74-80
7. [7]
  [7] Qin T, Gong J, Ma J, et al. Chem. Commun., 2014,50:15886-15889
8. [8]
  [8] Hasenknopf B, Lehn J M, Baum G, et al. Proc. Natl. Acad. Sci., 1996,93:1397-1340
9. [9]
  [9] Zhao L, Thompson L K, Xu Z, et al. J. Chem. Soc., Dalton Trans., 2001:1706-1710
10. [10]
  [10] SeppäläP, Colacio E, Mota A J, et al. Dalton Trans., 2012, 41:2648-2658
11. [11]
  [11] Biswas A, Drew M G B, Gómez-García C J, et al. Inorg. Chem., 2010,49:8155-8163
12. [12]
  [12] Kannan S, Pillai M R A, Droege P A, et al. Inorg. Chim. Acta, 1997,254:397-400
13. [13]
  [13] Dey S, Sarkar S, Mukherjee T, et al. Inorg. Chim. Acta, 2011, 376:129-135
14. [14]
  [14] Singh J, Hundal G, Corbella M, et al. Polyhedron, 2007,26:3893-3903
15. [15]
  [15] Nie F M, Dong Z Y, Lu F, et al. J. Coord. Chem., 2010,63:4259-4270
16. [16]
  [16] Chen X, Zhan S, Hu C, et al. J. Chem. Soc. Dalton Trans., 1997:245-250
17. [17]
  [17] Gehring S, Fleischhauer P, Paulus H, et al. Inorg. Chem., 1993,32:54-60
18. [18]
  [18] Jiang J, Chu Z, Huang W. Inorg. Chim. Acta, 2009,362:2933-2936
19. [19]
  [19] Chen L F, Cao X Y, Li Z J, et al. Inorg. Chem. Commun., 2008,11:961-964
20. [20]
  [20] Luo W, Meng X G, Xiang J F, et al. Inorg. Chim. Acta, 2008, 361:2667-2676
21. [21]
  [21] Botana L, Ruiz J, Seco J M, et al. Dalton Trans., 2011,40:12462-12471
22. [22]
  [22] Zhu Q, Tian C, Shen C, et al. CrystEngComm, 2013,15:2120-2126
23. [23]
  [23] Silva N M L, Pinheriro C B, Chacon E P, et al. J. Braz. Chem. Soc., 2011,22:660-668
24. [24]
  [24] Sheldrick G M. Acta Crystallogr., 2008,A64:112-122
25. [25]
  [25] Addison A W, Rao T N, Reedijk J, et al. J. Chem. Soc. Dalton Trans., 1984:1349-1356
26. [26]
  [26] Lu W, Zhu D R, Xu Y, et al. Struct. Chem., 2010,21:237-244
27. [27]
  [27] CHEN Lang(陈浪), CHEN Hui-Min(程慧敏), JIANG Jing-Jing(江静静), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28:381-385
28. [28]
  [28] GAO Da-Zhi(高大志), WANG Ruo-Xu(王若徐), YE Fan(叶帆), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013, 29:2438-2444
29. [29]
  [29] Joel T, Georgina A Á, Elia P B, et al. Spectrochim. Acta A, 2007,66:879-883
30. [30]
  [30] Wang X Z, Zhu D R, Xu Y, et al. Cryst. Growth Des., 2010, 10:887-894
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