Citation: GAO Hong-Ling, BI Yan-Xia, ZHANG Qin-Qin, CUI Jian-Zhong. Syntheses and Characterizations of Two Complexes with Pyrazine-2,3,5,6-tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1603-1608. doi: 10.11862/CJIC.2015.215 shu

Syntheses and Characterizations of Two Complexes with Pyrazine-2,3,5,6-tetracarboxylic Acid

1.
Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China

Corresponding author: CUI Jian-Zhong,
Received Date: 19 March 2015
Available Online: 19 May 2015
Fund Project: 国家自然科学基金(No.21271137,21473121) (No.21271137,21473121)教育部先进能源材料化学重点实验室开放基金(南开大学)资助项目。 (南开大学)

Two complexes with pyrazine polycarboxylic acid, namely {[Cu₂(pztc)(4,4'-bpy)(H₂O)₄]·6H₂O}_n (1), {(H₂bpe)[Cd(pztc)(H₂O)₂]·2.5H₂O}_n (2), (H₄pztc=pyrazine-2,3,5,6-tetracarboxylic acid, bpe=1,2-bis(4-pyridyl)ethane, 4,4'-bpy=4,4'-bipyridine), have been prepared by modifying the reaction conditions at room temperature and characterized by IR, elemental analysis, thermal gravimetric analysis, fluorescence measurement and single crystal X-ray diffraction analysis. The structures of two complexes are two-dimensional (2D) networks, but H₄pztc has different connection modes in 1 and 2. Complex 2 shows good luminescence properties in solid state at room temperature. Electron Paramagnetic Resonance (EPR) spectra of complex 1 is studied. CCDC: 1039147, 1; 1039296, 2.
- pyrazine polycarboxylic ligand;two-dimensional network;fluorescent property;electron paramagnetic resonance spectra
1. [1]
  [1] Yaghi O M, O'Keeffe M, Ockwig N W, et al. Nature, 2003, 423:705-714
2. [2]
  [2] Chen B L, Ockwig N W, Millward A R, et al. Angew. Chem. Int. Ed., 2005,44:4745-4749
3. [3]
  [3] Albrecht M, Lutz M, Spek A. L, et al. Nature, 2000,406:970-974
4. [4]
  [4] Yang J, Yue Q, Li G D, et al. Inorg. Chem., 2006,45:2857-2865
5. [5]
  [5] Li H, Eddaoudi M, O'Keeffe M, et al. Nature, 1999,402:276-279
6. [6]
  [6] Lu J Y. Coord. Chem. Rev., 2003,246:327-347
7. [7]
  [7] Yang A H, Zou J Y, Wang W M, et al. Inorg. Chem., 2014, 53:7092-7100
8. [8]
  [8] Quan Y P, Zhao L H, Yang A H, et al. CrystEngComm, 2009, 11:1679-1685
9. [9]
  [9] Yang A H, Quan Y P, Gao H L, et al. CrystEngComm, 2009, 11:2719-2727
10. [10]
  [10] Zhao L H, Quan Y P, Yang A H, et al. CrystEngComm, 2009, 11:1427-1432
11. [11]
  [11] Yang A H, Gao H L, Cui J Z, et al. CrystEngComm, 2001, 13:1870-1876
12. [12]
  [12] Yan S T, Shi L X, Sun F F, et al. CrystEngComm, 2010,12:3437-3440
13. [13]
  [13] Yang A H, Zhang H, Gao H L, et al. Cryst. Growth Des., 2008,8:3354-3359
14. [14]
  [14] Yang A H, Zhang H, Yin P, et al. Inorg. Chem. Commun., 2010,13:1304-1308
15. [15]
  [15] Wolff L, Dtsch B. Chem. Ges., 1887,20:425-433
16. [16]
  [16] Sheldrick G M. SHELXL-97, Program for the Solution of Crystal Structures, University of Göttingen, Göttingen, Germany, 1997.
17. [17]
  [17] Wang M S, Guo S P, Li Y, et al. J. Am. Chem. Soc., 2009, 131:13572-13573
18. [18]
  [18] Kreno L E, Leong K, Farha O K, et al. Chem. Rev., 2012, 112:1105-1125
19. [19]
  [19] (a)Gan W, Jones S B, Reibenspies J H, et al. Inorg. Chim. Acta, 2005,358:3958-3966(b)Machura B, witlicka A, Nawrot I, et al. Polyhedron, 2011, 30:2815-2823
20. [20]
  [20] Gao H L, Zhang Q Q, Cheung C W, et al. Inorg. Chem. Commun., 2014,46:194-197
21. [21]
  [21] Li F F, Zhang Q Q, Zhao Y Y, et al. RSC Adv., 2014,4:10424-10433
22. [22]
  [22] Yang J, Yue Q, Li G D, et al. Inorg. Chem., 2006,45:2857-2865
23. [23]
  [23] Wang X L, Qin C, Wang E B, et al. Inorg. Chem., 2004,43:1850-1856
24. [24]
  [24] Liu H Y, Wu H, Ma J F, et al. Cryst. Growth Des., 2010,10:4795-4805
25. [25]
  [25] Zou J Y, Gao H L, Shi W, et al. CrystEngComm, 2013,15:2682-2687
26. [26]
  [26] Wang J J, Gou L, Hu H M, et al. Cryst. Growth Des., 2007, 7:1514-1521
27. [27]
  [27] Kamalakannan P, Venkappayya D. Russ. J. Coord. Chem., 2002,28:423-433
28. [28]
  [28] Kivelson D, Neiman R. J. Chem. Phys., 1961,35:149-155
1. [1]
  Jinfeng Chu , Yicheng Wang , Ji Qi , Yulin Liu , Yan Li , Lan Jin , Lei He , Yufei Song . Comprehensive Chemical Experiment Design: Convenient Preparation and Characterization of an Oxygen-Bridged Trinuclear Iron(III) Complex. University Chemistry, 2024, 39(7): 299-306. doi: 10.3866/PKU.DXHX202310105
2. [2]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
3. [3]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
4. [4]
  Chun-Lin Sun , Yaole Jiang , Yu Chen , Rongjing Guo , Yongwen Shen , Xinping Hui , Baoxin Zhang , Xiaobo Pan . Construction, Performance Testing, and Practical Applications of a Home-Made Open Fluorescence Spectrometer. University Chemistry, 2024, 39(5): 287-295. doi: 10.3866/PKU.DXHX202311096
5. [5]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . 缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望. Acta Physico-Chimica Sinica, 2025, 41(3): 2308052-. doi: 10.3866/PKU.WHXB202308052
6. [6]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
7. [7]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
8. [8]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
9. [9]
  Huanhuan XIE , Yingnan SONG , Lei LI . Two-dimensional single-layer BiOI nanosheets: Lattice thermal conductivity and phonon transport mechanism. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 702-708. doi: 10.11862/CJIC.20240281
10. [10]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
11. [11]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . 二维材料基超级电容器的容量与倍率性能提升策略. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-. doi: 10.1016/j.actphy.2025.100063
12. [12]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
13. [13]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . 铂单原子功能化的二维Al-TCPP金属-有机框架纳米片用于增强光动力抗菌治疗. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-. doi: 10.1016/j.actphy.2025.100046
14. [14]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
15. [15]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
16. [16]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
17. [17]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
18. [18]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
19. [19]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
20. [20]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . 软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(251)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses and Characterizations of Two Complexes with Pyrazine-2,3,5,6-tetracarboxylic Acid

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com