Citation: YE Qin, XIANG Jun, LI Jia-Le, LIU Min, XU Jia-Huan, SHEN Xiang-Qian. Fabrication and Microwave Absorption Properties of NZFO-PZT Magnetoelectric Composite Nanofibers[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1296-1304. doi: 10.11862/CJIC.2015.204 shu

Fabrication and Microwave Absorption Properties of NZFO-PZT Magnetoelectric Composite Nanofibers

YE Qin ¹ ,
XIANG Jun ^1,, ,
LI Jia-Le ¹ ,
LIU Min ¹ ,
XU Jia-Huan ^1,, ,
SHEN Xiang-Qian ²

1.
1 School of Mathematics and physics, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212003, China;
2.
2 School of Material Science and Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China

Corresponding author: XIANG Jun, XU Jia-Huan,
Received Date: 14 April 2015
Available Online: 29 May 2015
Fund Project: 国家自然科学基金(No.11204108) (No.11204108)中国博士后科学基金(No.2013M540418) (No.2013M540418)江苏省博士后科研资助计划(No.1301055B)资助项目。 (No.1301055B)

(1-x)Ni_0.5Zn_0.5Fe₂O₄-(x)Pb(Zr_0.52Ti_0.48)O₃ (known simply as (1-x)NZFO-(x)PZT, x=0.1, 0.2, 0.3, 0.4, and 0.5) magnetoelectric composite nanofibers have been successfully fabricated using the electrospinning method. The effects of PZT content on structures, electromagnetic characteristics and microwave absorption properties of the resultant products have been investigated in detail. It is found that all the as-prepared composites nanofibers are composed of both spinel-structured NZFO and perovskite-structured PZT phases. The appropriate incorporation of PZT phase in the composite nanofibers can improve the electromagnetic impedance matching and attenuation characteristics of the corresponding microwave absorbing coatings due to the synergistic effects between magnetic loss of NZFO and dielectric loss of PZT and the enhanced interfacial effects, and consequently boost their microwave absorption performances. The (1-x)NZFO-(x)PZT composite nanofiber/silicone microwave absorbing coatings with x=0.3 and 0.4 exhibit the strongest microwave absorption ability in the low- and high-frequency ranges, respectively. When the coating thickness is between 2.5 and 5.0 mm, the minimum reflection loss (RL) value of the x=0.3 sample is -77.2 dB at 6.1 GHz and the effective absorption bandwidth with RL below -10 dB reaches 11.2 GHz covering the 2.8~12.9 and 16.9~18 GHz frequency ranges. While for x=0.4 sample, an optimal RL value of -37.6 dB is observed at 18 GHz and the effective absorption bandwidth is up to 12.5 GHz ranging from 3.3 to 12.5 and 14.7 to 18 GHz.
- Ni-Zn ferrite;lead zirconate titanate;magnetoelectric composite nanofiber;microwave absorbing performance;synergistic effect
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