Citation: JIAO Hua-Jing, WANG Qi, DING Liu-Liu, LU Chang-Sheng. Maleonitriledithiolate Modified β-Cyclodextrin: Self-Inclusion and Response to Metal Ions[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1269-1277. doi: 10.11862/CJIC.2015.180 shu

Maleonitriledithiolate Modified β-Cyclodextrin: Self-Inclusion and Response to Metal Ions

1.
1 State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;
2.
2 Jiangsu Province Special Equipment Safety Supervision Institute (JSSEI), Nanjing 211178, China

Corresponding author: LU Chang-Sheng,
Received Date: 3 April 2015
Available Online: 11 May 2015
Fund Project: 江苏省自然科学基金(No.BK2011550)资助项目。 (No.BK2011550)

The self-inclusion of maleonitriledithiolate-modified β-Cyclodextrin (mono[6-deoxy-6-(2-butene-dinitrile-2,3-dimercapto)]-β-Cyclodextrin, 6-mnt-β-Cyclodextrin) was studied by circular dichroism (CD) spectroscopy, ¹H NMR spectroscopy, isothermal titration calorimetry (ITC), and chemical titration methods. Chemical titration results indicate that sodium dodecyl sulfate (SDS) is able to effectively dissociate the configuration of 6-mnt-β-Cyclodextrin, as well as Cu²⁺ and Co²⁺ do in solution. The experimental data suggest that 6-mnt-β-Cyclodextrin prefers self-inclusion in aqueous solution, which could be reversibly unlocked by metal ions. In its unlocked conformation, 6-mnt-β-Cyclodextrin is able to include Neutral Red (NR) and exhibits host-guest interactions. Upon removal of the "key" metal ion, 6-mnt-β-Cyclodextrin liberates the guest molecule and restores its self-inclusion. Therefore, the maleonitriledithiolate-modified cyclodextrin host exhibits potential to controllably uptake and release its guest by selected metal ion coordination.
- mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto)]-β-Cyclodextrin;circular dichroism;self-inclusion;Ada
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