Citation: ZONG Guang-Cai, REN Ning, ZHANG Jian-Jun, QI Xiao-Xia, GAO Jie, ZHANG Da-Hai. Hydrothermal Syntheses, Crystal Structures, Luminescence, Thermal Stabilities and Bacteriostatic Activities of Two Lanthanide Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(7): 1425-1432. doi: 10.11862/CJIC.2015.176 shu

Hydrothermal Syntheses, Crystal Structures, Luminescence, Thermal Stabilities and Bacteriostatic Activities of Two Lanthanide Complexes

ZONG Guang-Cai ^1,2 ,
REN Ning ^3,, ,
ZHANG Jian-Jun ^1,2,, ,
QI Xiao-Xia ^1,2 ,
GAO Jie ^1,2 ,
ZHANG Da-Hai ³

1.
1 Testing and Analysis Center, Hebei Normal University, Shijiazhuang 050024, China;
2.
2 College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China;
3.
3 College of Chemical Engineering& Material, Handan College, Handan, Hebei 056005, China

Corresponding author: REN Ning, ZHANG Jian-Jun,
Received Date: 13 March 2015
Available Online: 20 April 2015
Fund Project: 国家自然科学基金(No.21073053、21473049) (No.21073053、21473049) 河北省自然科学基金(No.B2012205022)资助项目。 (No.B2012205022)

Two lanthanide complexes [Ln(3,4-DFBA)₃(phen)(H₂O)]2(H₂O)₂ (Ln=Sm (1), Ho (2); 3,4-DFBa=3,4-difluorobenzoate, phen=1,10-phenanthroline) were prepared by hydrothermal method. Their structures were determined by single-crystal X-ray diffraction method. The structures of complexes 1 and 2 are isostructural with the coordination number of eight. They crystallized in the triclinic space group P1. The 2D layered structure is formed by intermolecular forces of adjacent two binuclear molecules. The title complexes were characterized by elemental analysis, IR, UV, XRD, and so on. The thermal stability of the complexes was tested using TG-DTG technology. The luminescent property of complex 1 had been explored. Besides, the bacteriostatic activities of the two complexes to candida albicans, Gram negative bacteria (escherichia coli) and Gram positive bacteria (staphylococcus aureus) were also studied.
- lanthanides;3,4-difluorobenzoic acid;thermal analysis;luminescence;bacteriostatic activity;crystal structure
1. [1]
  [1] Hasegawa Y, Wada Y, Yanagida S. J. Photochem. Photobiol. C, 2004, 5:183-202
2. [2]
  [2] Yang L R, Liu L, Wu L Z, et al. Dyes Pigm., 2014, 111:176-184
3. [3]
  [3] Li W X, Guo F, Zheng Y S, et al. J. Lumin., 2014, 153:421-429
4. [4]
  [4] Weissman S I. J. Chem. Phys., 1942, 10:214-217
5. [5]
  [5] Ni Y R, Tao J, Jin J Y, et al. J. Alloys Compd., 2014, 612: 349-354
6. [6]
  [6] Li L F, Dong D B, Zhang J Y, et al. Mater. Lett., 2014, 131: 298-301
7. [7]
  [7] Li W X, Feng S Y, Liu Y, et al. J. Lumin., 2013, 143:746-753
8. [8]
  [8] Lekha L, Raja K K, Rajagopal G, et al. J. Mol. Struct., 2014, 1056-1057:307-313
9. [9]
  [9] Kulkarni A, Patil S A, Badami P S. Eur. J. Med. Chem., 2009, 44:2904-2912
10. [10]
  [10] Subhan M A, Rahman M S, Alam K, et al. Spectrochim. Acta A, 2014, 118:944-950
11. [11]
  [11] Lima L M P, Delgado R, Marques F, et al. Eur. J. Med. Chem., 2010, 45:5621-5627
12. [12]
  [12] Li X, Zhang Z Y, Zou Y Q. Eur. J. Inorg. Chem., 2005, 14: 2909-2918
13. [13]
  [13] Li Y, Zheng F K, Liu X, et al. Inorg. Chem., 2006, 45:6308-6316
14. [14]
  [14] Ma D, Li X, Huo R. J. Mater. Chem. C, 2014, 43:9073-9076
15. [15]
  [15] Wang J F, Li H, Zhang J J, et al. Sci. China Ser. B Chem., 2012, 55:2161-2175
16. [16]
  [16] Yang Z H, Xu J, Zhang W X, et al. J. Solid State Chem., 2007, 180:1390-1396
17. [17]
  [17] Sheldrick G M. SHELXTL-97, Programs for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
18. [18]
  [18] Zhou X J, Zhao X Q, Wang Y J, et al. Inorg. Chem., 2014, 53:12275-12282
19. [19]
  [19] Zheng J R, Ren N, Zhang J J, et al. J. Chem. Thermodyn., 2013, 57:169-177
20. [20]
  [20] An B L, Gong M L, Li M X, et al. J. Mol. Struct., 2004, 687: 1-6
21. [21]
  [21] ZHANG Ying-Ying(张莹莹), REN Shu-Xia(任书霞), ZHANG Jian-Jun(张建军), et al. Chinese Sci. Bull.(科学通报), 2014, 59(27):3398-3405
22. [22]
  [22] Łyszczek R, Rzaczyńska Z, Kula A, et al. J. Anal. Appl. Pyrolysis, 2011, 92:347-354
23. [23]
  [23] Liu D, Yu H, Wang Z G, et al. Polym. Int., 2010, 59:937-94
24. [24]
  [24] Hang J, Xu Y H, Chen X K, et al. J. Rare Earths, 2012, 30: 586-591
25. [25]
  [25] Liu J Y, Ren N, Zhang J J, et al. Thermochim. Acta, 2013, 570:51-58
26. [26]
  [26] Zhao Y F, Chu H B, Bai F, et al. J. Organomet. Chem., 2012, 716:167-174
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
3. [3]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
4. [4]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
5. [5]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
6. [6]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
7. [7]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
8. [8]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
9. [9]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
10. [10]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
11. [11]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
12. [12]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
13. [13]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
14. [14]
  Feng Lu , Tao Wang , Qi Wang . Preparation and Characterization of Water-Soluble Silver Nanoclusters: A New Design and Teaching Practice in Materials Chemistry Experiment. University Chemistry, 2025, 40(4): 375-381. doi: 10.12461/PKU.DXHX202406005
15. [15]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
16. [16]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
17. [17]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
18. [18]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
19. [19]
  Zehua Zhang , Haitao Yu , Yanyu Qi . 多重共振TADF分子的设计策略. Acta Physico-Chimica Sinica, 2025, 41(1): 2309042-. doi: 10.3866/PKU.WHXB202309042
20. [20]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(304)
HTML views(18)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142