Citation: LI Ting, LI Xin, ZHOU Shang-Yong, TIAN Li. Copper(Ⅱ) Complexes Based on 5-Sulfoisophthalate and Bis(1,2,4-triazol-1-yl)alkanes: Syntheses, Structures, and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1215-1223. doi: 10.11862/CJIC.2015.145 shu

Copper(Ⅱ) Complexes Based on 5-Sulfoisophthalate and Bis(1,2,4-triazol-1-yl)alkanes: Syntheses, Structures, and Properties

1.
Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China

Received Date: 3 January 2015
Available Online: 14 March 2015
Fund Project: 国家自然科学基金(No.21371133) (No.21371133)天津市自然科学基金(No.12JCZDJC27600)资助项目。 (No.12JCZDJC27600)

The reaction of copper(Ⅱ) nitrate with flexible bis(1,2,4-triazol-1-yl)alkanes and rigid ligand 5-sulfoisophthalic acid monosodium salt (NaH₂sip) affords three complexes [Cu_0.5(btm)(H₂O)](H₂sip)·H₂O}_n (1, btm=bis(1,2,4-triazol-1-yl)methane), {[Cu(btp)₂(H₂sip)(H₂O)](NO₃)·4H₂O}_n (2, btp=1,3-bis(1,2,4-triazol-1-yl)propane), and {[Cu(btb)₂(Hsip)]_n (3, btb=1,4-bis(1,2,4-triazol-1-yl)butane). Compound 1 contains one-dimensional (1D) double-strained chains. Compound 2 contains two-dimensional (2D) rectangular networks with (4,4) topology, in which the 2D planar nanogrid networks stacked in a step stacking fashion.3 is also 2D layers, in which double-strained chains [Cu(btb)]_n are connected into 2D layer architectures by the μ₂-Hsip^2- linkers. The three compounds also are characterized by Elemental analysis, EPR, and thermal stability.
- bis(1,2,4-triazol-1-yl)methane;1,3-bis-(1,2,4-triazol-1-yl)propane;1,4-bis(1,2,4-triazol-1-yl)butane;5-sulfoisophthalic acid monosodium salt;supramolecular structure;hydrogen-bond interaction
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