Citation: HAO Xiao-Min, GU Chang-Sheng, JI Li-Li, LI Shi-Jie, LI Yong, SONG Wen-Dong. Syntheses and Crystal Structures of Two Ag(Ⅰ) Complexes with 2,4-Dichlorophenoxyacetic Acid and Nitrogen Heterocyclic Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 1063-1070. doi: 10.11862/CJIC.2015.143 shu

Syntheses and Crystal Structures of Two Ag(Ⅰ) Complexes with 2,4-Dichlorophenoxyacetic Acid and Nitrogen Heterocyclic Ligands

1.
1 Department of Applied Chemistry, Guangdong Ocean University, Zhanjiang, Guangdong 524088, China;
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2 Innovation & Application Institute, Zhejiang Ocean University, Zhoushan, Zhejiang 316022, China

Corresponding author: GU Chang-Sheng, SONG Wen-Dong,
Received Date: 18 January 2015
Available Online: 22 March 2015
Fund Project: 广东省自然科学基金(No.S2012020011054) (No.S2012020011054)2011年省部产学研结合引导项目(No.102011B090400415) (No.102011B090400415)2011年度湛江市第八批科技攻关计划项目(No.2011C3108001)资助。 (No.2011C3108001)

Two coordination polymers {[Ag₂(ELBA)(4,4'-bipy)₂(NO₃)]·2H₂O}_n (1) and [Ag₂(ELBA)₂(2,2'-bipy)]_n (2) were synthesized by evaporation methods using 2,4-dichlorophenoxyacetic acid(ELBA), 4,4'-dipyridyl(4,4'-bipy), 2,2'-dipyridyl(2,2'-bipy) and AgNO₃. The complexes were characterized by elemental analysis, FT-IR, thermo-gravimetrie analysis (TGA) and X-ray single-crystal structure analysis, and fluorescence properties of the complex 2 have been studied. As a result, complexes 1 and 2 are one-dimensional structure. Among others, in complex 1, Ag(Ⅰ) ion is surrounded by two nitrogen atoms from two bipy ligands form an infinite chain, and adjacent Ag-bipy chains produce “rungs” of a ladder by silver ions contacts. And in compound 2, the similar S-shape one-dimensional infinite chain is obtained by Ag…Ag interactions. Hydrogen bonding and π…π interactions were observed in these complexes.
- silver complex;2,4-dichlorophenoxyacetic acid;crystal structure
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