Citation: LIU Chun-Yan, GONG Cai-Yun, ZHOU Dong-Xue, WANG Jing, LIU Jia-Shuo, LIU Zhao-Bin. Modified Jeffamine Molecular Tools for Ordered Mesoporous and Super-Micorporous Silica Microsphere Particles[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 954-960. doi: 10.11862/CJIC.2015.139 shu

Modified Jeffamine Molecular Tools for Ordered Mesoporous and Super-Micorporous Silica Microsphere Particles

1.
1 College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China;
2.
2 State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China;
3.
3 The High School Attached to Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: LIU Chun-Yan,
Received Date: 29 January 2015
Available Online: 30 March 2015
Fund Project: 国家自然科学基金(No.21306063) (No.21306063)江苏省基础研究计划(No.BK20130123)资助项目。 (No.BK20130123)

Alow toxicity and biodegradable polymetic temlplating route to ordered mesoporous and super-micorporous silica materials is reported. By grafting stearic acid on Jeffamine ED2003 (H₂N-(PO)_l(EO)_m(PO)_n-NH₂, l+n=6, m=39), a polyether amide polymeric surfactant was obtained, which has the ability of self-assembly in aqueous solution, named ED2003-fa-18. Using ED2003-fa-18 as a template, tetraethyl orthosilicate (TEOS) as inorganic silicon source, the ordered mesoporous and super-microporous silica microspheres were hydrothermally synthesized under acidic conditions at mild temperature. The resulting materials were characterized by powder X-ray diffraction (XRD), nitrogen sorption, infrared spectroscopy (IR), 1H NMR, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The influence of the templating concentration on the pore size and morphologies of the resulting materials has been investigated. The results show that the well-ordered mesoporous and super-microporous silica materials have been successfully synthesized. As the templating concentration (from 1wt% to 7wt%) increased, the pore diameter decreased obviously from mesoporous range to supermicroporous range. SEM photographs show that the as-synthesized silica materials were spherical nanoparticles of 20~30 nm, and these nanoparticles further agglomerated and formed a densely packed microspheres of 2~4 μm. In addition, ordered pore structures can be observed by the transmission electron microscopy (TEM).
- Jeffamine polyetheramine;modification;mesoporous silica;super-microporous silica;microsphere
1. [1]
  [1] Bagshaw S A, Hayman A R. Chem. Commun., 2000(7):533-534
2. [2]
  [2] Mclnall M D, Scott J, Mercier L, et al. Chem. Commun., 2001(21):2282-2283
3. [3]
  [3] Guo X J, Hou W H, Ding W P, et al. Microporous Mesoporous Mater., 2005,80:269-274
4. [4]
  [4] Liu Y S, Lin H P, Mou C Y. Microporous Mesoporous Mater., 2004,76:203-208
5. [5]
  [5] Zhou Y, Antonietti M. Chem. Mater., 2004,16(3):544-550
6. [6]
  [6] Alexander K L Y, Falk H, Antony J W, et al. Microporous Mesoporous Mater., 2012,148:62-72
7. [7]
  [7] WEI Hao(魏昊), HAN Lu(韩路), SHI Lin(石琳), et al. Chem. J. Chinese Universities(高等学校化学学报), 2011,32(3): 503-507
8. [8]
  [8] LI Shang-Yu(李尚禹), WANG Run-Wei(王润伟), WAN Li-Feng(万利丰), et al. Chem. J. Chinese Universities(高等学校化学学报), 2008,29(3):465-467
9. [9]
  [9] HU Wen-Bin(胡文斌), CUI Ying-De(崔英德), YIN Guo-Qiang(尹国强), et al. CIESC J.(化工学报), 2009,60(8):2137-2140
10. [10]
  [10] Tian R, Sun J, Zhang H, et al. Electrophoresis, 2006,27(4): 742-748
11. [11]
  [11] GAO Feng(高峰), ZHAO Jian-Wei(赵建伟), SHUI Song(水松), et al. Chem. J. Chinese Universities(高等学校化学学报), 2002,8(23):1494-1497
12. [12]
  [12] Lin H P, Cheng Y R, Mou C Y. Chem. Mater., 1998,10: 3772
13. [13]
  [13] Park I, Wang Z, Pinnavaia T J. Chem. Mater., 2005,17:383-386
14. [14]
  [14] Park I, Pinnavaia T J. Microporous Mesoporous Mater., 2009, 118:239-244
15. [15]
  [15] Hossain K Z, Sayari A. Microporous Mesoporous Mater., 2008, 114:387-394
16. [16]
  [16] May A, Pasc A, Stebe M J, et al. Langmuir, 2012,28:9816-9824
1. [1]
  Xiaojun Liu , Lang Qin , Yanlei Yu . Dynamic Manipulation of Photonic Bandgaps in Cholesteric Liquid Crystal Microdroplets for Applications. Acta Physico-Chimica Sinica, 2024, 40(5): 2305018-0. doi: 10.3866/PKU.WHXB202305018
2. [2]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
3. [3]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-0. doi: 10.3866/PKU.WHXB202408005
4. [4]
  Yu Liu , Pengfei Li , Yize Liu , Zaicheng Sun . Recent advances in carbon dots as a single photocatalyst. Acta Physico-Chimica Sinica, 2026, 42(2): 100167-0. doi: 10.1016/j.actphy.2025.100167
5. [5]
  Ruifeng CHEN , Chao XU , Jianting JIANG , Tianshe YANG . Gold nanorod/zinc oxide/mesoporous silica nanoplatform: A triple-modal platform for synergistic anticancer therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2272-2282. doi: 10.11862/CJIC.20250117
6. [6]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
7. [7]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
8. [8]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
9. [9]
  Sumiya Akter Dristy , Md Ahasan Habib , Shusen Lin , Mehedi Hasan Joni , Rutuja Mandavkar , Young-Uk Chung , Md Najibullah , Jihoon Lee . Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting. Acta Physico-Chimica Sinica, 2025, 41(7): 100079-0. doi: 10.1016/j.actphy.2025.100079
10. [10]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
11. [11]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
12. [12]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
13. [13]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-0. doi: 10.3866/PKU.WHXB202309031
14. [14]
  Tong WANG , Qinyue ZHONG , Qiong HUANG , Weimin GUO , Xinmei LIU . Mn-doped carbon quantum dots/Fe-doped ZnO flower-like microspheres heterojunction: Construction and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1589-1600. doi: 10.11862/CJIC.20250011
15. [15]
  Chengyan Ge , Jiawei Hu , Xingyu Liu , Yuxi Song , Chao Liu , Zhigang Zou . Self-integrated black NiO clusters with ZnIn₂S₄ microspheres for photothermal-assisted hydrogen evolution by S-scheme electron transfer mechanism. Acta Physico-Chimica Sinica, 2026, 42(1): 100154-0. doi: 10.1016/j.actphy.2025.100154
16. [16]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
17. [17]
  Yue Zhang , Bao Li , Lixin Wu . GO-Assisted Supramolecular Framework Membrane for High-Performance Separation of Nanosized Oil-in-Water Emulsions. Acta Physico-Chimica Sinica, 2024, 40(5): 2305038-0. doi: 10.3866/PKU.WHXB202305038
18. [18]
  Huimin Liu , Kezhi Li , Xin Zhang , Xuemin Yin , Qiangang Fu , Hejun Li . SiC Nanomaterials and Their Derived Carbons for High-Performance Supercapacitors. Acta Physico-Chimica Sinica, 2024, 40(2): 2304026-0. doi: 10.3866/PKU.WHXB202304026
19. [19]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
20. [20]
  Huiwei Ding , Bo Peng , Zhihao Wang , Qiaofeng Han . Advances in Metal or Nonmetal Modification of Bismuth-Based Photocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2305048-0. doi: 10.3866/PKU.WHXB202305048

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(754)
HTML views(130)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142