Citation: DUAN Yan-Lin, MA Ran-Ran, CAO Ting-Ting, LIU Ting, LI Cheng-Juan, WANG Su-Na. Two Unusual 2D→3D Entanglement Networks Self-Assembled from a T-shaped Tricarboxylate Ligand: Syntheses, Structures and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (6): 1231-1238. doi: 10.11862/CJIC.2015.132 shu

Two Unusual 2D→3D Entanglement Networks Self-Assembled from a T-shaped Tricarboxylate Ligand: Syntheses, Structures and Properties

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Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252000, China

Corresponding author: LI Cheng-Juan, WANG Su-Na,
Received Date: 10 February 2015
Available Online: 26 March 2015
Fund Project: 国家自然科学基金(No.20801025) (No.20801025)山东省自然科学基金(No.ZR2012BQ023) (No.ZR2012BQ023)山东省高等学校科技计划项目(No.J14LC10)资助。 (No.J14LC10)

Two Ni(Ⅱ)-organic frameworks, namely, {[Ni₃(BPT)₂(bpe)₂(H₂O)₆]·2DMF·7H₂O}_n (1) and {[Ni₃(BPT)₂(bpea)₂(H₂O)₆]·2DMF·5H₂O}_n (2) (H₃BPT = biphenyl-3,4',5-tricarboxylic acid, bpe = 1,2-bis(4-pyridyl)ethylene, bpea=1,2-bis(4-pyridyl)ethane, DMF=N,N-dimethylformamide), were solvothermally synthesized and characterized. In the two isostructural complexes, BPTligand and N-containing ligand bpea or bpe connect adjacent Ni centers to form a bilayer structure. The whole topology could be represented as (3,4)-connected (63)(65.8) with the tricarboxylate ligands and Ni atoms as 3-connected T-shaped and 4-connected tetrahedral nodes, respectively. Each bilayer polycatenates two other identical bilayers, giving rise to a 2D→3D polycatenating network with polyrotaxane moieties. Gas adsorptive measurements indicated compound 1 exhibited adsorption of CO₂ and N₂.
- metal-organic framework;polycatenating;biphenyl-3,4',5-tricarboxylic acid
1. [1]
  [1] Li M, Li D, Yaghi O M, et al. Chem. Rev., 2014,114:1343-1370
2. [2]
  [2] Mason J A, Veenstra M, Long J R. Chem. Sci., 2014,5:32-51
3. [3]
  [3] Zhao M, Ou S, Wu C D. Acc. Chem. Res., 2014,47:1199-1207
4. [4]
  [4] Cook T R, Zheng Y R, Stang P J. Chem. Rev., 2013,113:734 -777
5. [5]
  [5] Xuan W M, Zhu C F, Cui Y, et al. Chem. Soc. Rev., 2012, 41:1677-1695
6. [6]
  [6] Zhao D, Timmons D J, Yuan D Q, et al. Acc. Chem. Res., 2011,44:123-133
7. [7]
  [7] Batten S R, Robson R. Angew. Chem. Int. Ed., 1998,37:1461 -1494
8. [8]
  [8] Batten S R. CrystEngComm, 2001,3:67-72
9. [9]
  [9] Carlucci L, Ciani G, Proserpio D M. Coord. Chem. Rev., 2003,246:247-289
10. [10]
  [10] Wang X L, Qin C, Wang E B, et al. Carlucci L. Angew. Chem. Int. Ed., 2005,44:5824-5827
11. [11]
  [11] Chen H Y, Xiao D R, He J H, et al. CrystEngComm, 2011, 13:4988-5000
12. [12]
  [12] Yang Y, Du P, Liu Y Y, et al. Cryst. Growth Des., 2013,13: 4781-4795
13. [13]
  [13] Yang J, Ma J F, Batten S R, et al. Chem. Commun., 2008: 2233-2234
14. [14]
  [14] Wu H, Liu B, Yang J, et al. CrystEngComm, 2011,13:3661-3664
15. [15]
  [15] Cui Y F, Sun P P, Chen Q, et al. CrystEngComm, 2012,14: 4161-4164
16. [16]
  [16] Sun G M, Song Y M, Liu Y, et al. CrystEngComm, 2012,14: 5714-5716
17. [17]
  [17] Qin C, Wang X L, Wang E B, et al. Inorg. Chem., 2008,47: 5555-5557
18. [18]
  [18] Ma Y, Ceng A L, Gao E Q. Cryst. Growth Des., 2010,10: 2832-2834
19. [19]
  [19] Liu Y Y, Wang Z H, Yang J, et al. CrystEngComm, 2011, 13:3811-3821
20. [20]
  [20] Gao J Z, Yang J, Liu Y Y, et al. CrystEngComm, 2012,14: 8173-8175
21. [21]
  [21] Hu F L, Wu W, Liang P, et al. Cryst. Growth Des., 2013,13: 5050-5061
22. [22]
  [22] Blatov V A, Carlucci L, Ciani G, et al. CrystEngComm, 2004,6:377-395
23. [23]
  [23] Baburin I A, Blatov V A, Carlucci L, et al. J. Solid State Chem., 2005,178:2471-2493
24. [24]
  [24] Guo H D, Qiu D F, Guo X M, et al. CrystEngComm, 2009, 11:2611-2614
25. [25]
  [25] Liu F Q, Tilley T D. Inorg. Chem., 1997,36:5090-5096
26. [26]
  [26] Cao T T, Peng Y Q, Liu T, et al. CrystEngComm, 2014,16: 10658-10673
27. [27]
  [27] Wang S N, Yun R R, Wang D Q, et al. Cryst. Growth Des., 2012,12:79-92
28. [28]
  [28] Wang S N, Wang D Q, Dou J M, et al. Acta Cryst. C, 2010, 66:m141-m144
29. [29]
  [29] Wang S N, Li D C, Dou J M, et al. Acta Cryst. C, 2010,66: m118-m121
30. [30]
  [30] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
31. [31]
  [31] Sheldrick G M. SHELXL-97, Program for Refining Crystal Structure, University of Göttingen, Germany, 1997.
32. [32]
  [32] Dolomanov O. Olex Updated. University of Nottingham, UK, 2005.
33. [33]
  [33] Kondo M, Yoshitomi T, Seki K, et al. Angew. Chem. Int. Ed. Engl., 1997,36:1725-1727
34. [34]
  [34] Yaghi O M, Li H L. J. Am. Chem. Soc., 1996,118:295-296
35. [35]
  [35] Power K N, Hennigar T L, Zaworotko M J. New. J. Chem., 1998,22:177-181
36. [36]
  [36] Fu Z Y, Wu X T, Dai J C, et al. New. J. Chem., 2002,26: 978-980
37. [37]
  [37] Ji C C, Li J, Li Y Z, et al. CrystEngComm, 2011,13:459-466
38. [38]
  [38] Spek A L. J. Appl. Cryst., 2003,36:7-13
39. [39]
  [39] Li J R, Ma Y G, McCarthy M C, et al. Coord. Chem. Rev., 2010,255:1791-1823
40. [40]
  [40] Zhang Y J, Liu T, Kanegawa S J, et al. J. Am. Chem. Soc., 2010,132:912-913
41. [41]
  [41] Xiang H, Gao W Y, Zhong D C, et al. CrystEngComm, 2011, 13:5825-5832
42. [42]
  [42] Chen M S, Chen M, Takamizawa S, et al. Chem. Commun., 2011,47:3787-3789
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