Citation: ZHANG Xiao-Ge, GAO Lou-Jun, CHEN Xiao-Li, CUI Hua-Li, MA Hong-Yan. Syntheses, Crystal Structures and Fluorescent Properties of Zinc/Cadmium Complexes Based on Tetranuclear Metal Unit[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 739-748. doi: 10.11862/CJIC.2015.110 shu

Syntheses, Crystal Structures and Fluorescent Properties of Zinc/Cadmium Complexes Based on Tetranuclear Metal Unit

1.
Shaanxi Key Laboratory of Chemical Reaction Engineering, Department of Chemistry and Chemical Engineering, Yanan University, Yanan, Shaanxi 716000, China

Corresponding author: GAO Lou-Jun, CHEN Xiao-Li,
Received Date: 28 October 2014
Available Online: 14 January 2014
Fund Project: 国家自然科学基金(No.21101133) (No.21101133) 陕西省自然科学基础研究计划项目(No.2014JM2056)资助。 (No.2014JM2056)

Two complexes, Zn₄(Hhpa)₄(phen)₄ (1) and {[Cd₈(cnam)₂(bpy)₄(C₂O₄)₆(H₂O)₈]·2H₂O}_n(2) (H₂hpa=2-hydroxy-isophthalic acid, phen=phenanthroline, H₂cnam=4-oxo-4H-pyran-2,6-dicarboxylic acid and bpy=2,2'-bipyridyl), were synthesized under hydrothermal conditions and were characterized by elemental analysis, IR spectrum, single-crystal X-ray diffraction, Fluorescence, TGA and XRD. Complex 1 shows a cyclic tetranuclear structure. The neighboring tetranuclear structures are linked into 3D supramolecular network through π…π stacking interactions. While complex 2 is unprecedented 3D polymer based on tetranuclear cadmium clusters cross-linked by C₂O₄^2- ions and cnam^2- ligands. In 1 and 2, Hhpa^2-, cnam^2- ligand and C₂O₄^2- ion display colorful coordination modes. In addition, the thermal stabilities and luminescence properties of 1 and 2 were also studied. CCDC:1024511, 1; 1024510, 2.
- zinc/cadmium complexes;crystal structure;hydrothermal synthesis;luminescence
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