Citation: JING Xu, YANG Lin-Lin, CHANG Zhi-Duo, HE Cheng, DUAN Chun-Ying. Photocatalytic Hydrogen Production from Water Using Cobalt-Thiosemicarbazone Complex as Redox Catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 975-980. doi: 10.11862/CJIC.2015.090 shu

Photocatalytic Hydrogen Production from Water Using Cobalt-Thiosemicarbazone Complex as Redox Catalyst

1.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: DUAN Chun-Ying,
Received Date: 30 October 2014
Available Online: 3 February 2015
Fund Project: 国家自然科学基金(No.21471075) (No.21471075)973项目(No.2011CB808704)资助。 (No.2011CB808704)

By incorporating a phosphine donor within a thiosemicarbazone moiety to enhance the coordinated ability of the chelators, a cobalt complex Co-NSP (HNSP: 4-[2-(2-diphenylphosphino-benzylidene) thiosemicar-bohydrazone]benzenesulfonate) was obtained as the proton reduction catalyst for light driven H₂ evolution in homogeneous environment with fluorescein as the photosensitizer. The presence of NSP tridentate chelator benefits the formation of low oxidized species to increase the catalytic efficiency, and the incorporation of a sulfonate group enhances the water solubility of the catalyst. The amount of H₂ generation in 12 h photolysis maximizes in the presence of sacrificial reagent NEt₃ at pHvalue of 11.0. The initial TOF (turnover frequency) is about 200 mol H₂ per mole catalyst per hour with the turnover number (TON) about 2000 mol H₂ per mole of catalyst.
- thiosemicarbazone;cobalt complex;photocatalytic hydrogen ecolution;nsp tridentate chelator
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沈阳化工大学材料科学与工程学院沈阳 110142