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Citation: YANG Dai-Sheng, XU Li-Hua, CHEN Hui, ZHANG Li-Fang, NI Zhong-Hai, WANG Wen-Feng. Synthesis, Crystal Structure and Magnetic Properties of a One-Dimensional Cyanide-Bridged CrⅢ-CuⅡ Complex {[Cu(cyclam)][Cr(bpb)(CN)2]2·2H2O}n[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 565-570. doi: 10.11862/CJIC.2015.089 shu

Synthesis, Crystal Structure and Magnetic Properties of a One-Dimensional Cyanide-Bridged CrⅢ-CuⅡ Complex {[Cu(cyclam)][Cr(bpb)(CN)2]2·2H2O}n

  • 1.

    1 School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China;

  • 2.

    2 School of Resources and Geosciences, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China

  • Corresponding author: NI Zhong-Hai, 
  • Received Date: 18 September 2014
    Available Online: 10 January 2015

    Fund Project: 江苏省高校优势学科建设工程项目和中央高校基本科研业务费专项资金资助项目(No.2014ZDPY25)。 (No.2014ZDPY25)

  • A one-dimensional cyanide-bridged CrⅢ-CuⅡ complex {[Cu(cyclam)][Cr(bpb)(CN)2]2·2H2O}n (cyclam=1, 4,8, 11-tetraazacyclotetradecane, bpb2-=1,2-bis(pyridine-2-carboxamido)-benzenate) (1) has been synthesized by the reaction of building blocks [Cu(cyclam)](ClO4)2 and K[Cr(bpb)(CN)2]. Single crystal X-ray diffraction analysis reveals that complex 1 crystallizes in triclinic space group P1 with a=0.966 73(19) nm, b=1.345 1(3) nm, c= 1.382 0(3) nm, α=77.12(3)°, β=76.93(3)°, γ=82.02(3)°, V=1.699 1(6) nm3, Z=2, Dc=1.567 g·cm-3, μ=1.086 mm-1, F(000)=828, R1=0.041 3, wR2=0.120 0, the structure of complex 1 is a type of polymer with two different metal centers which are alternatively linked by cyanide group. Magnetic investigations indicate that complex 1 exhibits a weak ferromagnetic coupling between CrⅢ and CuⅡ centers through the cyanide bridge.
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