Citation: HAN Li-Feng, ZHANG Wei, LU Mo-Hong, LI Ming-Shi, SHAN Yu-Hua. Chemoselective Hydrogenolysis of Tetrahydrofurfuryl Alcohol to 1,5-Pentanediol over Mo Modified Rh/AC (Rh-MoO_x/AC) Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 297-302. doi: 10.11862/CJIC.2015.056 shu

Chemoselective Hydrogenolysis of Tetrahydrofurfuryl Alcohol to 1,5-Pentanediol over Mo Modified Rh/AC (Rh-MoO_x/AC) Catalysts

1.
Key Lab of Fine Chemical Engineering, Jiangsu, School of Petrochemical Engineering, Changzhou University, Changzhou, 213164, China

Corresponding author: LI Ming-Shi,
Received Date: 16 September 2014
Available Online: 1 December 2014
Fund Project: 国家自然科学基金(No.21307009) (No.21307009)江苏省高校自然科学基础研究项目(No.12KJB530001)资助项目 (No.12KJB530001)

Selective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol was investigated over Mo modified Rh/AC (Rh-MoO_x/AC) catalysts. The Rh-MoO_x/ACcatalysts were characterized by TEM, XPSand microcalorimetry of NH₃ adsorption. The reaction conditions of the hydrogenolysis were optimized. The results show that the medium strength acid site, provided by MoO_x with lower oxidation state by doping molybdenum, is the main factor for improving the catalytic activity. The optimized reaction conditions are catalyst-Rh-MoO_x/ACwith molar ratio n_Mo/n_Rh of 0.15, reduction temperature of 550 ℃, reaction temperature of 120 ℃, reaction pressure of 8 MPa, reaction time of 10 h and using water as the solvent,. Under these conditions, 64% conversion of tetrahydrofurfuryl alcohol with selectivity of almost 100% toward 1,5-pentanediol is obtained.
- catalysis;catalyst preparation;catalytic hydrogenation;Rh-MoO_x/AC catalyst;tetrahydrofurfuryl alcohol;1,5-pentanediol
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Chemoselective Hydrogenolysis of Tetrahydrofurfuryl Alcohol to 1,5-Pentanediol over Mo Modified Rh/AC (Rh-MoOx/AC) Catalysts

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通讯作者: 陈斌, bchen63@163.com

Chemoselective Hydrogenolysis of Tetrahydrofurfuryl Alcohol to 1,5-Pentanediol over Mo Modified Rh/AC (Rh-MoO_x/AC) Catalysts