Citation: JI Ke-Ming, MENG Fan-Hui, GAO Yuan, LI Zhong. Solution Combustion Prepared Ni-Based Catalysts and Their Catalytic Performance for Slurry Methanation[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 267-274. doi: 10.11862/CJIC.2015.050 shu

Solution Combustion Prepared Ni-Based Catalysts and Their Catalytic Performance for Slurry Methanation

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Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: LI Zhong,
Received Date: 4 August 2014
Available Online: 7 November 2014
Fund Project: 国家"973"计划(No.2012CB723105) (No.2012CB723105)山西省青年基金(No.2013021007-4) (No.2013021007-4)中国博士后科学基金(2013M541210) (2013M541210)太原理工大学校青年团队基金(No.2013T091)资助项目 (No.2013T091)

Ni-Al₂O₃, Ni-ZrO₂, Ni-La₂O₃ and Ni-CeO₂ catalysts were prepared by solution combustion method using Al(NO₃)₃, ZrO(NO₃)₂, La(NO₃)₃ and Ce(NO₃)₃ (mixed with Ni(NO₃)₂ and urea in aqueous solution) as the support precursor, respectively. The COmethanation performances of catalysts were studied in slurry-bed reactor, and the catalysts were characterized by low temperature N₂ adsorption-desorption, XRD, SEM, TEM, H₂-TPRand H₂ chemsorption. The results show that the combustion preparation process of Ni-Al₂O₃ catalyst using Al(NO₃)₂ as the precursor is stable for long-duration(up to 23 s) and the catalyst has larger surface area (468 m²·g^-1) and metal surface area (10 m²·g^-1), smaller Ni particle (3~5 nm), excellent dispersion of Ni, and the catalyst has good catalytic performance, whose COconversion and CH₄ selectivity are 94% and 95%, respectively, and no catalyst deactivation is observed in 100h. The preparation process for catalysts using ZrO(NO₃)₂ and La(NO₃)₃ as precursors does not show obvious flame and burning time is also shorter (12 s and 5 s), the surface areas, metal surface areas and catalytic performances are lower than that of Ni-Al₂O₃ while that for the catalyst using Ce(NO₃)₂ as the precursor has high intensity combustion. The catalyst obtained from Ce(NO₃)₂ precursor shows lower surface area (22 m²·g^-1) and metal surface area (5 m²·g^-1), larger Ni particle and worse dispersion of Ni and the worst methanation catalytic performance with COconversion and CH₄ selectivity of 41% and 89%, respectively.
- catalysis;catalyst prepration;slurry-bed reactor;CO methanantion;solution combustion method;Ni-based catalyst;support
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沈阳化工大学材料科学与工程学院沈阳 110142