Citation: PAN Xu-Chen, TANG Jing, XUE Hai-Rong, GUO Hu, FAN Xiao-Li, ZHU Ze-Tao, HE Jian-Ping. Synthesis and Electrocatalytic Performance of N-Doped Ordered Mesoporous Carbon-Ni Nanocomposite[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 282-290. doi: 10.11862/CJIC.2015.039 shu

Synthesis and Electrocatalytic Performance of N-Doped Ordered Mesoporous Carbon-Ni Nanocomposite

1.
College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

Corresponding author: HE Jian-Ping,
Received Date: 12 August 2014
Available Online: 5 November 2014
Fund Project: 国家自然科学基金(No.51372115)资助项目 (No.51372115)

Highly ordered mesoporous carbon co-modified with Ni-Ncan be prepared via homogeneous phase route as well as dual-phase route, named as Ni-N-OMC-1 and Ni-N-OMC-2 respectively. Triblock copolymer Pluronic F127 were employed as the template agent, urea as the Nprecursor, NiCl₂ as the Ni source and resorcinol-formaldehyde resin as the carbon precursor. X-ray diffraction (XRD), Raman, and transmission electron microscope (TEM) showed that nickel particles dispersed in the carbon matrix in forms of metal nickel, in situ catalyzing the graphitization of amorphous carbon. X-ray photoelectron spectroscopy (XPS) revealed that urea existed in four different Nspecies after heat treatment: sp³ nitrogen atoms bonded to carbon atoms, pyridine-like N, sp³ nitrogen atoms bonded to carbon atoms and quaternary-Natoms. The co-modification of nitrogen and nickel changed the physicochemical properties of carbon matrix, thus making for the loading and dispersing of Pt. Pt nanoparticles deposited on Ni-N-OMC-1 nanocompsite showed excellent electrocatalytic activity. The electrochemical active surface area of hydrogen oxidation was 138.53 m²·g^-1 and the limiting current density in ORRwas 5.32 mA·cm^-2, which indicated higher electrocatalytic ability than that of the commercial 20% Pt/Ccatalysts (4.49 mA·cm^-2, 96.98 m²·g^-1).
- homogeneous phase route;dual-phase route;ordered mesoporous carbon;co-modified with Ni-N;electrocatalytic activity
1. [1]
  [1] WANG Dao-Jun(王道军), WANG Tao(王涛), ZHOU Jian-Hua(周建华), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010,26(2):305-312
2. [2]
  [2] Wang J C, Liu Q. J. Phys. Chem. C, 2007,111(20):266-7272
3. [3]
  [3] Zhao X C, Wang A, Yan J W, et al. Chem. Mater., 2010,22 (19):5463-5473
4. [4]
  [4] Liang C D, Dudney N J, Howe J Y. Chem. Mater., 2009,21 (19):4724-4730
5. [5]
  [5] Li Z L, Liu J H, Xia C G, et al. ACS Catal., 2013,3(11):2440-2448
6. [6]
  [6] Datta K K R, Balasubramanian V V, Ariga K, et al. Chem. Eur. J., 2011,17(12):3390-3397
7. [7]
  [7] Wickramaratne N P, Perera V S, Park B W, et al. Chem. Mater., 2013,25(14):2803-2811
8. [8]
  [8] Lu A H, Li W C, Salabas E L, et al. Chem. Mater., 2006,18 (8):2086-2094
9. [9]
  [9] Chen Z, Weng D, Sohn H, et al. RSC Adv., 2012,2(5):1755-1758
10. [10]
  [10] TANG Jing(汤静), WANG Tao(王涛), HE Jian-Ping(何建平), et al. Acta Chim. Sinica(化学学报), 2011,69(15):1751-1759
11. [11]
  [11] Tang J, Wang T, Pan X C, et al. J. Phys. Chem. C, 2013, 117(33):16896-16906
12. [12]
  [12] Wang X Q, Liang C D, Dai S. Langmuir, 2008,24(14):7500-7505
13. [13]
  [13] Meng Y, Gu D, Zhang F Q, et al. Angew. Chem., 2005,117 (43):7215-7221
14. [14]
  [14] Wei Z Q, Xia T D, Ma J. Mater. Charact., 2007,58(10):1019-1024
15. [15]
  [15] Jia N Q, Wang Z Y, Yang G F, et al. Electrochem. Commun., 2007,9(2):233-238
16. [16]
  [16] Shao Y Y, Yin G P, Gao Y Z. J. Power Sources, 2007,171 (2):558-566
17. [17]
  [17] Yu X W, Ye S Y. J. Power Sources, 2007,172(1):145-154
18. [18]
  [18] Liu S H, Wu M T, Lai Y H, et al. Mater. Chem., 2011,21 (33):12489-12496
19. [19]
  [19] Yao J Y, Li L X, Song H H, et al. Carbon, 2009,47(2):436-444
20. [20]
  [20] Li Q, Yang J P, Feng D, et al. Nano Res., 2010,3(9):632-642
21. [21]
  [21] Moncoffre N, Hollinger G, Jaffrezic H, et al. Nucl. Instrum. Meth. B, 1985,7-8(1):177-183
22. [22]
  [22] Wang P F, Takeno T, Adachi K, et al. Appl. Surf. Sci., 2012,258(17):6576-6582
23. [23]
  [23] Geng D S, Hu Y H, Li Y L, et al. Electrochem. Commun., 2012,22:65-68
24. [24]
  [24] Delpeux S, Beguin F, Benoit R, et al. Eur. Polym., 1998,34 (7):905-915
25. [25]
  [25] Lahaye J, Nansé G, Bagreev A, et al. Carbon, 1999,37(4): 585-590
26. [26]
  [26] Yang D S, Kim C, Song M Y, et al. J. Phys. Chem. C, 2014, 118(30):16694-16702
27. [27]
  [27] Shao Y Y, Sui J H, Yin G P, et al. Appl. Catal. B: Environ., 2008,79(1):89-99
28. [28]
  [28] SHI Guo-Yu(史国玉), WANG Zong-Hua(王宗花), XIA Jian-Fei(夏建飞), et al. Acta Chim. Sinica(化学学报), 2013,71 (02):227-233
29. [29]
  [29] Liu R L, Wu D Q, Feng X L, et al. Angew. Chem., 2010, 122(14):2619-2623
30. [30]
  [30] Yue B, Ma Y W, Tao H S, et al. J. Mater. Chem., 2008,18 (15):1747-1750
31. [31]
  [31] Liu H, Guo R X, Liu Y, et al. Surf. Coat. Technol., 2012, 206(15):3350-3359
32. [32]
  [32] Prieto P, Nistor V, Nouneh K, et al. Appl. Surf. Sci., 2012, 258(22):8807-8813
33. [33]
  [33] WANG Bo(王博), ZHANG Jian-Min(张建民), LU Yan-Dong (路彦冬), et al. Acta Phys. Sin.(物理学报), 2011,60(1):506-514
34. [34]
  [34] Zhou J H, He J P, Ji Y J, et al. Electrochim. Acta, 2007,52 (14):4691-4695
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