Citation: XU Feng-Qin, HU Xiao-Fei, CHENG Fang-Yi, LIANG Jing, TAO Zhan-Liang, CHEN Jun. Preparation of Porous Carbon-Supported Ni Nanoparticles for Catalytic Hydrogen Generation from Ammonia Borane Hydrolysis[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 103-108. doi: 10.11862/CJIC.2015.032 shu

Preparation of Porous Carbon-Supported Ni Nanoparticles for Catalytic Hydrogen Generation from Ammonia Borane Hydrolysis

1.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering, College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: CHENG Fang-Yi,
Received Date: 22 July 2014
Available Online: 3 October 2014
Fund Project: 863项目(No.2012AA051503) (No.2012AA051503)国家自然科学基金(No.51101089,51371100,51271094) (No.51101089,51371100,51271094)973项目(No.2011CB631301) (No.2011CB631301)

Honeycomb-like hierarchical porous carbon was prepared and employed as substrate to support nickel nanparticles via an impregnation-chemical reduction method. The synthesized carbon-supported nickel (denoted as Ni/C) was used as catalysts for hydrogen generation from hydrolysis of ammonia borane (AB). Results of XRD, BET, SEM, Raman, and TEM measurements showed that the synthesized carbon possessed high specific surface area of 737 m²·g^-1 and partially graphited structure; the supported amorphous Ni nanoparticles had an average particle size of 10 nm and were uniformly dispersed on the porous carbon substrate. The synthesized Ni/C exhibited high catalytic activity towards the hydrolysis of AB. At hydrolysis temperature of 298 K, Ni/C with 30wt% Ni loading was the most active, resulting in a high hydrogen release rate of 1304.67 mL·min^-1·g^-1 and a low activation energy of 29.1 kJ·mol^-1. In addition, the Ni/C catalyst could be repeatedly utilized with respectable activity reservation for several times. The results indicate that Ni/C is a promising low-cost catalyst for hydrolytic dehydrogenation of AB.
- hierarchical porous carbon;carbon-supported Ni;ammonia borane;hydrolysis;hydrogen generation
1. [1]
  [1] Liu C, Fan Y Y, Liu M, et al. Science, 1999,286:1127-1129
2. [2]
  [2] TANG Xiao-Ming(唐晓鸣), LIU Ying-Liang(刘应亮). Chinese J. Inorg. Chem.(无机化学学报), 2001,17(2):161-167
3. [3]
  [3] Yang L, Su J, Luo W, et al. Int. J. Hydrogen Energy, 2014, 39:3360-3370
4. [4]
  [4] Zhang T R, Yang X J, Yang S Q, et al. Phys. Chem. Chem. Phys., 2011,13:18592-18599
5. [5]
  [5] Yang X J, Cheng F Y, Liang J, et al. Int. J. Hydrogen Energy, 2009,34:8785-8791
6. [6]
  [6] WU Guo-Tao(吴国涛), CHEN Wei-Dong(陈维东), XIONG Zhi-Tao(熊智涛). Chinese Journal of Nature(自然杂志), 2011,33(1):27-34
7. [7]
  [7] ZOU Shao-Shuang(邹少爽), TAO Zhan-Liang(陶占良), CHEN Jun(陈军). Acta Chim. Sinica(化学学报), 2011,69(18):2117-2122
8. [8]
  [8] TAO Zhan-Liang (陶占良), PENG Bo(彭博), LIANG Jing(梁静), et al. Materials China(中国材料进展), 2009,28(Z1):26-40
9. [9]
  [9] Graham T W, Tsang C W, Chen X H, et al. Angew. Chem. Int. Ed., 2010,49:8708-8711
10. [10]
  [10] HUANG Ren-Zhong(黄仁忠), YANG Wen-Jing(杨文静), LIU Liu(刘柳), et al. Journal of Shenyang Normal University: Natural Science(沈阳师范大学学报:自然科学版), 2011, 29(3):395-398
11. [11]
  [11] Cao N, Su J, Luo W, et al. Int. J. Hydrogen Energy, 2014, 39:426-435
12. [12]
  [12] Yang X J, Cheng F Y, Tao Z L, et al. J. Power Sources, 2011,196:2785-2789
13. [13]
  [13] Luo W, Campbell P G, Zakharov L N, et al. J. Am. Chem. Soc., 2011,133:19326-19329
14. [14]
  [14] Chandra M, XU Q. J. Power Sources, 2007,168:135-142
15. [15]
  [15] Zhao J Z, Ma H, Chen J. Int. J. Hydrogen Energy, 2007,30: 4711-4716
16. [16]
  [16] Umegaki T, Yan J M, Zhang X B, et al. Int. J. Hydrogen Energy, 2009,34:3816-3822
17. [17]
  [17] Li P Z, Aijaz A, Xu Q. Angew. Chem. Int. Ed., 2012,51: 6753-6756
18. [18]
  [18] Du J, Cheng F Y, Si M, et al. Int. J. Hydrogen Energy, 2013,38:5768-5774
19. [19]
  [19] Cao N, Luo W, Cheng G Z. Int. J. Hydrogen Energy, 2013, 38:11964-11972
20. [20]
  [20] Yang X J, Cheng F Y, Liang J, et al. Int. J. Hydrogen Energy, 2011,36:1984-1990
21. [21]
  [21] Yan J M, Zhang X B, Han S, et al. Inorg. Chem., 2009,48: 7389-7393
22. [22]
  [22] Umegaki T, Yan J M, Zhang X B, et al. J. Power Sources, 2009,191:209-216
23. [23]
  [23] WU Xue-Yan(吴雪艳), WANG Kai-Xue(王开学), CHEN Jie-Sheng(陈接胜). Prog. Chem.(化学进展), 2012,24(Z1): 262-274
24. [24]
  [24] CHENG Ji-Peng(程继鹏), ZHAN Xiao-Bin(张孝彬). Chinese J. Inorg. Chem.(无机化学学报), 2006,22(5):967-970
25. [25]
  [25] Qiu F Y, Li L, Liu G, et al. Int. J. Hydrogen Energy, 2013, 38:3041-3049
26. [26]
  [26] Zhao J Z, Cheng F Y, Yi C H, et al. J. Mater. Chem., 2009, 19:4108-4116
27. [27]
  [27] Yamada H, Nakamura H, Nakahara F, et al. J. Phys. Chem. C, 2007,111:227-233
28. [28]
  [28] Kruk M, Jaroniec M. Chem. Mater., 2001,13:3169-3183
29. [29]
  [29] Tuinstra F, Koenig J. J. Chem. Phys., 1970,53:1126-1130
30. [30]
  [30] Ozaya O, Ingerb E, Aktasc N, et al. Int. J. Hydrogen Energy, 2011,36:8209-8216
1. [1]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
2. [2]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
3. [3]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
4. [4]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
5. [5]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
6. [6]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
7. [7]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
8. [8]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
9. [9]
  Ping Ye , Lingshuang Qin , Mengyao He , Fangfang Wu , Zengye Chen , Mingxing Liang , Libo Deng . 荷叶衍生多孔碳的零电荷电位调节实现废水中电化学捕集镉离子. Acta Physico-Chimica Sinica, 2025, 41(3): 2311032-. doi: 10.3866/PKU.WHXB202311032
10. [10]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
11. [11]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
12. [12]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
13. [13]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
14. [14]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
15. [15]
  Lei Shu , Zimin Duan , Yushen Kang , Zijian Zhao , Hong Wang , Lihua Zhu , Hui Xiong , Nan Wang . An Exploration of the CO₂-Involved Carbon Cycle World. University Chemistry, 2024, 39(5): 144-153. doi: 10.3866/PKU.DXHX202309084
16. [16]
  Lei Shu , Zhengqing Hao , Kai Yan , Hong Wang , Lihua Zhu , Fang Chen , Nan Wang . Development of a Double-Carbon Related Experiment: Preparation, Characterization and Carbon-Capture Ability of Eggshell-Derived CaO. University Chemistry, 2024, 39(4): 149-156. doi: 10.3866/PKU.DXHX202310134
17. [17]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
18. [18]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
19. [19]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
20. [20]
  Lubing Qin , Fang Sun , Meiyin Li , Hao Fan , Likai Wang , Qing Tang , Chundong Wang , Zhenghua Tang . 原子精确的(AgPd)₂₇团簇用于硝酸盐电还原制氨：一种配体诱导策略来调控金属核. Acta Physico-Chimica Sinica, 2025, 41(1): 2403008-. doi: 10.3866/PKU.WHXB202403008

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(572)
HTML views(68)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142