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Citation: AN Ting, ZHAO Feng-Qi, MA Hai-Xia, REN Xiao-Ning, ZHAO Ning-Ning, WANG Qiong, YANG Yong. MnO2 Nanotube and Its Super Thermite: Preparation and Their Effect on Thermal Decomposition of Cyclotrimethylene Trinitramine[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 97-102. doi: 10.11862/CJIC.2015.010 shu

MnO2 Nanotube and Its Super Thermite: Preparation and Their Effect on Thermal Decomposition of Cyclotrimethylene Trinitramine

  • 1.

    1. Science and Technology on Combustion and Explosion Laboratory, Xi'an Modern Chemistry Research Institute, Xi'an 710065, China;

  • 2.

    2. Department of Chemical Engineering, Northwest University, Xi'an 710069, China;

  • 3.

    3. Department of Chemistry, Tsinghua University, Beijing 100084, China

  • Corresponding author: ZHAO Feng-Qi, 
  • Received Date: 20 July 2014
    Available Online: 25 September 2014

    Fund Project: 国家自然科学基金(No.21173163) (No.21173163)燃烧与爆炸技术重点实验室基金(No.9140C350302120C3501)资助项目 (No.9140C350302120C3501)

  • The nano-MnO2 was prepared by hydrothermal method, and then super thermite Al/MnO2 was prepared by ultrasonic dispersion method using nano-MnO2 and Al nanoparticles as raw materials. The physical phase, composition, morphology and structure of products were characterized by X-ray diffraction (XRD) and scanning electron microscope-energy dispersive spectrometer (SEM-EDS). The catalytic effect of MnO2 nanotube and the super thermite on the thermal decomposition of cyclotrimethylene trinitramine were investigated by differential scanning colorimetry (DSC). The results indicate that nano-MnO2 is in tubular structure, and the globose nano-Al particles are homodispersed on the surface of MnO2 nanotube. MnO2 nanotube and its super thermite influence the thermal decomposition behavior and decomposition process of cyclotrimethylene trinitramine. They can change the primary decomposition of liquid phase to the reaction of secondary gas phase and can change the shape of main decomposition peak obviously.
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