Advanced Search

Citation: WANG Hui-Sheng, PAN Zhi-Quan. Synthesis, Crystal Structure and Magneto-Structural Correlation of a [Mn8Ce] Cluster Substituted by Four Pyrazoles[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1104-1110. doi: 10.11862/CJIC.2014.188 shu

Synthesis, Crystal Structure and Magneto-Structural Correlation of a [Mn8Ce] Cluster Substituted by Four Pyrazoles

  • 1.

    Key Laboratory for Green Chemical Process of Ministry of Education, School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430074, China

  • Received Date: 28 November 2013
    Available Online: 27 January 2014

    Fund Project: 国家自然科学基金(No.21201136) (No.21201136)武汉工程大学科学研究基金(No.10122012)资助项目。 (No.10122012)

  • One [Mn8Ce] mixed metal cluster, namely, [Mn8O8Ce(O2CCH3)12(pyr)4]·2CH3OH (2·2CH3OH, pyr=pyrozole) has been obtained by adding (NH4)2Ce(NO3)6 to the acetonitrile/methanol solution containing Mn(O2CCH3)2·4H2O, pyrozole and acetic acid. The complex was fully characterized by X-ray single crystal structural diffraction, IR, elemental analysis and magnetic investigation. The structural analysis indicates that the complex crystallized in the monoclinic system, P21/c space group, and the eight MnⅢ ions formed a nonplanar loop, which was further attached to the central CeⅣ ion via eight μ3-O2- ions. Magnetic studies indicate that, within the cluster, the magnetic coupling interactions between Mn3+ ions are weak ferromagnetic, with the ground state Sbeing 6. Moreover, there are only very weak frequency-dependent signals from ac magnetic susceptibility investigations. By analyzing magneto-structural correlation of a series of [Mn8Ce] complexes, we found that with the angles at monoatomically bridging O2- increasing and with the angle at monoatomically bridging carboxylate Odecreasing, the ferromagnetic interactions between Mn atoms will be strengthened, which further lead to larger S.
  • 加载中
    1. [1]

      [1] Sessoli R, Tsai H L, Schake A R, et al. J. Am. Chem. Soc., 1993, 115:1804-1816

    2. [2]

      [2] (a)Zaleski C M, Depperman E C, Kampf J W, et al. Angew. Chem. Int. Ed., 2004, 43:3912-3914

    3. [3]

      (b)WANG Hui-Sheng(王会生), PAN Zhi-Quan(潘志权). Chinese J. Inorg. Chem.(无机化学学报), 2013, 29(7):1459-1464

    4. [4]

      [3] Lin P H, Burchell T J, Clerac R, et al. Angew. Chem. Int. Ed., 2008, 47:8848-8851

    5. [5]

      [4] Chilton N F, Langley S K, Moubaraki B, et al. Chem. Sci., 2013, 4:1719-1730

    6. [6]

      [5] Przychodzeń P, Korzeniak T, Podgajny R, et al. Coord. Chem. Rev., 2006, 250:2234-2260

    7. [7]

      [6] Leuenberger M, Loss D. Nature, 2001, 410:789-793

    8. [8]

      [7] Aromi G, Aguila D, Gamez F, et al. Chem. Soc. Rev., 2012, 41:537-546

    9. [9]

      [8] Ardavan A, Rival O, Morton, J J L, et al. Phys. Rev. Lett., 2007, 98:057201(1-4)

    10. [10]

      [9] Christou G, Gatteschi D, Hendrickson D N, et al. MRS Bull., 2000, 25:66-71

    11. [11]

      [10] Wang H S, Zhang Z C, Song X J, et al. Dalton Trans., 2011, 40:2703-2706

    12. [12]

      [11] Miyazaki Y, Bhattacharjee A, Nakano M, et al. Inorg. Chem., 2001, 40:6632-6636

    13. [13]

      [12] Schake A R, Tsai H L, de Vries N, et al. Chem. Commun., 1992:181-183

    14. [14]

      [13] King P, Wernsdorfer W, Abboud K A, et al. Inorg. Chem., 2005, 44:8659-8669

    15. [15]

      [14] Chakov Ni E, Soler M, Wernsdorfer W, et al. Inorg. Chem., 2005, 44:5304-5321

    16. [16]

      [15] Chakov N E, Lee S C, Harter A G, et al. J. Am. Chem. Soc., 2006, 128:6975-6989

    17. [17]

      [16] Soler M, Artus P, Folting K, et al. Inorg. Chem., 2001, 40: 4902-4912

    18. [18]

      [17] Boskovic C, Pink M, Huffman J C, et al. J. Am. Chem. Soc., 2001, 123:9914-9915

    19. [19]

      [18] Artus P, Boskovic C, Yoo J, et al. Inorg. Chem., 2001, 40: 4199-4210

    20. [20]

      [19] Soler M, Wernsdorfer W, Abboud K A, et al. J. Am. Chem. Soc., 2003, 125:3576-3588

    21. [21]

      [20] Soler M, Chandra S K, Ruiz D, et al. Polyhedron, 2001, 20: 1279-1283

    22. [22]

      [21] Tasiopoulos A J, Wernsdorfer W, Moulton B, et al. J. Am. Chem. Soc., 2003, 125:15724-15725

    23. [23]

      [22] Wang H S, Ma C B, Wang M, et al. J. Mol. Struct., 2008, 875:288-294

    24. [24]

      [23] Mishra A, Tasiopoulos A J, Wernsdorfer W, et al. Inorg. Chem., 2008, 47:4832-4843

    25. [25]

      [24] Canty A J, Minchin N J, Patrick J M, et al. Dalton Trans., 1983:1253-1259

    26. [26]

      [25] SAINT-Plus, Version 6.02; Bruker Analytical X-ray System, Madison, WI, 1999.

    27. [27]

      [26] Sheldrick G M. SHELXTL-97, Universitt of Göttingen, Göttingen, Germany, 1997.

    28. [28]

      [27] (a)Liu W, Thorp H H. Inorg. Chem., 1993, 32:4102-4105

    29. [29]

      (b)Brown I D, Shannon R D. Acta Crystallogr., 1973, A29: 266-282

    30. [30]

      (c)Roulhac P L, Palenik G J. Inorg. Chem., 2003, 42:118-121

    31. [31]

      [28] Shores M P, Sokol J J, Long J R. J. Am. Chem. Soc., 2002, 124:2279-2292

    32. [32]

      [29] Scott R T W, Parsons S, Murugesu M, et al. Angew. Chem., Int. Ed., 2005, 44:6540-6543

  • 加载中
    1. [1]

      Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188

    2. [2]

      Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192

    3. [3]

      Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278

    4. [4]

      Wenyan Dan ,  Weijie Li ,  Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060

    5. [5]

      Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

    6. [6]

      Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003

    7. [7]

      Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357

    8. [8]

      Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

    9. [9]

      Yan Liu ,  Yuexiang Zhu ,  Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084

    10. [10]

      Weina Wang ,  Fengyi Liu ,  Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029

    11. [11]

      Junqiao Zhuo ,  Xinchen Huang ,  Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100

    12. [12]

      Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173

    13. [13]

      Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207

    14. [14]

      Jinfeng Chu ,  Lan Jin ,  Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016

    15. [15]

      Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271

    16. [16]

      Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy4-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251

    17. [17]

      Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114

    18. [18]

      Yuyao Wang ,  Zhitao Cao ,  Zeyu Du ,  Xinxin Cao ,  Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014

    19. [19]

      Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307

    20. [20]

      Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(443)
  • HTML views(31)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return