Citation: HUANG Yan-Ping, ZHANG Xiao, LIU Lei, ZHANG Nan-Xi, XU Xian-Zhu. Synthesis and Crystal Structure of Transition Metal Coordination Compounds with Triethylenediamine Ligand and Their Florescence Properties Studies[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1001-1008. doi: 10.11862/CJIC.2014.186 shu

Synthesis and Crystal Structure of Transition Metal Coordination Compounds with Triethylenediamine Ligand and Their Florescence Properties Studies

1.
1 State Key Laboratory of Urban Water Resource and Environment;

Received Date: 8 April 2013
Available Online: 8 March 2014
Fund Project: 国家自然科学基金青年基金(No.51108122)；哈尔滨工业大学城市水资源与水环境国家重点实验室开放基金项目(No.QA201025)；中央高校基本科研业务费专项资金(No.HIT.NSRIF.2010053)以及哈尔滨市科技创新人才研究专项资金项目(青年科技创新人才)(No.2010RFQXG035) (No.51108122)；哈尔滨工业大学城市水资源与水环境国家重点实验室开放基金项目(No.QA201025)；中央高校基本科研业务费专项资金(No.HIT.NSRIF.2010053)以及哈尔滨市科技创新人才研究专项资金项目(青年科技创新人才)(No.2010RFQXG035)哈尔滨市科技创新人才研究专项资金项目(优秀学科带头人)(No.2007RFXXG018)共同资助。 (优秀学科带头人)(No.2007RFXXG018)

Aseries of transition metal coordination compounds based on the ligand, triethylenediamine(dabco), [CdCl₃H(dabco)₂] (1), [CoCl₃Hdabco] (2), [NiCl₂(H₂O)₃Hdabco]Cl (3), [CuCl₃H(dabco)₂]Cl·H₂O (4) have been prepared and characterized by elemental analyses, IRspectra, thermogravimety and single crystal X-Ray diffraction structure analyses. Compound 1 displays an one-dimensional straight chain via the hydrogen bonding interactions. Compound 2 possesses the left helix molecular structure. Compound 3 possesses the right helix molecular structure and compound 4 exhibits a two-dimensional molecular sheet with grids. Compounds 1 to 4 show intensive photoluminescence.
- transition-metal coordination compounds;triethylenediamine;crystal structure;florescence properties
1. [1]
  [1] Ockwig N W, Delgado-Friedrichs O, O'Keeffe M, et al. Acc. Chem. Res., 2005, 38:176-182
2. [2]
  [2] YU Jing-Hua(于景华), DING Chang-Jiang(丁长江), HAN Ke-Fei(韩克飞), et al. Chinese J. Inorg. Chem.(无机化学学报), 2006, 22(4):607-611
3. [3]
  [3] Hoskins B F, Robson R. J. Am. Chem. Soc., 1989, 111:5962-5964
4. [4]
  [4] Murray L J, Dinc M, Long J R. Chem. Soc. Rev., 2009, 38(5): 1294-1314
5. [5]
  [5] Holliday B J, Mirkin C A. Angew. Chem. Int. Ed., 2001, 40 (11):2022-2043
6. [6]
  [6] Khlobystov A N, Blake A J, Champness N R, et al. Coord. Chem. Rev., 2001, 222:155-192
7. [7]
  [7] Ohba M, Fukita N, Okawa H. J. Chem. Soc. Dalton Trans., 1997, 977(10):1733-1737
8. [8]
  [8] Gatteschi D. Adv. Mater., 1994, 6:635-645
9. [9]
  [9] Ohba M, kawa H, Ito T, et al. J. Chem. Soc. Chem. Commun., 1995:1545-1546
10. [10]
  [10] Ohba M, Maruono N, Okawa H, et al.J. Am. Chem. Soc., 1994, 116:11566-11567
11. [11]
  [11] Zaworotko M. J. Angew. Chem. Int. Ed. Engl., 2000, 39:3052-3054
12. [12]
  [12] Tong M L, Chen X M, Ye B H, et al. Angew. Chem. Int. Ed., 1999, 38:2237-2240
13. [13]
  [13] Batten S R, Robson R. Angew. Chem. Int. Ed., 1998, 37: 1460-1494
14. [14]
  [14] LI Jing(李婧), ZHOU Jian-Hao(周建豪), LI Yi-Zhi(李一志), et al. Chinese J. Inorg. Chem.(无机化学学报), 2004, 20(7): 841-844
15. [15]
  [15] Friesner R A, Banks J L, Murphy R B. J. Med. Chem., 2004, 47:1739-1749
16. [16]
  [16] Van Asselt R, Elsevier C J, Smeets W J. Recl. Trav. Chim. Pays-Bas., 1994, 113(2):88-98
17. [17]
  [17] Cairns A J, Perman J A, Wojtas L, et al. J. Am. Chem. Soc., 2008, 130(5):1560-1561
18. [18]
  [18] Xu W X, Li J, Liu R P, et al. Inorg. Chem. Commun., 2013, 28:12-15
19. [19]
  [19] Wang J K, Chen H, Liu F F. Synth. React. Inorg. Met. Org. Chem., 2013, 43(2):165-168
20. [20]
  [20] Yan J J, Cheng K, Qiu Y. Asian J. Chem., 2013, 25(2):1149-1151
21. [21]
  [21] Dolomanov O V, Bourhis L J, Gildea R J, et al. J. Appl. Cryst., 2009, 42:339-341
22. [22]
  [22] Spek A L. Acta Crystallogr. Sect. D: Biol. Crystallogr., 2009, 65:148-155
23. [23]
  [23] Sampanthar J T, Vittal J J. Main Group Chem., 2001, 24:127-128
24. [24]
  [24] Xiao J M. Acta Crystallogr. Sect. C: Cryst. Struct. Commun., 2010, 66(11):348-350
25. [25]
  [25] Liu Y Y, Ma J F, Yang J, et al. Inorg. Chem., 2007, 46(8): 3027-3037
26. [26]
  [26] Zeng M H, Zhang W X, Sun X Z, et al. Angew. Chem. Int. Ed., 2005, 44(20):3079-3082
27. [27]
  [27] Brown I D, Altermatt D. Acta Crystallogr. B Sect.: Struct. Sci., 1985, 41:244-247
28. [28]
  [28] Brese N E, O'Keeffe M. Acta Crystallogr. B Sect.: Struct. Sci., 1991, 47:192-197
29. [29]
  [29] Adams S. Acta Crystallogr. B Sect.: Struct. Sci., 2001, 57: 278-287
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沈阳化工大学材料科学与工程学院沈阳 110142