Citation: YANG Xiao, A M Showkot Hossain, ZHU Yu, MENG Su-Ci, XIA Chang-Kun, XIE Ji-Min. Syntheses, Crystal Structure, Properties of Cobalt and Zinc Complexes Based on N,N’-Diisobutyl-2,3-diaminoquinoxaline[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1160-1166. doi: 10.11862/CJIC.2014.176 shu

Syntheses, Crystal Structure, Properties of Cobalt and Zinc Complexes Based on N,N’-Diisobutyl-2,3-diaminoquinoxaline

1.
1 School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China;

Received Date: 18 July 2013
Available Online: 21 February 2014
Fund Project: 国家自然科学基金(No.21171075/BO10303，21103073/BO30201)；江苏省研究生创新项目(No.cxzz13_0679)以及国家博士后科学基金(No.2013T60500)资助项目。 (No.21171075/BO10303，21103073/BO30201)；江苏省研究生创新项目(No.cxzz13_0679)以及国家博士后科学基金(No.2013T60500)

N,N'-Diisobutyl-2,3-diaminoquinoxaline was synthesized by 2,3-dichloroquinoxaline and isobutylamine. And the complexes ([Co(DIDAQX)Cl₂]) (1, DIDAQX=N,N'-Diisobutyl-2,3(1H,4H)-diaminoquinoxaline) and ([Zn(DIDAQX)Cl₂]) (2) (Same revision as above)were prepared, which characterized by elemental analysis, IR spectra, single crystal X-ray diffraction, TGanalysis, fluorescence and electrochemical properties. For 1, DFT and TD-DFT calculations have been performed to obtain its UV-Vis absorption spectrum, and a satisfactory theoretical-experimental agreement was achieved. The crystal structures of complexes 1 and 2 show that they crystallize in orthorhombic space group Pbca with a=1.4082(3) nm, b=1.4628(3) nm, c=1.7970(4) nm; V= 3.7017(14) nm³, Z=8 of 1 and a=1.4082(3) nm, b=1.4648(3) nm, c=1.7969(4) nm; V=3.7065(14) nm³, Z=8 of 2. In the structure of complexes, each metal atom is four coordinated. Besides chelated by the DIDAQX with two nitrogen atoms, the atom is also coordinated by two Cl atoms, thus form a distorted tetrahedral geometry.
- Cobalt(Ⅱ) complex;Zinc(Ⅱ) complex;crystal structure;property;density functional theory
1. [1]
  [1] Yan L, Li F W, Dai G F, et al. Med. Chem. Lett., 2007, 17 (3):609
2. [2]
  [2] Schutz H. Benzodiazepines. Heidelberg: Springer, 1982.
3. [3]
  [3] Nasr M. N. A. Arch. Pharm., 2002, 335:389
4. [4]
  [4] Seitz L E, Suling W J, Reynolds R C. J. Med. Chem., 2002, 45 (25):5604
5. [5]
  [5] He W, Meyers M R, Hanney B, et al. Bioorg. Med. Chem. Lett., 2003, 13:3097
6. [6]
  [6] Sonawane N D, Rangnekar D W J. Heterocycl. Chem., 2002, 39:303
7. [7]
  [7] Hirayama T, Yamasaki S, Ameku H, et al. Dyes Pigment, 2005, 67:105
8. [8]
  [8] Lindsley C W, Zhao Z, Leister W H, et al. Bioorg. Med. Chem. Lett., 2005, 15:761
9. [9]
  [9] Thomas K R J, Lin J T, Tao Y T, et al. J. Mater. Chem., 2002, 12:3516
10. [10]
  [10] Adnni Z E, Mcharfi M, Sfaira M, et al. Int. J. Electrochem. Sci., 2012, 41:6738-6751
11. [11]
  [11] Adnni Z E, Mcharfi M, Sfaira M, et al. Int. J. Electrochem. Sci., 2012, 41:8713-8733
12. [12]
  [12] Zhu Y, Xia C K, Meng S C, et al. Polyhedron, 2013, 61:181-187
13. [13]
  [13] Frisch M J. Gaussian 09, Revision A. 02; Gaussian Inc.: Wallingford, CT, 2009.
14. [14]
  [14] Perdew J P, Burke K, Ernzerhof M, et al. Phys. Rev. Lett., 1996, 77:3865-3868
15. [15]
  [15] Höllwarth A, Böhme M, Dapprich S, et al. Chem. Phys. Lett., 1993, 208:111-114
16. [16]
  [16] Shanmuganathan S, Markus K K, Joachim H, et al. Chem. Commun., 2006:640-642
17. [17]
  [17] Sheldrick G M. SHELXS-97, Program for Automatic Solution of Crystal Structures, University of Göettingen, Germany, 1997.
18. [18]
  [18] Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göettingen, Germany, 1997.
19. [19]
  [19] Doring M, Fehling P, Gorls H, et al. J. Prakt. Chem. Chem. Zeitung, 1999, 341:752
20. [20]
  [20] Hampel O, Rode C, Walther D, et al. Z. Naturforsch, 2002, 57b:946-956
21. [21]
  [21] Geoffrey D. Inorg. Chim. Acta, 1988, 149:21-30
22. [22]
  [22] Pascal R, Carolin K, Olaf H, et al. Eur. J. Inorg. Chem., 2010:4770-4782
23. [23]
  [23] Piotr S, Jozef U, Slawomir S, et al. J. Chem. Soc., 1996: 3469-3473
24. [24]
  [24] Jong H J, Young H A, Kang Y K, et al. Polyhedron, 2008, 27:319-324
25. [25]
  [25] Soo G R, Jong U Y, Jong H J. Polyhedron, 2004, 23:2063-2067
26. [26]
  [26] Bharadwaj P K, Schugar H J, Potenza J A, et al. Acta Crystallogr., Sect. C, 1991, 47:754
27. [27]
  [27] Liu Y, Yu Y H, Liu Y F, et al. Z. Anorg. Allg. Chem., 2013, 639(1):193-196
28. [28]
  [28] ZHU Yu(朱禹), HUANG Wen-Hao(黄文浩), ZHU Min(朱敏). Chinese J. Inorg. Chem.(无机化学学报), 2013, 29(1): 133-137
1. [1]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
2. [2]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
3. [3]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
4. [4]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
5. [5]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
8. [8]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
9. [9]
  Hao XU , Ruopeng LI , Peixia YANG , Anmin LIU , Jie BAI . Regulation mechanism of halogen axial coordination atoms on the oxygen reduction activity of Fe-N₄ site: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 695-701. doi: 10.11862/CJIC.20240302
10. [10]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
11. [11]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
12. [12]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
13. [13]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
14. [14]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
15. [15]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
16. [16]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
17. [17]
  Kaifu Zhang , Shan Gao , Bin Yang . Application of Theoretical Calculation with Fun Practice in Raman Spectroscopy Experimental Teaching. University Chemistry, 2025, 40(3): 62-67. doi: 10.12461/PKU.DXHX202404045
18. [18]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
19. [19]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
20. [20]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(478)
HTML views(90)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142