Citation: CHU Xiao-Fei, HE Yun-Qiu, LI Yi-Ming, HUANG He-Zhou, LIU De-Yu, CHEN Hui-Min, LI Wen-You. Sb Doped ZnSnO₃ Transparent and Conducting Thin Films：Preparation and Property[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1212-1220. doi: 10.11862/CJIC.2014.169 shu

Sb Doped ZnSnO₃ Transparent and Conducting Thin Films：Preparation and Property

1.
Department of Materials Science and Engineering, Tongji University, Shanghai, 201800, China

Received Date: 18 November 2013
Available Online: 17 February 2014
Fund Project: 国家自然科学基金(No.51175162)资助项目。 (No.51175162)

Undoped and Sb doped ZnSnO₃ thin films were synthesized by a sol-gel spin-coating method. Acomparative study between these films was presented. The structure, electrical and optical properties of ZnSnO₃ thin films doped with 0mol%, 1mol%, 8mol% and 30mol% of Sb were investigated by X-ray diffraction (XRD), field emission-scanning electron microscope (FE-SEM), X-ray photoelectron spectroscope (XPS), Hall measurement and ultraviolet-visible spectroscope (UV-Vis). The results show that all films correspond to a pure phase of ZnSnO₃ structure and that Sb doped ZnSnO₃ films have lower resistivity than those of undoped ZnSnO₃ films. The minimum resistivity is obtained in ZnSnO₃ films doped with 8.0mol% of Sb. In addition, interstitial zinc ions introduced by antimony ion doping in ZnSnO₃ crystal lattice lead to a better conductivity. Furthermore, all doped ZnSnO₃ films are with >80% transmittance in the region above 475 nm.
- conducting;transparent;films;sol-gel
1. [1]
  [1] Fortunato E, Ginley D, Hosono H, et al. MRS Bull., 2007, 32:242-247
2. [2]
  [2] Porch A, Morgan D V, Perks R M, et al. J. Appl. Phys., 2004, 95:4734-4737
3. [3]
  [3] Marks T J, Veinot J G C, Cui J, et al. Synth. Met., 2002, 127:29-35
4. [4]
  [4] Ginley D S, Bright C. MRS Bull., 2000, 25:15-18
5. [5]
  [5] Popovi J, Greta B, Tkalec E. Mater. Sci. Eng., B, 2011, 176: 93-98
6. [6]
  [6] Fan J C C, Goodenough J B. J. Appl. Phys., 1997, 48:3524-3531
7. [7]
  [7] Moholkar A V, Pawar S M, Rajpure K Y, et al. Appl. Surf. Sci., 2009, 255:9358-9364
8. [8]
  [8] Nasr B, Dasgupta S, Wang D. J. Appl. Phys., 2010, 108: 103721-1-103721-6
9. [9]
  [9] Coutts T J, Young D L. J. Vac. Sci. Technol. A, 2000, 18(6): 2646-2660
10. [10]
  [10] Jain V K, Kumar P, Bhandari D. Thin Solid Films, 2010, 519:1082-1086
11. [11]
  [11] Lee Y E, Norton D P, Budai J D. J. Appl. Phys., 2001, 90: 3863-3866
12. [12]
  [12] Jain V K, Kumar P, Kumar M. J. Alloys Compd., 2011, 509: 3541-3546
13. [13]
  [13] Hayashi Y, Kondo K, Murai K, et al. Vacuum, 2004, 74:607-611
14. [14]
  [14] Kurz A, Aegerter M A. Thin Solid Films, 2008, 516:4513-4518
15. [15]
  [15] Kurz A, Brakecha K, Puetz J. Thin Solid Films, 2006, 502: 212-218
16. [16]
  [16] Ko J H, Kim I H, Kim D. Appl. Surf. Sci., 2007, 253:7398-7403
17. [17]
  [17] Knapp C E, Hyett G, Parkin I P. Chem. Mater., 2011, 23: 1719-1726
18. [18]
  [18] Tetsuka H, Shan Y J, Tezuka K. Vacuum, 2006, 80:1038-1041
19. [19]
  [19] Inoue K, Tominaga K, Tsuduki T. Vacuum, 2009, 83:552-556
20. [20]
  [20] Minami T, Tsukada S, Minamino Y. J. Vac. Sci. Technol. A, 2005, 23(4):1128-1132
21. [21]
  [21] Minami T. MRS Bull., 2000, 25:38-44
22. [22]
  [22] Minami T, Miyata T, Yamamoto T. Surf. Coat. Technol., 1998, 108-109:583-587
23. [23]
  [23] Mianami T, Sonohara H, Sato H, et al. Jpn. J. Appl. Phys., 1994, 33:1693-1696
24. [24]
  [24] Inaguma Y, Yoshida M, Katsumata T. J. Am. Chem. Soc., 2008, 130:6704-6705
25. [25]
  [25] Xue X Y, Chen Y J, Wang Y G, et al. Appl. Phys. Lett., 2005, 86:233101(1-3)
26. [26]
  [26] JI Ling-Li(季伶俐), HE Yun-Qiu(贺蕴秋), LI Le(李乐). Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(3):437-444
27. [27]
  [27] Hoel C A, Mason T O, Gaillard J F. Chem. Mater., 2010, 22: 3569-3579
28. [28]
  [28] Laurent A, Josette O F. J. Power Sources, 2003, 119-121: 585-590
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沈阳化工大学材料科学与工程学院沈阳 110142

Sb Doped ZnSnO3 Transparent and Conducting Thin Films：Preparation and Property

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Sb Doped ZnSnO₃ Transparent and Conducting Thin Films：Preparation and Property