Citation: LI Ling, LIN Kui, ZHANG Fan, CUI Lan, WANG Hui, CHEN Xiao-Ping, ZHANG Li-Shuang, Sayyar Ali Shah, CUI Shen. Preparation of N-Doped Long Bamboo-Like Carbon Nanotubes and Their Growth Mechanism[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1097-1103. doi: 10.11862/CJIC.2014.157 shu

Preparation of N-Doped Long Bamboo-Like Carbon Nanotubes and Their Growth Mechanism

1.
1 Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China;

Received Date: 8 October 2013
Available Online: 17 December 2013

N-doped long bamboo-like carbon nanotubes(NDLBLCNTs) were prepared by DCarc-discharge with the coevaporation of anode and stainless steel sheet(SSS). The morphology, structure, and composition of the products were characterized by using scanning electron microscope(SEM), field emission high resolution transmission electron microscope(HRTEM), energy dispersive X-ray(EDX) spectrometer, electron energy loss spectroscopy (EELS), and transmission electron microscope(TEM). The results show that the lengths of the NDLBLCNTs are between 640 nm and 835 nm, the inner diameters are in the range of 23~35 nm, and the outer diameters are in the range of 28~47 nm. In each of the inner cavities formed at the "bamboo joints" there is a black nanoparticle. Both the diameters of such black nanoparticles and the content of NDLBLCNTs in the product are related with the melted and evaporated area of the SSS. The temperature gradient between the SSSand the center of arc discharge zone is about 87.5~94.4 ℃·mm^-1. The coevaporation of the SSS together with the anode is the sufficient and necessary condition for the formation NDLBLCNTs. The growth mechanism of the NDLBLCNTs is discussed briefly.
- arc-discharge;N-doped;long bamboo-like carbon nanotubes;coevaporation;growth mechanism
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