Citation: CHU Zhao-Jing, BAI Xiao-Guang, WANG Yu-Cheng, CHEN Jin-Mei, ZHAO Hong. Crystal, Structures of, Cobalt(Ⅱ) and, Copper(Ⅱ) Complexes with 3-Amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 945-951. doi: 10.11862/CJIC.2014.148 shu

Crystal, Structures of, Cobalt(Ⅱ) and, Copper(Ⅱ) Complexes with 3-Amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole

1.
1 School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China;

Corresponding author: ZHAO Hong,
Received Date: 8 October 2013
Available Online: 17 November 2013
Fund Project: 国家自然科学基金(No.20801012) (No.20801012)江苏爱纳吉新能源科技有限公司(No.8507040091)资助项目。 (No.8507040091)

Two compounds CoCl₄(Athpp)₂·2H₂O (1) and CuCl₄(Athpp)₂ (2) were respectively obtained by the reactions of 3-amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole (Athpp) with cobalt(Ⅱ) chlorine and copper(Ⅱ) chlorine. The compounds have been characterized by FT-IR, elemental analyses and crystal structures. The compound 1 crystallizes in P1 space group and the compound 2 crystallizes in P2₁/n space group. The central metals are adopt distorted octahedral geometry. In addition, the fluorescent spectroscopy of the compounds were studied in solid state at room temperature.
- cobalt(Ⅱ) compound;copper(Ⅱ) compound;crystal structure;pyrazole derivative
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