Citation: CHU Zhao-Jing, BAI Xiao-Guang, WANG Yu-Cheng, CHEN Jin-Mei, ZHAO Hong. Crystal, Structures of, Cobalt(Ⅱ) and, Copper(Ⅱ) Complexes with 3-Amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 945-951. doi: 10.11862/CJIC.2014.148 shu

Crystal, Structures of, Cobalt(Ⅱ) and, Copper(Ⅱ) Complexes with 3-Amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole

1.
1 School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China;

Corresponding author: ZHAO Hong,
Received Date: 8 October 2013
Available Online: 17 November 2013
Fund Project: 国家自然科学基金(No.20801012) (No.20801012)江苏爱纳吉新能源科技有限公司(No.8507040091)资助项目。 (No.8507040091)

Two compounds CoCl₄(Athpp)₂·2H₂O (1) and CuCl₄(Athpp)₂ (2) were respectively obtained by the reactions of 3-amino-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole (Athpp) with cobalt(Ⅱ) chlorine and copper(Ⅱ) chlorine. The compounds have been characterized by FT-IR, elemental analyses and crystal structures. The compound 1 crystallizes in P1 space group and the compound 2 crystallizes in P2₁/n space group. The central metals are adopt distorted octahedral geometry. In addition, the fluorescent spectroscopy of the compounds were studied in solid state at room temperature.
- cobalt(Ⅱ) compound;copper(Ⅱ) compound;crystal structure;pyrazole derivative
1. [1]
  [1] (a)Perrin M, Thozet A, Cabildo P, et al. Can. J. Chem., 1993, 71:1443-1449
2. [2]
  (b)Foces C F, Alkorta I, Elguero J. Acta Cryst., 2000, 56: 1018-1028
3. [3]
  (c)Foces C F, Echevarria A, Jagerovic N, et al. J. Am. Chem. Soc., 2001, 123:7898-7906
4. [4]
  [2] (a)Mohamed A A. Acta Cryst., 2002:m228-m229
5. [5]
  (b)Pacios V G, Arroyo M, Anton N, et al. J. Chem. Soc. Dalton Trans., 2009:2135-2141
6. [6]
  [3] HAN Wen(韩伟), HAN Mei-Ling(韩美令), LIU Qi(刘琦), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 09: 1997-2004
7. [7]
  [4] Yang G, Raptis R G. Cryst. Growth Des., 2008, 8:981-985
8. [8]
  [5] Yang G, Marínez J R, Raptis R G. Inorg. Chim. Acta, 2009, 362:1546-1552
9. [9]
  [6] Murray H, Raptis R G, Fackler J P. Inorg. Chem., 1988, 27: 26-33
10. [10]
  [7] Raptis R G, Fackler J P. Inorg. Chem., 1988, 27:4179-4182
11. [11]
  [8] Angaridis P A, Mezei G, Raptis R G, et al. Inorg. Chem., 2002, 41:2219-2228
12. [12]
  [9] Mezei G, Raptis R G. Inorg. Chim. Acta, 2004, 357:3279-3288
13. [13]
  [10] Mezei G, Carrillo M R, Raptis R G. Inorg. Chim. Acta, 2004, 357:3721-3723
14. [14]
  [11] Miras H N, Zhao H, Raptis R G, et al. Eur. J. Inorg. Chem., 2008:4745-4755
15. [15]
  [12] Mezei G, Baran P, Raptis R G. Angew. Chem. Int. Ed., 2004, 116:584-587
16. [16]
  [13] Miras H N, Chakraborty I, Raptis R G. Chem. Commun., 2010, 46:2569-2571
17. [17]
  [14] Yang G, Baran P, Raptis R G, et al. Cryst. Growth Des., 2013, 13:264-269
18. [18]
  [15] Nicola C D, Forlin E, Garau F, et al. Cryst. Growth Des., 2013, 13:126-135
19. [19]
  [16] Li Z P, Xing Y H, Zhang Y H, et al. J. Coord. Chem., 2009, 62:564-567
20. [20]
  [17] Liu C B, Gong Y N, Chen Y, et al. Inorg. Chim. Acta, 2012, 383:277-286
21. [21]
  [18] LU Wen-Guan(卢文贯), LIU Hong-Wen(刘宏文). Chinese J. Inorg. Chem.(无机化学学报), 2010, 26(8):1450-1456
22. [22]
  [19] WANG Xin-Yu(王欣羽), LI Zhen(李桢), SUN Qiao(孙巧), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 3:483-490
23. [23]
  [20] Wyatt P G, Woodhead A J, Berdini V, et al. J. Med. Chem., 2008, 51:4986-4999
24. [24]
  [21] Langford H M, Williams P D, Homnick C F, et al. Bioorg. Med. Chem. Lett., 2008, 18:721-725
25. [25]
  [22] (a)Seo H J, Kim M J, Lee S H, et al. Bioorg. Med. Chem. Lett., 2010, 18:1149-1162
26. [26]
  (b)Silvestri R, Ligresti A, Regina G L, et al. Eur. J. Med. Chem., 2010, 45:5878-5886
27. [27]
  (c)Donohue S R, Dannals R F, Halldin C. J. Med. Chem., 2011, 54:2961-2970
28. [28]
  (d)Sasmal P K, Reddy D S, Talwar R, et al. Bioorg. Med. Chem. Lett., 2011, 21:562-568
29. [29]
  [23] WANG Yu-Cheng(王玉成), BAI Xiao-Guang(白晓光), SHAO Qong-Guang (邵荣光), et al. China Patent, 102134243. 2011 -07-27.
30. [30]
  [24] BAI Xiao-Guang(白晓光). Thesis for the Doctorate of Chinese Academy of Medical Sciences and Peking Union Medical College(北京协和医学院博士论文). 2012.
31. [31]
  [25] Sheldrick G M. SHELXL-97, Program for the Solution of Crystal Structures, University of Gottingen, Germany, 1997.
32. [32]
  [26] (a)Razvudovskaya L V, Erikova M V, Putsykina E B, et al. Russ. J. Gen. Chem., 1993, 63:1145-1148
33. [33]
  (b)Ding L, Grehn L, Ragnarsson S. Acta Chem. Scan., 1990, 44:75
34. [34]
  (c)Elnagdi M H. Tetrahedron, 1974, 30:2791-2796
35. [35]
  [27] (a)Chivers T, Richardson J F, Smith N R M. Inorg. Chem., 1985, 24:2453-2458
36. [36]
  (b)Neumüller B, Dehnicke K. Z. Anorg. Allg. Chem., 2007: 103-105
37. [37]
  (c)Neumüller B, Dehnicke K. Z. Anorg.Allg. Chem., 2007, 633:2262-2267
38. [38]
  [28] Liu J F, Huang F P, Bian H D, et al. Z. Anorg. Allg. Chem., 2013:2347-2353
39. [39]
  [29] Fang S M, Zhang Q, Hu M, et al. Cryst. Growth Des., 2010, 10:4773-4785
40. [40]
  [30] Wang J J, Hu T L, Bu X H. CrystEngComm, 2011, 13:5152-5161
41. [41]
  [31] Bie H Y, Lu J, Xu J Q, et al. J. Solid State Chem., 2005, 178:1445-1453
1. [1]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
2. [2]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
3. [3]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
4. [4]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
5. [5]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
6. [6]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
7. [7]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
8. [8]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
9. [9]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
10. [10]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
11. [11]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
12. [12]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
13. [13]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
14. [14]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
15. [15]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
16. [16]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
17. [17]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
18. [18]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
19. [19]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
20. [20]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(363)
HTML views(15)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142