Citation: GUAN Lei, GAO Wei, ZHANG Zu-Kang, WANG Ying. Synthesis, Crystal Structures and Luminescent Properties of Two Nickel Mononuclear Complexes Containing N-donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1187-1194. doi: 10.11862/CJIC.2014.139 shu

Synthesis, Crystal Structures and Luminescent Properties of Two Nickel Mononuclear Complexes Containing N-donor Ligands

1.
1 School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China;

Received Date: 16 September 2013
Available Online: 25 October 2013

The synthesis of the two Ni(Ⅱ) mononuclear complexes containing N-donor ligands [Ni(phen)₂(H₂O)₂](1,6-nds)·2H₂O (1) and [Ni(phen)₃](1,6-nds)·10H₂O (2) (1,6-nds=1,6-naphthalene-disulfonate anion, phen=1,10-phenanthroline) was conducted in water by the reflux method. For the complex 1, the nickel ion coordinates with two 1,10-phenanthroline ligands and two water molecules, respectively, forming the [Ni(phen)₂(H₂O)₂]²⁺ cation, and the two uncoordinated water molecules connect to the [Ni(phen)₂(H₂O)₂]²⁺ cations and 1,6-nds anions to form a two-dimensional layered structure via the hydrogen bonds. For the complex 2, the nickel ion coordinates with three 1,10-phenanthroline ligands to form the [Ni(phen)₃]²⁺ cation. There are abundant hydrogen bonds between free water molecules and 1,6-nds anions, leading to a three-dimensional network structure. In the two complexes, the 1,6-nds anions don't coordinate with the nickel ions, only balance the charges. The complexes exhibit strong luminescence with emission maximum at 443 and 438 nm at room temperature, respectively.
- nickel complex;luminescent property;crystal structure
1. [1]
  [1] Zhao X B, Xiao B, Fletcher A J, et al. Science, 2004, 306: 1012-1015
2. [2]
  [2] Gao X M, Li D S, Wang J J, et al. CrystEngComm, 2008, 10: 479-482
3. [3]
  [3] Plecnik C E, Liu S, Shore S G. Acc. Chem. Res., 2003, 36: 499-508
4. [4]
  [4] Ma L F, Liu B, Wang L Y, et al. J. Chem. Soc., Dalton Trans., 2010, 39:2301-2308
5. [5]
  [5] Silvio Q, Giovanni M, Alessandra F, et al. Inorg. Chem., 2004, 43:1294-1301
6. [6]
  [6] Li Z M, Zhang J G, Cui Y, et al. J. Chem. Eng. Data, 2010, 55:3109-3116
7. [7]
  [7] Liu K, You H, Jia G, et al. Cryst. Growth Des., 2009, 9: 3519-3524
8. [8]
  [8] An B L, Gong M L, Li M X, et al. J. Mol. Struct., 2004, 687:1-6
9. [9]
  [9] Joo Y H, Twamley B, Garg S, et al. Angew. Chem. Int. Ed., 2008, 47:6236-6239
10. [10]
  [10] Zhang J G, Li Z M, Zang Y, et al. J. Hazard. Mater., 2010, 178:1094-1099
11. [11]
  [11] Kuppler R J, Timmons D J, Fang Q R, et al. Coord. Chem. Rev., 2009, 253:3042-3066
12. [12]
  [12] Tao G H, Guo Y, Parrish D A, et al. J. Mater. Chem., 2010, 20:2999-3005
13. [13]
  [13] Kong L Y, Zhang Z H, Zhu H F, et al. Angew. Chem. Int. Ed., 2005, 44:4352-4355
14. [14]
  [14] CČté A P, Shimizu G K H. Chem. Eur. J., 2003, 9:5361-5370
15. [15]
  [15] Sheriff T S, Carr P, Piggott B. Inorg. Chim. Acta, 2003, 348: 115-122
16. [16]
  [16] SONG Jin-Hao(宋金浩), GU Ya-Kun(顾雅琨), LI Xia(李夏). Chinese J. Inorg. Chem. (无机化学学报), 2010, 26:1457-1462
17. [17]
  [17] Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structure, University of Göttingen, Germany, 1997.
18. [18]
  [18] Sheldrick G M. Acta Crystallogr. Sect. A, 2008, 64:112-122
19. [19]
  [19] Sheldrick G M. SHELXL-97, Program for the Solution of Crystal Structure, University of Göttingen, Germany. 1997.
1. [1]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
2. [2]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
3. [3]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
4. [4]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
5. [5]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
6. [6]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
7. [7]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
8. [8]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
9. [9]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
10. [10]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
11. [11]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
12. [12]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
13. [13]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
14. [14]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
15. [15]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
16. [16]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
17. [17]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
18. [18]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
19. [19]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
20. [20]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(512)
HTML views(56)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142