Citation: LIU Jie-Xiang, ZHANG Yong-Qing, ZHANG Xiao-Guang, WANG Jian-Long, ZHAO Ling-Feng, YANG Jin, WANG Rui. Preparation and Characterization of Intercalation Materials with Layered Hydroxide Salts (LHS)[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 837-844. doi: 10.11862/CJIC.2014.129 shu

Preparation and Characterization of Intercalation Materials with Layered Hydroxide Salts (LHS)

1.
1 School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China;

Corresponding author: LIU Jie-Xiang, ZHANG Xiao-Guang,
Received Date: 15 September 2013
Available Online: 18 November 2013
Fund Project: 河北省自然科学基金(No.B2011202118)；山东大学胶体与界面化学教育部重点实验室开放课题(No.201202)；河北省高等学校科学技术研究项目(No.QN20131050) (No.B2011202118)；山东大学胶体与界面化学教育部重点实验室开放课题(No.201202)；河北省高等学校科学技术研究项目(No.QN20131050)“大学生创新创业训练计划”国家级项目(No.201310080018)资助项目。 (No.201310080018)

Intercalation of dodecyl benzene sulphonate (DBS) and sulfobutyl ether β-cyclodextrin (SBE-β-CD) into layered zinc hydroxide nitrate (Zn-LHS) and nickel/zinc hydroxide nitrate (NiZn-LHS) was synthesized by coprecipitation and ion-exchanged methods. The effect of anion concentration and pHvalue on preparation was systematically investigated and compared. The products were characterized by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and thermogravimetry and differential thermal analysis (TG-DTA), and scanning electron microscope (SEM). The results showed that Zn-LHS-DBS with pure phase and good crystallinity was obtained at DBS concentration of 0.19~0.38 mol·L^-1, pH=6.0~7.0, temperature of hydrothermal treatment of 60~100 ℃ by coprecipitation method. The NiZn-LHS-SBE-β-CD with good structure was prepared by ion-exchanged method. Zn-LHS-SBE-β-CD with pure phase was not successfully prepared by both coprecipitation and ion-exchanged method due to the particular structure of SBE-β-CD and poor hydrothermal stability of Zn-LHS. Furthermore, TG-DTA data indicated that stability of SBE-β-CD and DBSimproved distinctly in the interlayer due to the strong supra-molecular interaction existed between anions and hostlayer of LHS.
- zinc hydroxide nitrate;nickel/zinc hydroxide nitrate;dodecyl benzene sulphonate;sulfobutyl ether β-cyclodextrin;thermostability
1. [1]
  [1] Arízaga G G C. J. Solid State Chem., 2012, 185:150-155
2. [2]
  [2] Demel J, Kubát P, Jirka I, et al. J. Phys. Chem. C, 2010, 114:16321-16328
3. [3]
  [3] Rojas R, Giacomelli C E. Colloid Surf. A, 2013, 419:166-173
4. [4]
  [4] Yang J H, Han Y S, Park M, et al. Chem. Mater., 2007, 19: 2679-2685
5. [5]
  [5] Biswick T D, Park H, Shul Y G, et al. J. Phys. Chem. Solids, 2010, 71:647-649
6. [6]
  [6] Biswick T, Park D H, Choy J H. J. Phys. Chem. Solids, 2012, 73:1510-1513
7. [7]
  [7] Bull R M R, Markland C, Williams G R, et al. J. Mater. Chem., 2011, 21:1822-1828
8. [8]
  [8] Hussein M Z, Hashim N, Yahaya A H, et al. Solid State Sci., 2010, 12:770-775
9. [9]
  [9] Wang B, Zhang H, Evans David G, et al. Mater. Chem. Phys., 2005, 92:190-196
10. [10]
  [10] Liu X L, Wei M, Wang Z L, et al. J. Phys. Chem. C, 2008, 112:17517-17524
11. [11]
  [11] Nakayama H, Kuwano K, Tsuhako M. J. Phys. Chem. Solids, 2008, 69:1552-1555
12. [12]
  [12] Rajamathi J T, Ravishankar N, Rajamathi M. Solid State Sci., 2005, 7:195-199
13. [13]
  [13] bin Hussein M Z, Ghotbi M Y, Yahaya A H, et al. Solid State Sci., 2009, 11:368-375
14. [14]
  [14] Marangoni R, Ramos L P, Wypych F. J. Colloid Interface Sci., 2009, 330:303-309
15. [15]
  [15] XING Fang-Fang(邢方方), NI Zhe-Ming(倪哲明), WANG Ping(王平), et al. Acta Chim. Sin.(化学学报), 2007, 65(23): 2738-2742
16. [16]
  [16] Newman S P, Jones W C. J. Solid State Chem., 1999, 148: 26-40
17. [17]
  [17] Quan Z L, Yang H, Zheng B, et al. Colloid Surf. A, 2009, 348:164-169
18. [18]
  [18] Rojas R, Ángeles Ulibarri M, Barriga C, et al. Appl. Clay Sci., 2010, 49:176-181
19. [19]
  [19] del Arco M, Gutiérrez S, Martín C, et al. J. Solid State Chem., 2004, 177:3954-3962
20. [20]
  [20] Wang J, Wei M, Rao G Y, et al. Solid State Chem., 2004, 177:366-371
21. [21]
  [21] Cursino A C T, Gardolinski da Costa Gardolinski J E F. J. Colloid Interface Sci., 2010, 347:49-55
22. [22]
  [22] MacPhail R A, Strauss H L, Snyder R G, et al. J. Phys. Chem., 1984, 88:334-341
23. [23]
  [23] Moujhaid E M, Inacio J, Besse J P, et al. Micro. Meso. Mater., 2003, 57:37-46
24. [24]
  [24] Pérez-Ramírez J, Mul G, Kapteijn F, et al. J. Mater. Chem., 2001, 11:821-830
25. [25]
  [25] Wypych F, Arízaga G G C, da Costa Gardolinski J E F. J. Colloid Interface Sci., 2005, 283:130-138
26. [26]
  [26] WANG Bin(王斌). Thesis for the Master's Degree of Beijing University of Chemical Technology(北京化工大学硕士毕业论文), 2005.
1. [1]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
2. [2]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
3. [3]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
4. [4]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
5. [5]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
6. [6]
  Daming Zhang , Zhiwei Niu , Qiang Jin , Zongyuan Chen , Zhijun Guo . Eu(III)-硅酸盐胶体的制备与稳定性研究——一个由科研成果转化的放射化学综合实验的设计. University Chemistry, 2025, 40(6): 183-192. doi: 10.12461/PKU.DXHX202408058
7. [7]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
8. [8]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
9. [9]
  Lubing Qin , Fang Sun , Meiyin Li , Hao Fan , Likai Wang , Qing Tang , Chundong Wang , Zhenghua Tang . 原子精确的(AgPd)₂₇团簇用于硝酸盐电还原制氨：一种配体诱导策略来调控金属核. Acta Physico-Chimica Sinica, 2025, 41(1): 2403008-. doi: 10.3866/PKU.WHXB202403008
10. [10]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
11. [11]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
12. [12]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
13. [13]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
14. [14]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
15. [15]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
16. [16]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
17. [17]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
18. [18]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
19. [19]
  Yingtong Shi , Guotong Xu , Guizeng Liang , Di Lan , Siyuan Zhang , Yanru Wang , Daohao Li , Guanglei Wu . PEG-VN改性PP隔膜用于高稳定性高效率锂硫电池. Acta Physico-Chimica Sinica, 2025, 41(7): 100082-. doi: 10.1016/j.actphy.2025.100082
20. [20]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(414)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142