Citation: HU Chun-Yan, NIE Xu-Liang, XIONG Hui, HUANG Chang-Gan. Synthesis, Crystal Structures and Antibacterial Activities of Two Complexes of Copper Assembled by Triazole Pesticides Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 621-626. doi: 10.11862/CJIC.2014.108 shu

Synthesis, Crystal Structures and Antibacterial Activities of Two Complexes of Copper Assembled by Triazole Pesticides Ligands

1.
1 College of Science, Jiangxi Agricultural University, Nanchang 330045, China;

Received Date: 15 May 2013
Available Online: 1 November 2013
Fund Project: 国家自然科学基金(No.30760021) (No.30760021)江西省教育厅青年基金(No.GJJ13261)资助项目。 (No.GJJ13261)

Two copper complexes [CuL₄¹Cl₂] (1) and [CuL₄²Cl₂·4H₂O] (2) (L₁=Uniconazole,L₂=Paclobutrazol) were synthesized with triazole pesticides ligands uniconazole and paclobutrazol by solvothermal condition and structurally characterized by element analysis, IR and single crystal X-ray diffraction. Complex 1 is the Triclinic system, space group P1 with a=0.895 6(3) nm, b=1.326 7(4) nm, c=1.491 8(4) nm, α=94.828(3)°, β=97.774(3)°, γ=105.280(3)°, V=1.680 8(9) nm³. Complex 2 is the Triclinic system, space group P1 with a=1.021 89(19) nm, b=1.329(3) nm, c=1.366 4(3) nm, α=81.564(2)°, β=79.508(2)°, γ=79.185(2)°, V=1.785 3(7) nm³. In two complexes, Each six-coordinated Cu(Ⅱ) adopts a distorted octahedral geometry with four nitrogen atoms from triazole ligands and two Cl ions. 1 and 2 was linked into a one dimensional chain by intermolecular hydrogen bonds. Antibacterial activities of complex 1 and 2 increased significantly than corresponding ligands. CCDC: 931901, 1; 932228, 2.
- uniconazole;paclobutrazol;Cu;crystal structure;antibacterial activities
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沈阳化工大学材料科学与工程学院沈阳 110142