Citation: WANG Li, ZHOU Yuan-Lin, LI Ying-Jun. Controlled Synthesis and Luminescence Properties of Ginkgo-Like PbWO₄[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 828-836. doi: 10.11862/CJIC.2014.099 shu

Controlled Synthesis and Luminescence Properties of Ginkgo-Like PbWO₄

WANG Li ^1,2 ,
ZHOU Yuan-Lin ^1,2,, ,
LI Ying-Jun ^1,2

1.
1 State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China;

Corresponding author: ZHOU Yuan-Lin,
Received Date: 6 September 2013
Available Online: 30 October 2013
Fund Project: 国家自然科学基金委员会-中国工程物理研究院联合基金(No.11176026)资助项目。 (No.11176026)

In this paper, Ginkgo-like PbWO₄ has been synthesized using direct precipitation method, taking sodium tartrate as the surfactant. The structure and property of synthesized products have been characterized by combination of scanning electron microscope (SEM), X-ray power diffraction (XRD), energy dispersive X-ray spectroscopy (EDS) and fluorescence emission spectra (PL). Investigations were carried out on the sodium tartrates inhibitory effect on the crystal face(004), and the impact of pHvalue and aging temperature on products morphology. Aprobable mechanism for products formation is proposed based on the internal crystal structure analysis. The results indicated that the most uniform crystal morphology will be obtained at the aging temperature of 30 ℃. PbWO₄ crystal presented intense green emission under ultraviolet excitation, which will reach a maximum luminous intensity at pH=9.
- ginkgo-like;lead tungstate;controlled synthesis;crystal structure;photoluminescence
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沈阳化工大学材料科学与工程学院沈阳 110142

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Controlled Synthesis and Luminescence Properties of Ginkgo-Like PbWO₄