Citation: HUANG Yin, MENG Xiang-Gao, QIN Jin-Gui*. Synthesis, Crystal Structure and Nonlinear Optical Property of K₂W₃SeO₁₂[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(1): 179-184. doi: 10.11862/CJIC.2014.082 shu

Synthesis, Crystal Structure and Nonlinear Optical Property of K₂W₃SeO₁₂

1.
1 College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China;

Received Date: 1 November 2013
Available Online: 27 November 2013
Fund Project:

K₂W₃SeO₁₂ was synthesized by hydrothermal method. It crystallizes in space group R3c of the rhombohedral system, with cell parameters a=b=c=1.25361(10) nm, α=β=γ=33.5390(10)°. It was further characterized by the tests of XRD, EDX, ATR-FTIR, UV-Vis-NIR, TGand SHG (second harmonic generation). Its powders show a phase-matchable SHG response of approximately 9 times of KDP. It also exhibits wide band gap (3.24 eV) and good thermal stability. Its infrared absorption wavelength can reach up to 10 μm. Therefore, K₂W₃SeO₁₂ is regarded as a promising candidate for NLO (nonlinear optical) materials in the mid-IRregion.
- tungsten selenites;hydrothermal synthesis;nonlinear optical property;crystal structure;band gap,
1. [1]
  [1] SU Xu (苏旭), LIU Tao (刘涛), ZHANG Gang (张刚), et al. Chinese J. Inorg. Chem.(无机化学学报), 2006, 22(7):1163-1168
2. [2]
  [2] DONG Chun-Ming(董春明), WANG Shan-Peng(王善朋), TAO Xu-Tang (陶绪堂). Journal of Synthetic Crystals(人工晶体学报), 2006, 35(4):785-789
3. [3]
  [3] Halasyamani P S. Chem. Mater., 2004, 16:3586-3592
4. [4]
  [4] Halasyamani P S, Poeppelmeier K R. Chem. Mater., 1998, 10:2753-2769
5. [5]
  [5] Ok K M, Halasyamani P S, Casanova D, et al. Inorg. Chem., 2006, 18:3176-3183
6. [6]
  [6] Marvel M R, Lesage J, Baek J, et al. J. Am. Chem. Soc., 2007, 129:13963-13969
7. [7]
  [7] Halasyamani P S, Poeppelmeier K R. Inorg. Chem., 2008, 47:8427-8428
8. [8]
  [8] Mao J G, Jiang H L, Kong F. Inorg. Chem., 2008, 47:8498-8510
9. [9]
  [9] ZHANG Jun-Jie(张俊杰), ZHANG Zhong-Han(张中晗), TAO Xu-Tang(陶绪堂). Journal of Shandong University: Natural Science(山东大学学报:理学版), 2011, 46(10):99-120
10. [10]
  [10] Harrison W T A, Dussack L L, Vogt T, et al. J. Solid State Chem., 1995, 120:112-120
11. [11]
  [11] Nguyen S D, Halasyamani P S. Inorg. Chem., 2013, 52:2637-2647
12. [12]
  [12] Sheldrick G M. Acta Cryst., 2008, A64:112-122
13. [13]
  [13] Kurtz S K, Perry T T. J. Appl. Phys., 1968, 39:3798-3813
1. [1]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
2. [2]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
5. [5]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
6. [6]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
7. [7]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
8. [8]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
9. [9]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
10. [10]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
11. [11]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
12. [12]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
13. [13]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
14. [14]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
15. [15]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
16. [16]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
17. [17]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
18. [18]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
19. [19]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
20. [20]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(730)
HTML views(149)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Crystal Structure and Nonlinear Optical Property of K2W3SeO12

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis, Crystal Structure and Nonlinear Optical Property of K₂W₃SeO₁₂