Citation: LIU Jin-Jian, LIU Zu-Liang, CHENG Jian. Synthesis, Crystal Structure and Catalytic Properties of Two Energetic Complexes Containing 2,6-Diamino-3,5-dinitropyrazine-1-oxide[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 696-704. doi: 10.11862/CJIC.2014.064 shu

Synthesis, Crystal Structure and Catalytic Properties of Two Energetic Complexes Containing 2,6-Diamino-3,5-dinitropyrazine-1-oxide

1.
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Received Date: 4 June 2013
Available Online: 22 September 2013
Fund Project:

Two energetic complexes with 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105) [Cu₄O₂ (C₄N₆O₅H₂)₂(CH₃COO)₂(DMF)₂]·DMF(1)((C₄N₆O₅H₂)^2-is obtained by losing two protons from LLM-105) and [Co(C₄N₆O₅H₃)₃]·7H₂O(2) ((C₄N₆O₅H₃)^- is obtained by losing a proton from LLM-105) have been synthesized and structurally characterized using X-ray diffraction. The results reveal that complex 1 belongs to the orthorhombic system (space group Pbca) and complex 2 belongs to the trigonal system (space group R3). Thermal decomposition of LLM-105 and two complexes was examined by DSC and TG-DTG analyses. The kinetic parameters of the exothermic processes of two complexes were studied by the Kissingers and Ozawa-Doyles methods. DSC measurements show that two complexes have decreased the higher thermal decomposition temperature of AP by 117.42 and 71.85 ℃, increased the exothermic quantity of decomposition by 1 916.97 and 1 433.76 J·g^-1 respectively, showing good catalytic effects on the thermal decomposition of AP. CCDC: 938305, LLM-105; 911164, 1; 911163, 2.
- LLM-105;energetic complex;crystal structure;thermal decomposition;catalytic property
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沈阳化工大学材料科学与工程学院沈阳 110142