Citation: HUANG Yao, ZHOU Ming-Shan, ZHU Chao, LIU Long-Jiang, ZHOU Xiao-Jun, ZHANG Yong-Ming, FU Fei-E, JIN E. Synthesis, Structures and Luminescence Property of a 3D Zinc Coordination Polymer Based on 3, 5-Dimethyl-1H-1, 2, 4-triazole and 1,4-Benzenedicarboxylate Dianion[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 901-906. doi: 10.11862/CJIC.2014.045 shu

Synthesis, Structures and Luminescence Property of a 3D Zinc Coordination Polymer Based on 3, 5-Dimethyl-1H-1, 2, 4-triazole and 1,4-Benzenedicarboxylate Dianion

1.
Key Laboratory of Yunnan University for Special Energy and Function Materials, School of Chemical Engineering, Yunnan Open University, Kunming 650500, China

Corresponding author: HUANG Yao,
Received Date: 20 May 2013
Available Online: 18 September 2013
Fund Project: 云南科技厅应用基础研究计划面上项目(No.2011FZ198)；云南教育厅科研基金重点项目(No.2011Z009)资助项目。 (No.2011FZ198)；云南教育厅科研基金重点项目(No.2011Z009)

Anew zinc(Ⅱ) coordination polymer {[Zn₃(Hdmtrz)₂(1,4-bdc)₃]·2H₂O}_n (1), where Hdmtrz=3,5-dimethyl-1-H-1,2,4-triazole and 1,4-bdc=1,4-benzenedicarboxylate dianion, has been prepared by hydrothermal method and structurally characterized by elemental analysis, infrared spectra, X-ray powder diffraction, thermogravimetric analysis and single-crystal X-ray diffraction. The title compound crystallizes in triclinic, space group P1 with a=0.91797(18) nm, b=0.9833(2) nm, c=1.0717(2) nm, α=100.81(3)°, β=102.589(3)°, γ=106.90(3)°, V=0.8418(3) nm³, Z=1, and compound 1 shows a 3D framework with Schläfli symbols of {4¹²·6³} which is a typical pcu(α-Po) structure. The zinc(Ⅱ) complex exhibits strong fluorescence absorption at 471 nm (λ_max) in the solid state at room temperature.
- Zn(Ⅱ) coordination polymer;crystal structure;topology;luminescence
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沈阳化工大学材料科学与工程学院沈阳 110142