Citation: LIU Chun-Bo, WANG Qian-Qian, BAI Hong-Ye, CHE Guang-Bo, ZHANG Qing, LI Chun-Xiang. Hydrothermal Syntheses and Properties of Compounds Based on₁,10-Phenanthroline- 5,6-dione and Keggin-Type Polyoxometalate[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 391-397. doi: 10.11862/CJIC.2014.039 shu

Hydrothermal Syntheses and Properties of Compounds Based on₁,10-Phenanthroline- 5,6-dione and Keggin-Type Polyoxometalate

1.
1 School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China;

Corresponding author: CHE Guang-Bo,
Received Date: 23 March 2013
Available Online: 3 November 2013
Fund Project:

Three compounds based on Keggin-type polyoxometalate (POMs) using₁,10-phen-5,6-dione (Do) as neutral organic ligand, namely, (HDo)₆(PW₁₂O₄₀)₂·H₂O (1), [Cu(Do)₂(H₂O)]₂[Cu(Do)₂(PW₁₂O₄₀)(H₂O)](PW₁₂O₄₀)(2) and [Pb(Do)₂(PW₁₂O₄₀)](HDo)(3), have been synthesized under hydrothermal conditions and characterized by elemental analyses, infrared spectra, inductively coupled plasma analyses, X-ray photoelectron spectroscopy and single-crystal X-ray diffraction. Compounds 1 and 2 are zero-dimensional structures, and compound 3 exhibits one-dimensional chain. The thermal stabilities and photoluminescent properties of three compounds have also been investigated. CCDC: 767622, 1; 767623, 2; 767619, 2.
- 1,10-phenanthroline-5,6-dione;keggin-type polyoxometalate;hydrothermal;crystal structure
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Hydrothermal Syntheses and Properties of Compounds Based on1,10-Phenanthroline- 5,6-dione and Keggin-Type Polyoxometalate

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通讯作者: 陈斌, bchen63@163.com

Hydrothermal Syntheses and Properties of Compounds Based on₁,10-Phenanthroline- 5,6-dione and Keggin-Type Polyoxometalate