Citation: BAIYIN Meng-He, GANG Gang, NAREN Ji-Ru-Ga. Solvothermal Synthesis and Crystal Structure of K₂CdSnS₄[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 405-410. doi: 10.11862/CJIC.2014.012 shu

Solvothermal Synthesis and Crystal Structure of K₂CdSnS₄

1.
1 College of Chemistry & Environmental Science, Inner Mongolia Normal University, Hohhot 010022, China;

Corresponding author: BAIYIN Meng-He,
Received Date: 10 April 2013
Available Online: 5 October 2013
Fund Project:

Layered K₂CdSnS₄ (1) was synthesized solvothermally and characterized by X-ray single crystal diffraction. The crystals belong to the space group C2/c, with a=1.1021(5) nm, b=1.1030(5) nm, c=1.5151(10) nm, α=90°, β=100.416(12)°, γ=90°, V=1.8114(17) nm³, Z=8, D_c=3.209 g·cm^-3, M_r=437.60, μ=6.853 mm^-1, F(000)= 1600, λ=0.071073 nm, and the final R=0.1042 and wR=0.2008 for all observed reflections. The compound is comprised of sheets with adamantane-like [Cd₂Sn₂S₁₀]^8- units. UV-Vis reflectance spectrum of compound 1 reveals that 1 is a semiconductor with a band gap of 2.2 eV. CCDC: 424763.
- solvothermal synthesis;crystal structure;quaternary thiostannate;optical property
1. [1]
  [1] Xiong W W, Athresh E U, Zhang Q C, et al. J. Am. Chem. Soc., 2013,135:1256-1259
2. [2]
  [2] Wang Y L, Feng M L, Huang X Y, et al. Inorg. Chem. Commun., 2013,33:10-14
3. [3]
  [3] Zhang Q C, Malliakas C D, Kanatzidis M G. Inorg. Chem., 2009,48:10910-10912
4. [4]
  [4] GANG Gang(刚刚), BAIYIN Meng-He(白音孟和), WANG Xiao-Jing(王晓靖), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013,29(5):979-984
5. [5]
  [5] WANG Jiao(王娇), PAN Ying-Li(潘迎利), JIA Ding-Xian (贾定先), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010,26(8):1339-1344
6. [6]
  [6] CHEN Zhen(陈震), WANG Ru-Ji(王如骥). Chinese J. Inorg. Chem.(无机化学学报), 1999,15(5):661-666
7. [7]
  [7] Palchik O, Iyer R G, Kanatzidis M G, et al. Z. Anorg. Allg. Chem., 2004,630:2237-2247
8. [8]
  [8] Liu G N, Jiang X M, Guo G C, et al. Inorg. Chem., 2011,50: 5740-5746
9. [9]
  [9] Zhang R C, Yao H G, An Y L, et al. Chem. Commun., 2010, 46:4550-4552
10. [10]
  [10] Marking G A, Evain M, Kanatzidis M G, et al. J. Solid State Chem., 1998,141:17-28
11. [11]
  [11] Liao J H, Varotsis C, Kanatzidis M G. Inorg. Chem., 1993, 32:2453-2462
12. [12]
  [12] Kanatzidis M G. Chem. Mater., 1990,2:353-363
13. [13]
  [13] Jiang T, Lough A, Bedard R L, et al. J. Mater. Chem., 1998,8:721-732
14. [14]
  [14] Jiang T, Ozin G A. J. Mater. Chem., 1998,8:1099-1108
15. [15]
  [15] Sheldrick W S, Wachhold M. Angew. Chem. Int. Ed., 1997, 36:206-224
16. [16]
  [16] Sheldrick W S, Wachhold M. Cood. Chem. Rev., 1998,176: 211-322
17. [17]
  [17] Devi M S, Vidyasagar K. J. Chem. Soc. Dalton Trans., 2002, 2092-2096
18. [18]
  [18] Palchik O, Iyer R G, Kanatzidis M G, et al. Inorg. Chem., 2003,42:5052-5054
19. [19]
  [19] Löken S, Tremel W. Z. Anorg. Allg. Chem., 1998,624:1588- 1594
20. [20]
  [20] Marking G A, Hanko J A, Kanatzidis M G. Chem. Mater., 1998,10:1191-1199
21. [21]
  [21] Liao J H, Kanatzidis M G. Chem. Mater., 1993,5:1561-1569
22. [22]
  [22] Behrens M, Ordolff M E, Bensch W, et al. Inorg. Chem., 2010,49:8305-8309
23. [23]
  [23] Manos M J, Kanazidis M G. Inorg. Chem., 2009,48:4658- 4660
24. [24]
  [24] Pienack N, Nther C, Bensch W. Solid State Sci., 2007,9: 100-107
25. [25]
  [25] Pienack N, Nther C, Bensch W, et al. Inorg. Chem., 2008, 47:9606-9611
26. [26]
  [26] Pienack N, Bensch W. Z. Anorg. Allg. Chem., 2006,632: 1733-1736
27. [27]
  [27] Pienack N, Mller K, Bensch W, et al. Solid State Sci., 2007,9:1110-1114
28. [28]
  [28] AnY L, Ji M, Baiyin M H, et al. Inorg. Chem., 2003,42: 4248-4249
29. [29]
  [29] Baiyin M H, An Y L, Liu X, et al. Inorg. Chem., 2004,43: 3764-3765
30. [30]
  [30] Baiyin M H, Ye L, An Y L, et al. Bull. Chem. Soc. Jpn., 2005,78:1283-1284
31. [31]
  [31] An Y L, Baiyin M H, Ye L, et al. Inorg. Chem. Commun., 2005,8:301-303
32. [32]
  [32] Wang Y Y, Baiyin M H, An Y L, et al. Chem. Res. Chinese Universities, 2006,22:411-414
33. [33]
  [33] Baiyin M H, Liang F Y, Xu X Q, et al. Chem. Res. Chinese Universities, 2011,27:915-918
34. [34]
  [34] Sheldrick G M. SHELXS97 and SHELXL97, Program Suite for the Solution and Refinement of Crystal Structures, University of Gttingen, Germany, 1997
35. [35]
  [35] Albertelli-II G D, Cowen J A, Kanatzidis M G, et al. Phys. Rev. B, 1997-I,55:11056-11059
36. [36]
  [36] Teske C L. Z. Anorg. Allg. Chem., 1980,460:163-168
37. [37]
  [37] An Y L, Ye L, Baiyin M H, et al. J. Solid State Chem., 2004,177:2506-2510
38. [38]
  [38] Yaghi O M, Sun Z, Richrdson D A, et al. J. Am. Chem. Soc., 1994,116:807-808
39. [39]
  [39] Tan K, Darovsky A, Parise J B. J. Am. Chem. Soc., 1995, 117:7039-7040
40. [40]
  [40] Nellis D M, Ko Y, Parise J B, et al. J. Chem. Soc. Chem. Commun., 1995,186:541-542
41. [41]
  [41] Parise J B, Tan K. Chem. Commun., 1996,194:1687-1688
42. [42]
  [42] Cahill C L, Parise J B. Chem. Mater., 1997,9:807-811
43. [43]
  [43] Bowes C L, Huynh W U, Kirkby S J. Chem. Mater., 1996,8: 2147-2152
44. [44]
  [44] MacLachlan M J, Coombs N, Bedard R L, et al. J. Am. Chem. Soc., 1999,121:12005-12017
45. [45]
  [45] Bonhomme F, Kanatzidis M G. Chem. Mater., 1998,10: 1153-1159
1. [1]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
2. [2]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
3. [3]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
4. [4]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
5. [5]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
6. [6]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
7. [7]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
8. [8]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
9. [9]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
10. [10]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
11. [11]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
12. [12]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
13. [13]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
14. [14]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
15. [15]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
16. [16]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
17. [17]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
18. [18]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
19. [19]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
20. [20]
  Shenhao QIU , Qingquan XIAO , Huazhu TANG , Quan XIE . First-principles study on electronic structure, optical and magnetic properties of rare earth elements X (X=Sc, Y, La, Ce, Eu) doped with two-dimensional GaSe. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2250-2258. doi: 10.11862/CJIC.20240104

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(889)
HTML views(82)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Solvothermal Synthesis and Crystal Structure of K2CdSnS4

Metrics

通讯作者: 陈斌, bchen63@163.com

Solvothermal Synthesis and Crystal Structure of K₂CdSnS₄