Citation: ZHANG Ji-Cai, LI Ying-Nan, HUANG Di, XU Fang-Yuan, CHENG Xiao-Shan, YOU Zhong-Lu. Alternate Arrangement of Cl and Br Substituent Groups in Crystal Packing：Syntheses and Structures of Schiff Bases and Their Copper(Ⅱ) Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2014, (2): 425-430. doi: 10.11862/CJIC.2014.004 shu

Alternate Arrangement of Cl and Br Substituent Groups in Crystal Packing：Syntheses and Structures of Schiff Bases and Their Copper(Ⅱ) Complexes

1.
1 Department of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China;

Corresponding author: YOU Zhong-Lu,
Received Date: 29 April 2013
Available Online: 13 September 2013
Fund Project:

Two new Schiff bases, N,N'-bis(5-chlorosalicylidene)-1,3-diaminopentane (H₂CAP) and N,N'-bis(5-bromosalicylidene)-1,3-diaminopentane (H₂BAP), and their copper(Ⅱ) complexes, [Cu(CAP)] (1), [Cu(BAP)] (2) and [Cu(CAP)_0.5(BAP)_0.5] (3), have been prepared and structurally characterized by elemental analysis, IRand electronic spectroscopy. The complexes have also been characterized by single-crystal X-ray diffraction studies. The Cu atom in each of the complexes is in a tetrahedrally distorted square planar coordination. By combination of complex 1 and 2, a new aggregation 3 was formed. There are interesting alternate arrangement of Cl and Br substituent groups in the crystal packing of the aggregation. CCDC: 889058, 1; 889059, 2; 889057, 3.
- Schiff base;copper complex;self-assembly;complex aggregation;mononuclear complex
1. [1]
  [1] ZHANG Yan(张燕), XIONG Bi(熊碧), CAI Ping(蔡苹), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(11):2437- 2443
2. [2]
  [2] Lu Y, Shi D H, You Z L, et al. J. Coord. Chem., 2012,65: 339-352
3. [3]
  [3] PU Xiao-Hua(蒲小华). Chinese J. Inorg. Chem.(无机化学学报), 2012,28(10):2211-2216
4. [4]
  [4] ZHANG Qi-Long(张奇龙), ZHU Xing-Cheng(朱兴城), XU Hong(徐红), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(6):1151-1156
5. [5]
  [5] Mandal S, Saha R, Mahanti B, et al. Inorg. Chim. Acta, 2012,387:1-7
6. [6]
  [6] LUO Xin-Ze(罗新泽), ZHOU Hong-Bo(周洪波). Chinese J. Inorg. Chem.(无机化学学报), 2012,28(6):1183-1189
7. [7]
  [7] Kumar G, Devi S, Johari R, et al. Eur. J. Med. Chem., 2012, 52:269-274
8. [8]
  [8] Di Bella S, Oliveri I P, Colombo A, et al. Dalton Trans., 2012,41:7013-7016
9. [9]
  [9] You Z L, Sun H, Ding B W, et al. J. Coord. Chem., 2011,64: 3510-3520
10. [10]
  [10] YOU Zhong-Lu(由忠录), XIAN Dong-Mei(献冬梅), ZHANG Mei(张梅), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(6):1271-1278
11. [11]
  [11] Zhang M, Xian D M, Zhang N, et al. Struct. Chem., 2012, 23:1489-1496
12. [12]
  [12] You Z L, Ni L L, Shi D H, et al. Eur. J. Med. Chem., 2010, 45:3196-3199
13. [13]
  [13] You Z L, Lu Y, Zhang N, et al. Polyhedron, 2011,30:2186- 2194
14. [14]
  [14] Bruker, SMART and SAINT. Bruker AXS Inc, Madison, 2002.
15. [15]
  [15] Sheldrick G M. SADABS. University of Göttingen, Germany, 1996.
16. [16]
  [16] Sheldrick G M. SHELXTL V5.1, Software Reference Manual, Bruker AXS Inc, Madison, 1997.
17. [17]
  [17] Lal R A, Choudhury S, Ahmed A, et al. J. Coord. Chem., 2009,62:3864-3874
18. [18]
  [18] Zhou Y M, Ye X R, Xin F B, et al. Transition Met. Chem., 1999,24:118-120
19. [19]
  [19] Patil S A, Naik V H, Kulkarni A D, et al. Spectrochim. Acta A, 2010,75:347-354
20. [20]
  [20] DAI Mei-Bi(戴美碧), ZHANG Qi-Long(张奇龙), ZHU Xing- Cheng(朱兴城), et al. Chinese J. Inorg. Chem.(无机化学学报), 2008,24(9):1381-1386
21. [21]
  [21] Heshmatpour F, Rayati S, Hajiabbas M A, et al. Polyhedron, 2012,31:443-450
22. [22]
  [22] Szlyk E, Barwiolek M, Kruszynski R, et al. Inorg. Chim. Acta, 2005,358:3642-3652
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沈阳化工大学材料科学与工程学院沈阳 110142