Citation: LU Wen-Guan, LIU Hong-Wen, FAN Zhi-Xuan, LAI Xiu-Xia, YANG Xiao-Yun, TAN Guo-Can. Synthesis, Structure and Property of a 3D Cd(Ⅱ) Coordination Polymer Based on Mixed-Ligands of Imidazole-4,5-Dicarboxylate and 1,4-Benzenedicarboxylate[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(3): 591-596. doi: 10.11862/CJIC.2014.003 shu

Synthesis, Structure and Property of a 3D Cd(Ⅱ) Coordination Polymer Based on Mixed-Ligands of Imidazole-4,5-Dicarboxylate and 1,4-Benzenedicarboxylate

1.
Department of Chemistry, Shaoguan University, Shaoguan, Guangdong 512005, China

Received Date: 20 February 2013
Available Online: 18 September 2013
Fund Project: 国家自然科学基金(No.21071099) (No.21071099)2012年广东省大学生创新训练计划(No.gdcxcy2012-28)资助项目。 (No.gdcxcy2012-28)

Reaction of CdCl₂ with mixed-ligands of imidazole-4,5-dicarboxylic acid (H₃IDC) and 1,4-benzenedicar-boxylic acid (H₂BDC) under hydrothermal condition, yielded a new 3D cadmium(Ⅱ) coordination polymer of[Cd₂(HIDC)(BDC)(H₂O)]_n(1), which was structurally characterized by elemental analysis, infrared spectroscopy, powder X-ray diffraction, and single-crystal X-ray diffraction. The result of single-crystal X-ray diffraction analysis reveals that complex 1 crystallizes in the monoclinic crystal system with P2₁/n space group, a=0.884 34(2) nm, b=1.577 50(3) nm, c=1.071 58(3) nm, β=97.227(2), V=1.483 03(6) nm³, Z=4, D_c=2.513 g·cm^-3, F(000)=1 072, the final R₁=0.031 5, wR₂=0.053 1 for 2 674 observed reflections with I>2σ(I). In complex 1, the interconnection of Cd(Ⅱ) ions by carboxylate oxygen atoms from BDC^2- ligands result in an infinite 1D polymeric chain of {[Cd₂(CO₂)]₂(CO₂)₂}_n along a axis. The polymeric chains are further connected by HIDC^2- and BDC^2- bridging ligands to form a complicated 3D metal-organic framework architecture. Furthermore, its thermal stability and luminescent property at room temperature in the solid state were also investigated. CCDC: 923674.
- coordination polymer;mixed-ligands;crystal structure;luminescent property
1. [1]
  [1] Lin Z Z, Jiang F L, Chen L, et al. Cryst. Growth Des., 2007,7:1712-1715
2. [2]
  [2] Lu W G, Jiang L, Feng X L, et al. Inorg. Chem., 2009,48: 6997-6999
3. [3]
  [3] Gong Y N, Meng M, Zhong D C, et al. Chem. Commun., 2012,48:12002-12004
4. [4]
  [4] Han Z B, Lu R Y, Liang Y F, et al. Inorg. Chem., 2012,51: 674-679
5. [5]
  [5] Guo X D, Zhu G S, Fang Q R, et al. Inorg. Chem., 2005,44: 3850-3855
6. [6]
  [6] He J H, Yu J H, Zhang Y T, et al. Inorg. Chem., 2005,44: 9279-9282
7. [7]
  [7] LU Wen-Guan (卢文贯), LIU Hong-Wen (刘宏文). Chinese J. Inorg. Chem. (无机化学学报), 2010,26(8):1450-1456
8. [8]
  [8] Cheng X N, Zhang W X, Lin Y Y, et al. Adv. Mater., 2007, 19:1494-1498
9. [9]
  [9] Kuppler R J, Timmons D J, Fang Q R, et al. Coord. Chem. Rev., 2009,253:3042-3066
10. [10]
  [10] Dai J C, Wu X T, Fu Z Y, et al. Chem. Commun., 2002: 12-13
11. [11]
  [11] Sudik A C, Cté A P, Yaghi O M. Inorg. Chem., 2005,44: 2998-3000
12. [12]
  [12] Weng D F, Zheng X J, Jin L P. Eur. J. Inorg. Chem., 2006: 4184-4190
13. [13]
  [13] Guo X D, Zhu G S, Sun F X, et al. Inorg. Chem., 2006,45: 2581-2587
14. [14]
  [14] Sun J Y, Zhou Y M, Fang Q R, et al. Inorg. Chem., 2006,45:8677-8684
15. [15]
  [15] Yang G D, Dai J C, Lian Y X, et al. Inorg. Chem., 2007,46: 7910-7916
16. [16]
  [16] Yang X P, Jones R A, Rivers J H. Dalton Trans., 2007: 3936-3942
17. [17]
  [17] Fang R Q, Zhang X H, Zhang X M. Cryst. Growth Des., 2006,6:2637-2639
18. [18]
  [18] Zhang M B, Chen Y M, Zheng S T, et al. Eur. J. Inorg. Chem., 2006:1423-1428
19. [19]
  [19] Zhong R Q, Zou R Q, Xu Q. Micropor. Mesopor. Mater., 2007,102:122-127
20. [20]
  [20] Gu J Z, Lu W G, Jiang L, et al. Inorg. Chem., 2007,46: 5835-5837
21. [21]
  [21] Xu Q, Zou R Q, Zhong R Q, et al. Cryst. Growth Des., 2008,8:2458-2463
22. [22]
  [22] Alkordi M H, Liu Y L, Larsen R W, et al. J. Am. Chem. Soc., 2008,130:12639-12641
23. [23]
  [23] Gurunatha K L, Uemura K, Maji T K. Inorg. Chem., 2008, 47:6578-6580
24. [24]
  [24] Gu Z G, Cai Y P, Fang H C, et al. Chem. Commun., 2010, 46:5373-5375
25. [25]
  [25] YUAN Li (袁利), LU Wen-Guan (卢文贯). Chinese J. Inorg. Chem. (无机化学学报), 2011,27(7):1324-1328
26. [26]
  [26] Zheng S R, Cai S L, Yang Q Y, et al. Inorg. Chem. Commun., 2011,14:826-830
27. [27]
  [27] Chen W, Wang J Y, Chen C, et al. Inorg. Chem., 2003,42: 944-946
28. [28]
  [28] Zeng M H, Wu M C, Liang H, et al. Inorg. Chem., 2007,46: 7241-7243
29. [29]
  [29] Luo F, Che Y X, Zheng J M. Cryst. Growth Des., 2008,8: 2006-2010
30. [30]
  [30] Zeng M H, Zhou Y L, Wu M C, et al. Inorg. Chem., 2010, 49:6436-6442
31. [31]
  [31] Gu Z G, Wang M F, Peng H M, et al. Inorg. Chem. Commun., 2010,13:1439-1444
32. [32]
  [32] Lu W G, Deng J H, Zhong D C. Inorg. Chem. Commun., 2012,20:312-316
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沈阳化工大学材料科学与工程学院沈阳 110142