Citation: Dong-mei Cui. Studies on Homo- and Co-polymerizations of Polar and Non-polar Monomers Using Rare-earth Metal Catalysts[J]. Acta Polymerica Sinica, ;2020, 51(1): 12-29. doi: 10.11777/j.issn1000-3304.2020.19142 shu

Studies on Homo- and Co-polymerizations of Polar and Non-polar Monomers Using Rare-earth Metal Catalysts

Dong-mei Cui ^,

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Corresponding author: Dong-mei Cui, dmcui@ciac.ac.cn
Received Date: 31 July 2019
Revised Date: 28 August 2019
Available Online: 23 October 2019

The homo- and co-polymerizations of polar and non-polar monomers, since they can remain the stereo-regularity of the non-polyolefin precursors and meanwhile introduce polar groups into the non-polar polyolefins to improve their surface properties or bring unpredicted new functionalities, have attracted great attention of both academia and industries. However, polar groups are Lewis-basic while the catalysts employed in the polymerizations are usually Lewis acidic, which are prone to interact with the catalytic metal center to poison the catalysts, thus the study on homo- and co-polymerizations has been a challenging project. To date, many achievements have been obtained, and the following research should focus on realizing the homopolymerizations of polar monomers, increasing the activity and insertion ratio of the polar monomer in the copolymers, regulating the polar monomer composition and distribution along the copolymer macromolecular chains and isolating high molecular weight and practically available products. In this review, we summarized the recent developments of our group on the homo- and co-polymerizations of polar monomers, in particular polar styrenes and conjugated dienes with styrene, ethylene, butadien, isoprene and other popular nonpolar olefins, aiming to provide the readers novel strategies for designing new catalysts and polar monomers, as well as the unprecedented mechanisms.
- Rare-earth metal catalyst,
- Coordination polymerization,
- Polar monomer,
- Conjugated dienes,
- Polyolefin
1. [1]
  Zhang Yongjie(张勇杰), Li Huayi(李化毅), Dong Jinyong(董金勇), Hu Youliang(胡友良). Chemistry Advances(化学进展), 2014, 26: 110
2. [2]
  Qiao Jinliang(乔金樑). Chemical Engineering of Petroleum(石油化工), 2015, 44: 1033 doi: 10.3969/j.issn.1000-8144.2015.09.001
3. [3]
  Ouchi M, Terashima T, Sawamoto M. Chem Rev, 2009, 109(11): 4963 − 5050 doi: 10.1021/cr900234b
4. [4]
  Matyjaszewski K, Xia J. Chem Rev, 2001, 101(9): 2921 − 2990 doi: 10.1021/cr940534g
5. [5]
  Baughman T, Chan C, Winey K, Wagener K. Macromolecules, 2007, 40(18): 6564 − 6571 doi: 10.1021/ma070841r
6. [6]
  Mutlu H, de Espinosa L, Meier M. Chem Soc Rev, 2011, 40(3): 1404 − 1445 doi: 10.1039/B924852H
7. [7]
  Opper K, Wagener K. J Polym Sci, Part A: Polym Chem, 2011, 49(3): 821 − 831
8. [8]
  Franssen N, Bas de Bruin R. Chem Soc Rev, 2013, 42(13): 5809 − 5832 doi: 10.1039/c3cs60032g
9. [9]
  Nakamura A, Anselment T, Claverie J, Goodall B, Jordan R, Mecking S, Rieger B, Sen A, van Leeuwen P, Nozaki K. Chem Res, 2013, 46(7): 1438 − 1449 doi: 10.1021/ar300256h
10. [10]
  Chen E. Chem Rev, 2009, 109(11): 5157 − 5214 doi: 10.1021/cr9000258
11. [11]
  Yang X, Liu C, Wang C, Sun X, Guo Y, Wang X, Wang Z, Xie Z, Tang Y. Angew Chem Int Ed, 2009, 48(43): 8099 − 8102 doi: 10.1002/anie.200903334
12. [12]
  Chen Z, Li J, Tao W, Sun X, Yang X, Tang Y. Macromolecules, 2013, 46(7): 2870 − 2875 doi: 10.1021/ma400283p
13. [13]
  Aaltonen P, Lofgren B. Macromolecules, 1995, 28(15): 5353 − 5357 doi: 10.1021/ma00119a027
14. [14]
  Aaltonen P, Fink G, Lofgren B, Seppala J. Macromolecules, 1996, 29(16): 5255 − 5260 doi: 10.1021/ma951607g
15. [15]
  Imuta J, Kashiwa N, Toda Y. J Am Chem Soc, 2002, 124(7): 1176 − 1177 doi: 10.1021/ja0174377
16. [16]
  Terao H, Ishii S, Mitani M, Tanaka H, Fujita T. Am Chem Soc, 2008, 130(52): 17636 − 17637 doi: 10.1021/ja8060479
17. [17]
  Stehling U, Stein K, Kesti M, Waymouth R. Macromolecules, 1998, 31(7): 2019 − 2027 doi: 10.1021/ma971053c
18. [18]
  Wang X, Wang Y, Shi X, Liu J, Chen C, Li Y. Macromolecules, 2014, 47(2): 552 − 559 doi: 10.1021/ma4022696
19. [19]
  Zhang Y, Mu H, Pan L, Wang X, Li Y. ACS Catal, 2018, 8(7): 5963 − 5976 doi: 10.1021/acscatal.8b01088
20. [20]
  Kesti M, Coates G, Waymouth R. Chem Soc, 1992, 114(24): 9679 − 9680 doi: 10.1021/ja00050a069
21. [21]
  Xu G, Chung T. Macromolecules, 2000, 33(16): 5803 − 5809 doi: 10.1021/ma000303d
22. [22]
  Kim K, Jo W, Kwak S, Kim K, Hwang S, Kim J. Macromolecules, 1999, 32(26): 8703 − 8710 doi: 10.1021/ma991036i
23. [23]
  Ittel S, Johnson L, Brookhart M. Chem Rev, 2000, 100(4): 1169 − 1204 doi: 10.1021/cr9804644
24. [24]
  Nakamura A, Ito S, Nozaki K. Chem Rev, 2009, 109(11): 5215 − 5244 doi: 10.1021/cr900079r
25. [25]
  Johnson L, Killian C, Brookhart M. J Am Chem Soc, 1995, 117(23): 6414 − 6415 doi: 10.1021/ja00128a054
26. [26]
  Johnson L, Mecking S, Brookhart M. J Am Chem Soc, 1996, 118(1): 267 − 268 doi: 10.1021/ja953247i
27. [27]
  Mecking S, Johnson L, Wang L, Brookhart M. J Am Chem Soc, 1998, 120(5): 888 − 899 doi: 10.1021/ja964144i
28. [28]
  Dai S, Sui X, Chen C. Angew Chem Int Ed, 2015, 54(34): 9948 − 9953 doi: 10.1002/anie.201503708
29. [29]
  Dai S, Sui X, Chen C. Chem Commun, 2016, 52: 9113 − 9116 doi: 10.1039/C6CC00457A
30. [30]
  Dai S, Chen C. Angew Chem Int Ed, 2016, 55(42): 13281 − 13285 doi: 10.1002/anie.201607152
31. [31]
  Zhang D, Chen C. Angew Chem Int Ed, 2017, 56(46): 14672 − 14676 doi: 10.1002/anie.201708212
32. [32]
  Li M, Wang X, Luo Y, Chen C. Angew Chem Int Ed, 2017, 56(38): 11604 − 11609 doi: 10.1002/anie.201706249
33. [33]
  Chen M, Chen C. Angew Chem Int Ed, 2018, 57(12): 3094 − 3098 doi: 10.1002/anie.201711753
34. [34]
  Chen Min(陈敏), Chen Changle(陈昶乐). Acta Polymerica Sinica(高分子学报), 2018, (11): 1372 − 1384 doi: 10.11777/j.issn1000-3304.2018.18155
35. [35]
  Tan C, Chen C. Angew Chem Int Ed, 2019, 58(22): 7192 − 7200 doi: 10.1002/anie.201814634
36. [36]
  Wang F, Chen C. Polym Chem, 2019, 10(19): 2354 − 2369 doi: 10.1039/C9PY00226J
37. [37]
  Weng W, Shen Z, Jordan R. J Am Chem Soc, 2007, 129(50): 15450 − 15451 doi: 10.1021/ja0774717
38. [38]
  Luo S, Vela J, Lief G, Jordan R. J Am Chem Soc, 2007, 129(29): 8946 − 8947 doi: 10.1021/ja072562p
39. [39]
  Chen C, Luo S, Jordan R. J Am Chem Soc, 2008, 130(39): 12892 − 12893 doi: 10.1021/ja8056858
40. [40]
  Diamanti S, Ghosh P, Shimizu F, Bazan G. Macromolecules, 2003, 36(26): 9731 − 9735 doi: 10.1021/ma035102z
41. [41]
  Diamanti S, Khanna V, Hotta A, Yamakawa D, Shimizu F, Kramer E, Fredrickson G, Bazan G. J Am Chem Soc, 2004, 126(34): 10528 − 10529 doi: 10.1021/ja047231g
42. [42]
  Schneider Y, Azoulay J, Coffin R, Bazan G. J Am Chem Soc, 2008, 130(32): 10464 − 10465 doi: 10.1021/ja803006d
43. [43]
  Coffin R, Schneider Y, Kramer E, Bazan G. J Am Chem Soc, 2010, 132(39): 13869 − 13878 doi: 10.1021/ja1056938
44. [44]
  Younkin T, Conner E, Henderson J, Friedrich S, Grubbs R, Bansleben D. Science, 2000, 287(462): 460 − 462
45. [45]
  Connor E, Younkin T, Henderson J, Hwanf S, Grubbs R, Roberts W, Litzau J. J Polym Sci, Part A: Polym Chem, 2002, 40(16): 2842 − 2854 doi: 10.1002/pola.10370
46. [46]
  Waltman A, Younkin T, Grubbs R. Organometallics, 2004, 23(22): 5121 − 5123 doi: 10.1021/om049360b
47. [47]
  Carrow B, Nozaki K. J Am Chem Soc, 2012, 134(21): 8802 − 8805 doi: 10.1021/ja303507t
48. [48]
  Sakai N, Nozaki K, Takaya H. J Am Chem Soc, 1994, 116(4): 395 − 396
49. [49]
  Konishi Y, Tao W, Yasuda H, Ito S, Oishi Y, Ohtaki H, Tanna A, Tayano T, Nozaki K. ACS Macro Lett, 2018, 7(2): 213 − 217 doi: 10.1021/acsmacrolett.7b00904
50. [50]
  Ota Y, Ito S, Kobayashi M, Kitade S, Sakata K, Tayano T, Nozaki K. Angew Chem Int Ed, 2016, 55(26): 7505 − 7509 doi: 10.1002/anie.201600819
51. [51]
  Kawakami T, Ito S, Nozaki K. Dalton T, 2015, 44(47): 20745 − 20752 doi: 10.1039/C5DT03551A
52. [52]
  Drent E, van Dijk R, van Ginkel R, van Oort B, Pugh R. Chem Commun, 2002, (7): 744 − 745 doi: 10.1039/b111252j
53. [53]
  Skupov K, Marella P, Simard M, Yap G, Allen N, Conner D, Goodall B, Claverie J. Macromol Rapid Commun, 2007, 28(20): 2033 − 2038 doi: 10.1002/marc.200700370
54. [54]
  Nakano R, Nozaki K. J Am Chem Soc, 2015, 137(28): 10934 − 10942
55. [55]
  Ito S, Kanazawa M, Munakata K, Kuroda J, Okumura Y, Nozaki K. J Am Chem Soc, 2011, 133(5): 1232 − 1235 doi: 10.1021/ja1092216
56. [56]
  Ito S, Munakata K, Nakamura A, Nozaki K. J Am Chem Soc, 2009, 131(41): 14606 − 14607 doi: 10.1021/ja9050839
57. [57]
  Kochi T, Noda S, Yoshimura K, Nozaki K. J Am Chem Soc, 2007, 129(29): 8948 − 8949 doi: 10.1021/ja0725504
58. [58]
  Masusa Y, Hasegawa M, Yamashita M, Nozaki K, Ishida N, Murakami M. J Am Chem Soc, 2013, 135(19): 7142 − 7145 doi: 10.1021/ja403461f
59. [59]
  Ota Y, Ito S, Kuroda J, Okumura Y, Nozaki K. J Am Chem Soc, 2014, 136(34): 11898 − 11901 doi: 10.1021/ja505558e
60. [60]
  Berkefeld A, Mecking S. Angew Chem Int Ed, 2008, 47(14): 2538 − 2542 doi: 10.1002/anie.200704642
61. [61]
  Guironnet D, Roesle P, Runzi T, Göttker-Schnetmann I, Mecking S. J Am Chem Soc, 2009, 131(2): 422 − 423 doi: 10.1021/ja808017n
62. [62]
  Guironnet D, Caporaso L, Neuwald B, Goöttker-Schnetmann I, Cavallo L, Mecking S. J Am Chem Soc, 2010, 132(12): 4418 − 4426 doi: 10.1021/ja910760n
63. [63]
  Ruünzi T, Froöhlich D, Mecking S. J Am Chem Soc, 2010, 132(50): 17690 − 17691 doi: 10.1021/ja109194r
64. [64]
  Friedberger T, Wucher P, Mecking S. J Am Chem Soc, 2012, 134(2): 1010 − 1018 doi: 10.1021/ja207110u
65. [65]
  Jian Zhongbao(简忠保). Acta Polymerica Sinica(高分子学报), 2018, (11): 1359 − 1371 doi: 10.11777/j.issn1000-3304.2018.18146
66. [66]
  Jian Z, Baier M, Mecking S. J Am Chem Soc, 2015, 137(8): 2836 − 2839 doi: 10.1021/jacs.5b00179
67. [67]
  Jian Z, Mecking S. Angew Chem Int Ed, 2015, 54(52): 15845 − 15849 doi: 10.1002/anie.201508930
68. [68]
  Jing Y, Sheares V. Macromolecules, 2000, 33(17): 6255 − 6261 doi: 10.1021/ma9918046
69. [69]
  Jing Y, Sheares V. Macromolecules, 2000, 33(17): 6262 − 6268 doi: 10.1021/ma0002287
70. [70]
  Yang Y, Lee J, Cho M, Sheares V. Macromolecules, 2006, 39(25): 8625 − 8631 doi: 10.1021/ma061249p
71. [71]
  Beery M. Rath M, Sheares V Macromolecules, 2001, 34(8): 2469 − 2475 doi: 10.1021/ma001491a
72. [72]
  Takenaka K, Hanada K, Shiomi T. Macromolecules, 1999, 32(12): 3875 − 3877 doi: 10.1021/ma981506t
73. [73]
  Yaegashi T, Takeshita H, Takenaka K, Shiomi T. J Polym Sci Part A: Polym Chem, 2003, 41(10): 1545 − 1552 doi: 10.1002/pola.10675
74. [74]
  Yaegashi T, Yodoya S, Nakamura M, Takeshita H, Takenaka K, Shiomi T. J Polym Sci, Part A: Polym Chem, 2004, 42(4): 999 − 1007 doi: 10.1002/pola.11051
75. [75]
  Takenaka K, Hirao A, Hattori T, Nakahama S. Macromolecules, 1987, 20(8): 2034 − 2035 doi: 10.1021/ma00174a062
76. [76]
  Takenaka K, Hirao A, Hattori T, Nakahama S. Macromolecules, 1989, 22: 1563 − 1567 doi: 10.1021/ma00194a010
77. [77]
  Hirao A, Hiraishi Y, Nakahama S, Takenaka K. Macromolecules, 1998, 31(2): 281 − 287 doi: 10.1021/ma971214c
78. [78]
  Natta G, Dall′Asta G, Mazzanti G, Casale A. Makromol Chem, 1962, 58(1): 217 − 225 doi: 10.1002/macp.1962.020580115
79. [79]
  Kawamura T, Uryu T, Matsuzaki K. Makromol Chem, 1982, 183(1): 125 − 141 doi: 10.1002/macp.1982.021830111
80. [80]
  Li D, Li S, Cui D, Zhang X. Organometallics, 2010, 29(9): 2186 − 2193 doi: 10.1021/om100100r
81. [81]
  Liu D, Yao C, Wang R, Wang M, Wang Z, Wu C, Lin F, Li S, Wan X, Cui D. Angew Chem Int Ed, 2015, 54(17): 5205 − 5209 doi: 10.1002/anie.201412166
82. [82]
  Chai Y, Wang L, Liu D, Wang Z, Run M, Cui D. Chem Eur J, 2019, 25(8): 2043 − 2050 doi: 10.1002/chem.201805012
83. [83]
  Malanga M. Adv Mater, 2000, 12(23): 1869 − 1872 doi: 10.1002/1521-4095(200012)12:23<1869::AID-ADMA1869>3.0.CO;2-#
84. [84]
  Shi X, Nishiura M, Hou Z. Angew Chem Int Ed, 2016, 55(47): 14812 − 14817 doi: 10.1002/anie.201609065
85. [85]
  Liu D, Wang R, Wang M, Wu C, Wang Z, Yao C, Liu B, Wan X, Cui D. Chem Commun, 2015, 51(22): 4685 − 4688 doi: 10.1039/C5CC00470E
86. [86]
  Liu D, Wang M, Chai Y, Wan X, Cui D. ACS Catal, 2019, 9(3): 2618 − 2625 doi: 10.1021/acscatal.9b00555
87. [87]
  Wang Z, Liu D, Cui D. Macromolecules, 2016, 49(3): 781 − 787 doi: 10.1021/acs.macromol.5b02263
88. [88]
  Lang X, Jia W, Wang Y, Zhu Z. Catal Commun, 2015, 70: 58 − 61 doi: 10.1016/j.catcom.2015.07.017
89. [89]
  Ishihara N, Kuramoto M, Uoi M. Macromolecules, 1988, 21(12): 3356 − 3360 doi: 10.1021/ma00190a003
90. [90]
  Wang Z, Wang M, Liu J, Liu D, Cui D. Chem Eur J, 2017, 23(72): 18151 − 18155 doi: 10.1002/chem.201704584
91. [91]
  Soga K, Nakatani H, Monoi T. Macromolecules, 1990, 23(4): 953 − 957 doi: 10.1021/ma00206a009
92. [92]
  Grassi A, Longo P, Proto A, Zambelli A. Macromolecules, 1989, 22(1): 104 − 108 doi: 10.1021/ma00191a021
93. [93]
  Liu D, Wang M, Wang Z, Wu C, Pan Y, Cui D. Angew Chem Int Ed, 2017, 56(10): 2714 − 2719 doi: 10.1002/anie.201611066
94. [94]
  Li S, Liu D, Wang Z, Cui D. ACS Catal, 2018, 8(7): 6086 − 6093 doi: 10.1021/acscatal.8b00885
95. [95]
  Wang C, Luo G, Nishiura M, Song G, Yamamoto A, Luo Y, Hou Z. Sci Adv, 2017, 3(7): e1701011 doi: 10.1126/sciadv.1701011
96. [96]
  Guo N, Stern C, Marks T. J Am Chem Soc, 2008, 130(7): 2246 − 2261 doi: 10.1021/ja076407m
97. [97]
  Liu B, Qiao K, Fang J, Wang T, Wang Z, Liu D, Xie Z, Maron L, Cui D. Angew Chem Int Ed, 2018, 57(45): 14896 − 14901 doi: 10.1002/anie.201808836
98. [98]
  Payne A. J Appl Polym Sci, 1962, 6(19): 57 − 63 doi: 10.1002/app.1962.070061906
99. [99]
  Payne A. J Appl Polym Sci, 1962, 6(21): 368 − 372 doi: 10.1002/app.1962.070062115
100. [100]
  Sheares V, Wu L, Li Y, Emmick T. J Polym Sci, Part A: Polym Chem, 2000, 38(22): 4070 − 4080 doi: 10.1002/1099-0518(20001115)38:22<4070::AID-POLA70>3.0.CO;2-P
101. [101]
  Hirao A, Goseki R, Ishizone T. Macromolecules, 2014, 47(6): 1883 − 1905 doi: 10.1021/ma401175m
102. [102]
  Wu L, Sheares V. J Polym Sci Part A: Polym Chem, 2001, 39(19): 3227 − 3238 doi: 10.1002/pola.1305
103. [103]
  Yao C, Liu N, Long S, Wu C, Cui D. Polym Chem, 2016, 7(6): 1264 − 1270 doi: 10.1039/C5PY01801C
104. [104]
  Leicht H, Göttker-Schnetmann I, Mecking S. ACS Macro Lett, 2016, 5(6): 777 − 780 doi: 10.1021/acsmacrolett.6b00321
105. [105]
  Long S, Lin F, Yao C, Cui D. Macromol Rapid Commun, 2017, 38(17): 1700227 doi: 10.1002/marc.201700227
106. [106]
  Li L, Li S, Cui D. Macromolecules, 2016, 49(4): 1242 − 1251 doi: 10.1021/acs.macromol.5b02654
107. [107]
  Li L, Li S, Cui D. J Polym Sci, Part A: Polym Chem, 2017, 55(6): 1031 − 1039 doi: 10.1002/pola.28463
1. [1]
  Xunzhang Fan , Yuanjin Zhao , Shufang Luo , Aihua He . Karl Ziegler: A Pioneer in the Polyolefin Industry – Commemorating the 50th Anniversary of the German Chemist’s Passing. University Chemistry, 2024, 39(8): 389-394. doi: 10.3866/PKU.DXHX202312065
2. [2]
  Lilong Gao , Yuhao Zhai , Dongdong Zhang , Linjun Huang , Kunyan Sui . Exploration of Thiol-Ene Click Polymerization in Polymer Chemistry Experiment Teaching. University Chemistry, 2025, 40(4): 87-93. doi: 10.12461/PKU.DXHX202405143
3. [3]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
4. [4]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
5. [5]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . 基于激发态手性铜催化的烯烃E→Z异构的动力学拆分——推荐一个本科生综合化学实验. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
6. [6]
  Hongling Yuan , Jialin Xie , Jiawei Wang , Jixiang Zhao , Jiayan Liu , Qing Feng , Wei Qi , Min Liu . Cyclic Olefin Copolymer (COC): The Agile Vanguard in the Realm of Materials. University Chemistry, 2024, 39(7): 294-298. doi: 10.12461/PKU.DXHX202311041
7. [7]
  Zhenxing Liu , Jiaen Hu , Zishi Cheng , Xinqi Hao . 基础有机化学教学中烯烃的氧化反应. University Chemistry, 2025, 40(6): 139-144. doi: 10.12461/PKU.DXHX202408107
8. [8]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
9. [9]
  Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052
10. [10]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
11. [11]
  Zihao Guo , Shichen Ma , Kin Shing Chan . 烯烃环化反应中6电子试剂的等瓣相似性和等电子关系. University Chemistry, 2025, 40(6): 160-166. doi: 10.12461/PKU.DXHX202408038
12. [12]
  Jiamin Li , Wenyue Zhong , Kin Shing Chan . “烯”君入瓮又入学——据元素周期表与酸碱理论谈烯烃教学. University Chemistry, 2025, 40(6): 177-182. doi: 10.12461/PKU.DXHX202408040
13. [13]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . Hollow structured photocatalysts. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-. doi: 10.1016/j.actphy.2025.100071
14. [14]
  Fanpeng Meng , Fei Zhao , Jingkai Lin , Jinsheng Zhao , Huayang Zhang , Shaobin Wang . 优化氮化碳纳米片/球形共轭聚合物S型异质结界面电场以促进析氢反应. Acta Physico-Chimica Sinica, 2025, 41(8): 100095-. doi: 10.1016/j.actphy.2025.100095
15. [15]
  Danqing Wu , Jiajun Liu , Tianyu Li , Dazhen Xu , Zhiwei Miao . Research Progress on the Simultaneous Construction of C—O and C—X Bonds via 1,2-Difunctionalization of Olefins through Radical Pathways. University Chemistry, 2024, 39(11): 146-157. doi: 10.12461/PKU.DXHX202403087
16. [16]
  Weina Wang , Lixia Feng , Fengyi Liu , Wenliang Wang . Computational Chemistry Experiments in Facilitating the Study of Organic Reaction Mechanism: A Case Study of Electrophilic Addition of HCl to Asymmetric Alkenes. University Chemistry, 2025, 40(3): 206-214. doi: 10.12461/PKU.DXHX202407022
17. [17]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
18. [18]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
19. [19]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
20. [20]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(3278)
HTML views(339)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Studies on Homo- and Co-polymerizations of Polar and Non-polar Monomers Using Rare-earth Metal Catalysts

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com