Citation: Ya-li Wang, Bing-xue Liu, Guo-feng Tian, Sheng-li Qi, De-zhen Wu. Research Progress of Cathode Binder for High Performance Lithium-ion Battery[J]. Acta Polymerica Sinica, ;2020, 51(4): 326-337. doi: 10.11777/j.issn1000-3304.2019.19215 shu

Research Progress of Cathode Binder for High Performance Lithium-ion Battery

Ya-li Wang ¹ ,
Bing-xue Liu ³ ,
Guo-feng Tian ^{1, 2} ,
Sheng-li Qi ^{1, 2,,} ,
De-zhen Wu ^{1, 2}

1.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029
2.
Changzhou Institute of Advanced Materials, Beijing University of Chemical Technology, Changzhou 213164
3.
China Automotive Battery Research Institute Co., Beijing 101407

Corresponding author: Sheng-li Qi, qisl@mail.buct.edu.cn
Received Date: 23 December 2019
Revised Date: 17 January 2020
Available Online: 24 March 2020

Figures(11)

Developing high-performance battery systems requires the collaborative optimization of every battery components, including electrodes, electrolyte, separators and binder systems. The strategies of synthesizing electrode materials and developing novel electrolyte system are widely investigated. Cathode binder, a crucial material to maintain structure stability of cathode, plays an essential role in efficiently enhancing energy density and ensuring safety of lithium ion battery. In recent years, designing advanced binder systems has attracted researchers’ attention. In this account, the research progress on material and structural design of cathode binder and application about cathode binder of lithium ion battery are reviewed comprehensively. The effects that cathode binders play on stabilizing cathode material, promoting reduction of battery internal impedance and regulating electrochemical performances of lithium ion battery are primarily introduced. Meanwhile, the characteristics of the oil-soluble binder represented by poly(vinylidene fluoride) (PVDF), polyimide (PI), functional polymer binder and the water-soluble binder represented by poly(acrylic acid) (PAA) and carboxymethyl cellulose (CMC) are concluded in detail. PVDF has good chemical stability and adhesion, but suffers from large swelling ratio; PI has excellent high temperature resistance and good mechanical properties, but the cost is relatively high; functional polymer binder has good electrical conductivity and can effectively suppress the shuttle effect of Li-S lithium batteries, but the preparation process is complicated; PAA is flexible, but mechanical properties are poor; CMC has good dispersibility and large mechanical strength, but it needs to be matched with styrene-butadiene rubber due to the large brittleness. Furthermore, combining with the existing research reports, methods of designing advanced cathode binder systems are concluded to provide valuable guidance for the performance optimization. The development prospects and application exploration are also discussed.
- Lithium-ion battery,
- Cathode binder,
- Poly(vinylidene fluoride),
- Polyimide,
- Functional polymer binder,
- Poly(acrylic acid),
- Carboxymethyl cellulose
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