Citation: Jie Hao, Yu-xia Gao, Hou-rui Chen, Jun Hu, Yong Ju. Sustainable Polymers Based on Natural Terpenes[J]. Acta Polymerica Sinica, ;2020, 51(3): 239-266. doi: 10.11777/j.issn1000-3304.2019.19180 shu

Sustainable Polymers Based on Natural Terpenes

Jie Hao ¹ ,
Yu-xia Gao ³ ,
Hou-rui Chen ¹ ,
Jun Hu ^2,, ,
Yong Ju ^1,,

1.
Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology, Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084
2.
Bejing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029
3.
College of Science, China Agricultural University, Beijing 100094

Corresponding author: Jun Hu, jhu@mail.buct.edu.cn Yong Ju, juyong@mail.tsinghua.edu.cn
Received Date: 10 October 2019
Revised Date: 7 November 2019

Sustainable polymers are a class of materials derived from renewable resources and exhibit closed-loop life cycles. The development of sustainable polymers has been an important research topic to meet the need of nonpetroleum-based materials and to reduce the dependence on fossil fuel over the past decades. Terpenes is a kind of natural products with extensive supply sources and has multiple reactive sites and chiral centers. They can be divided into cyclic monoterpenes, linear monoterpenes and polycyclic terpenes according to the number of isoprene units and skeleton ring in their molecular structures. Such structural characteristic can not only simplify the synthesis of sustainable polymers, but also be used to design sustainable polymers with accurate structure at the molecular level according to a variety of demands. Moreover, natural terpenes can endow sustainable polymers with unique stereochemical structures, good biological activity and biocompatibility, thus broadening their applications in surface coating, biological medicine, and tissue engineering. From the perspective of structural design, there are three main ways to construct natural terpene-based sustainable polymers: (1) main-chain sustainable polymers can be obtained by self-condensation polymerization or co-condensation of terpenes or their derivatives; (2) side-chain sustainable polymers can be obtained by homopolymerization or copolymerization of terpenes with unsaturated functional groups or terpene monomers modified by unsaturated moieties; (3) sustainable polymers end-capped with terpenes can be obtained by modifying the polymer chain end with terpenes or their derivatives. It should be noted that the structure discrepancy between natural terpenes may require different design strategies to create functional sustainable polymers. This paper reviews the progress of natural terpene-based sustainable polymers in recent decades in the order of cyclic monoterpenes, linear monoterpenes and polycyclic terpenes. The main resources, monomer design strategies and polymerization methods of natural terpenes, as well as the characteristics, advantages and potential applications of natural terpene-based sustainable polymers are discussed.
- Natural products,
- Sustainable polymers,
- Terpenes
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沈阳化工大学材料科学与工程学院沈阳 110142

Sustainable Polymers Based on Natural Terpenes

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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