Citation: Shao-shen Xu, Miao Du, Yi-hu Song, Zi-liang Wu, Qiang Zheng. Effect of Sodium Dodecyl Sulfate on the Rheological Behavior of Poly(vinyl alcohol) Aqueous Solution[J]. Acta Polymerica Sinica, ;2020, 51(4): 403-410. doi: 10.11777/j.issn1000-3304.2019.19178 shu

Effect of Sodium Dodecyl Sulfate on the Rheological Behavior of Poly(vinyl alcohol) Aqueous Solution

MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027

Corresponding author: Miao Du, dumiao@zju.edu.cn
Received Date: 29 September 2019
Revised Date: 11 November 2019
Available Online: 16 December 2019

Figures(7)

Rheological behaviors of poly(vinyl alcohol) (PVA) aqueous solution are influenced remarkably by the intermolecular hydrogen bond interaction in the semi-dilute solution region. Owing to the hydrogen bond network, 10 wt% PVA aqueous solution exhibits a high viscosity which limits the development of its solution processing method to some extent. Sodium dodecyl sulfate (SDS), as a surfactant, can destroy the hydrogen bond interaction, thus playing a certain viscosity-reducing role. Based on measuring the critical aggregation concentration (CAC) and critical micelle concentration of SDS in 10 wt% PVA aqueous solution (CMC_P), the steady and dynamic rheological behaviors of PVA-SDS aqueous solution were studied in detail. The concentrations of SDS (c_sur) can influence the rheological behavior of PVA aqueous solution in different ways at various regions. ① c_sur < CAC, the apparent viscosity (η_a) of the solution doesn’t change a lot as the c_sur changes. ② CAC < c_sur < CMC_P, η_a decreases as the c_sur increases. Particularly, η_a reaches the minimum while c_sur = CMC_P and a wider second platform is displayed in this area. ③ c_sur > CMC_P, SDS form micelles that act as physical cross-linking points, and the dynamic storage modulus (G′) of the composite solution also increases significantly. The changes in the hydrogen bond network of the PVA solution was indirectly characterized by the changes of the hydration number measured by Differential Scanning Calorimeter. After introducing SDS, the number of bound water (n) decreases due to the interaction between SDS and PVA. However, n almost keeps constant when c_sur > CMC_P. The viscous activation energy also shows a similar change. When c_sur is much larger, the micelles formed by SDS in water are conducive to the formation of physical cross-linking network, which contribute more to the solution elasticity, leading to the increase of G′ (greater than that of dynamic loss modulus). Compared with the dilute solution, SDS has a greater viscosity reduction effect on the PVA semi-dilute solution.
- Poly(vinyl alcohol),
- Sodium lauryl sulfate,
- Hydrogen bond,
- Rheological behavior
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