Citation: Han Zhao, Qing Shang, Meng Yang, Shuai Jin, Yang-yang Wang, Ning Zhao, Xiao-pin Yin, Cai-ling Ding, Jian Xu. Surface Modification of Ultra-high Molecular Weight Polyethylene Fiber by Catechol-tetraethylenepentamine[J]. Acta Polymerica Sinica, ;2020, 51(3): 287-294. doi: 10.11777/j.issn1000-3304.2019.19172 shu

Surface Modification of Ultra-high Molecular Weight Polyethylene Fiber by Catechol-tetraethylenepentamine

Han Zhao ¹ ,
Qing Shang ¹ ,
Meng Yang ¹ ,
Shuai Jin ^2,3 ,
Yang-yang Wang ^2,3 ,
Ning Zhao ¹ ,
Xiao-pin Yin ^2,3 ,
Cai-ling Ding ^2,3 ,
Jian Xu ^1,2,,

1.
Laboratory of Polymer Chemistry and Physics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190
2.
Shandong Ruyi Technology Group Co., Ltd., Jining 272000
3.
National Engineering Research Center for Spining Technology, Jining 272000

Corresponding author: Jian Xu, jxu@iccas.ac.cn
Received Date: 22 September 2019
Revised Date: 29 October 2019

In recent years, research on interface modification based on dopamine has been greatly developed, but the high price of dopamine limits its practical application. Cheap catechol-tetraethylenepentamine (Cat-TEPA), similar to dopamine, can spontaneously polymerize and then deposit on the surface of various materials, exhibiting strong adhesion, reactivity, and no selectivity to the substrate. Surface modification based on Cat-TEPA has become a universal method suitable for practical applications. In this paper, ultra-high molecular weight polyethylene (UHMWPE) fiber was modified by Cat-TEPA. Transmission electron microscopy (TEM), infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and the static contact angle investigations were used to characterize the structure and performance of the modified fibers. The interfacial shear strength (IFSS) between the fiber and the epoxy resin before and after modification was measured by monofilament extraction experiment. The effects of reactant ratio and reaction time on interface properties were explored and the optimal modification conditions were determined. The results show that Cat-TEPA modification does not affect the crystallization and thermal stability of the fiber, and the surface wettability of the fiber is improved after modification. An optimal IFSS increase of about 44% has been obtained when the molar ratio of Cat-TEPA is 1:4 and reaction time is 24 h.
- Dopamine,
- Catechol,
- Tetraethylenepentamine,
- Ultra-high molecular weight polyethylene,
- Surface modification,
- Shear strength
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