Citation: Tan An, Hui Yu, Li-jun Xu, Zhi-kang Xu, Ling-shu Wan. Modification of Microporous Polymer Membranes via Surface Co-deposition and the Separation Performances[J]. Acta Polymerica Sinica, ;2019, 50(12): 1298-1304. doi: 10.11777/j.issn1000-3304.2019.19086 shu

Modification of Microporous Polymer Membranes via Surface Co-deposition and the Separation Performances

MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027

Corresponding author: Ling-shu Wan, lswan@zju.edu.cn
Received Date: 25 April 2019
Revised Date: 10 June 2019

Surface deposition systems such as dopamine and tannic acid have received great attention in recent years and have been widely applied in surface modification of polymer separation membranes. It is generally accepted that only polyphenols containing catechol structure can effectively form surface coatings. This paper reports a novel surface co-deposition systems based on ferulic acid and Cu²⁺. It should be noted that ferulic acid, a monophenol, contains only one phenolic hydroxyl group, without acatechol structure. Co-deposition coatings were prepared on various substrates, and the effects of composition and deposition time were investigated. Results indicate that the ferulic acid/Cu²⁺ system is able to form coating layer on most substrates. However, the coatings cannot be effectively formed on highly hydrophilic susbtrates such as silica, glass, and quartz. Microporous polypropylene membrane with surface coatings was prepared under optimal deposition conditions, and the surface structure and properties were characterized by field emission scanning electron microscopy (FE-SEM), attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), zeta potential analyzer, and water contact angle measurement. The modified membranes were applied to the separation of oil-in-water emulsions and dye adsorption. The results show that the modified membrane becomes hydrophilic and strongly negatively charged, while the surface porous structure changes little. The modified membranes can be used for the separation of various oil-in-water emulsions with high separation efficiency. It is also demonstrated that the membranes can be used repeatedly in the separation of emulsions. Furthermore, the coatings endow the membranes with strongly negatively charged surfaces, and hence the modified membranes show great potential in the adsorption of positively charged dyes. The results may introduce a novel monophenol-based system for surface deposition and greatly expand the types of surface deposition phenols.
- Surface deposition,
- Ferulic acid,
- Microporous polypropylene membrane,
- Oil/water separation,
- Dye adsorption
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