Citation: Jia Tian, Wei-an Zhang. Construction and Applications of Well-defined Porphyrin-containing Polymers[J]. Acta Polymerica Sinica, ;2019, 50(7): 653-670. doi: 10.11777/j.issn1000-3304.2019.19018 shu

Construction and Applications of Well-defined Porphyrin-containing Polymers

Jia Tian ,
Wei-an Zhang ^,

Shanghai Key Laboratory of Functional Materials Chemistry, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237

Corresponding author: Wei-an Zhang, wazhang@ecust.edu.cn
Received Date: 25 January 2019
Revised Date: 27 February 2019
Available Online: 3 April 2019

Porphyrins and their derivatives have attracted much attention due to their unique properties and various functions, and have been widely used in energy, catalysis and biomedical fields. Porphyrin-containing polymers possess both porphyrin and polymeric characteristics, which have also aroused great interest. On the basis of functional porphyrin units, the well-defined porphyrin-containing polymers not only have a clear and specific macromolecular structure, but also have been endowed with a variety of novel and unique features. By modifying the porphyrin units into the initiators, monomers or chain transfer agents, well-defined functional porphyrin-containing polymers with specific structures could be efficiently constructed by ring-opening polymerization (ROP), atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) polymerization or the combination of other strategies such as click chemistry. These well-defined porphyrin-containing polymers including telechelic polymers, alternating copolymers, block copolymers, star polymers, supramolecular polymers, can self-assemble to diverse morphologies such as spherical micelles, vesicles, nanorods and wormlike-structures and possess great potential in photodynamic therapy. Particularly, porphyrin-containing alternating copolymers can be obtained by RAFT copolymerization of 4-vinylbenzyl-terminated tetraphenylporphyrin and maleimide isobutyl polyhedral oligomeric silsesquioxane (POSS). The steric hindrance of POSS significantly reduces the π-π stacking of porphyrin units, which remarkably improve the singlet oxygen quantum yield and the photodynamic therapy efficacy.
- Block copolymer,
- Porphyrin,
- Star polymer,
- Supramolecular polymer,
- Photodynamic therapy
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Construction and Applications of Well-defined Porphyrin-containing Polymers

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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