Citation: Chen Lin, Xu-ming Xie. Preparation of GO/PMMA Nanocomposites with Significantly Increased Properties through Metal Ion Coordination[J]. Acta Polymerica Sinica, ;2019, 50(2): 170-178. doi: 10.11777/j.issn1000-3304.2018.18178 shu

Preparation of GO/PMMA Nanocomposites with Significantly Increased Properties through Metal Ion Coordination

Chen Lin ,
Xu-ming Xie ^,

Key Laboratory of Advanced Materials, Department of Chemical Engineering, Tsinghua University, Beijing 100084

Corresponding author: Xu-ming Xie, xxm-dce@mail.tsinghua.edu.cn
Received Date: 13 August 2018
Revised Date: 13 September 2018
Available Online: 6 December 2018

Metal ion coordinated GO/PMMA composites have been prepared by melt method. The interfacial interaction between the nanofiller and the polymer matrix is significantly increased due to the coordination bonding. As a result, the mechanical and thermal properties of the composites are highly improved. To study the property variation with the change of metal ions and preparation methods, two different metal ions (Cu(II) and Fe(III)) were added into the GO/PMMA system, respectively, and the composites were prepared by two different methods—the direct-melt method and the master-batch method. Fourier transform infrared spectroscopy (FTIR), Raman spectra, X-ray diffraction (XRD), scanning electron microscopy (SEM), tensile test, and thermogravimetic analysis (TGA) were performed to study the structures and properties of the composites. The FTIR results showed that GO and PMMA are successfully bridged via coordination bonding, for the characteristic peaks showed obvious blue shifts. Raman spectra indicated that coordination causes no extra defect to the GO sheets. SEM images showed that the GO sheets could be homogeneously dispersed in PMMA through master-batch method, while a poor dispersion through direct-melt method. From the tensile test results, it could be seen that the composites prepared by master-batch method had a better mechanical performance than those prepared by direct-melt method because of the different dispersion states. Fe(III)-coordinated composites have better mechanical performance than Cu(II)-coordinated composites do, due to the higher valence state of iron ions. The Young’s modulus and tensile strength of Fe(III)-0.5 wt% GO/PMMA composite are 29.6% and 31.8%, respectively, higher than those of the composite with only GO, and 75.0% and 35.7%, respectively, higher than those of neat PMMA. The temperature of maximum weight loss of Fe(III)-0.5 wt% GO/PMMA is 26 °C higher than that of GO/PMMA, and 82 °C higher than that of neat PMMA. This metal ion coordination method is efficient and simple, and can easily bridge nanofillers and polymer matrixes containing polar groups. This approach opens up a new strategy for improving the performance of many kinds of nanocomposites.
- Graphene oxide,
- Coordination,
- PMMA,
- Nanocomposite,
- Tensile property
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