Citation: Jun Song, Jun-nan Li, Yuan-fu Hou, Bo-wen Cheng, Lei Hao, Xue-xue Guo. Preparation and Properties of Antibacterial Cellulose Sorbate Films[J]. Acta Polymerica Sinica, ;2019, 50(1): 62-70. doi: 10.11777/j.issn1000-3304.2018.18168 shu

Preparation and Properties of Antibacterial Cellulose Sorbate Films

Jun Song ^1,2,, ,
Jun-nan Li ^1,2 ,
Yuan-fu Hou ^1,2 ,
Bo-wen Cheng ^1,2 ,
Lei Hao ^1,2 ,
Xue-xue Guo ^1,2

Corresponding author: Jun Song, sjhb2000@163.com
Received Date: 23 July 2018
Revised Date: 27 September 2018
Available Online: 9 November 2018

Cellulose has attracted considerable attention due to its unique advantages such as abundant availability, renewability, non-pollution, and biocompatibility. However, β-glucose units in cellulose backbone are vulnerable to erosion and degradation by aquatic microorganisms. The antibacterial modification of cellulose was proposed by covalently introducing sorbic acid through esterification process. Antibacterial cellulose sorbate films were prepared by one-step in situ reaction and immersion precipitation phase inversion process with wood-pulp cellulose as raw material, sorbic acid as antibacterial agent, and N,N'-dicyclohexylcarbodiimide (DCC) as dehydrating agent to improve its antibacterial performance. Among them, the molar ratio of hydroxyl in cellulose to sorbic acid was 1:2, the reaction temperature was 80 °C and the reaction time was 4, 6, 8, 10 and 12 h, respectively. The casting solutions were casted with casting knife of 250 μm thickness. And then antibacterial cellulose sorbate films were obtained after solvents evaporation and immersion precipitation process. The structure and performances of the obtained cellulose sorbate films were characterized by various methods such as Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), thermogravimetric analysis (TG-DTG) and differential scanning calorimetry analysis (DSC). The new characteristic peak of ester group (1715 cm⁻¹) in FTIR spectra indicated that cellulose sorbate films were successfully prepared by esterification reaction. XPS and ¹³C-NMR analysis results also showed the synthesis of cellulose sorbate. However, the crystal type and structure of cellulose had changed during esterification process. The results of TG and DSC showed that the effect of intra- and inter-molecular hydrogen bonds in cellulose were reduced or destroyed by the introduction of sorbic-acyl, leading to slightly lower thermal stability of the cellulose sorbate films. The dynamic contact antibacterial test results indicated that cellulose sorbate films had inhibitory effect on E. coli and S. aureus and possessed higher inhibition rate against S. aureus (99.2% − 100%) than that of E. coli (90.4% − 100%) due to different cell wall structures of E. coli and S. aureus. Therefore, the synthesized cellulose sorbate may have some potential applications in packing, environmental coatings, as well as some functional materials.
- Cellulose,
- Sorbic acid,
- N,N'-dicyclohexyl car bodiimide,
- Antibacterial,
- Immersion precipitation phase inversion
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