Citation: Min Chen, Chang-le Chen. Polar and Functionalized Polyolefins: New Catalysts, New Modulation Strategies and New Materials[J]. Acta Polymerica Sinica, ;2018, 0(11): 1372-1384. doi: 10.11777/j.issn1000-3304.2018.18155 shu

Polar and Functionalized Polyolefins: New Catalysts, New Modulation Strategies and New Materials

Min Chen ,
Chang-le Chen ^,

Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026

Corresponding author: Chang-le Chen, changle@ustc.edu.cn
Received Date: 3 July 2018
Revised Date: 6 August 2018
Available Online: 21 August 2018

In the past 50 years, the studies of olefin polymerization have achieved great successes in both academia and industry. Polyolefins have huge annual production and wide applications. However, one of their biggest limitations is their nonpolar nature. The introduction of a small amount of polar and functionalized groups can greatly improve many properties, broaden their applications, and increase their business values. Transition metal catalyzed copolymerization of olefin with polar monomers is the most direct route to access polar and functionalized polyolefins, which is also highly challenging. With the " polar monomer problem” as the central theme, this account mainly focuses on the works from our own research group and describes the following topics: modification of existing catalyst systems, development of new catalyst systems, design of new polymerization modulation strategies, and the synthesis and property studies of special polyolefins and polar functionalized polyolefins materials.
- Polar functionalized polyolefins,
- Polar monomer,
- Olefin copolymerization,
- Catalysts,
- Modulation strategies
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